研究了尖晶石锂锰氧化物电极首次脱锂过程中的电化学阻抗特征.通过选取适当的等效电路拟合实验所得的电化学阻抗谱数据,获得了首次脱锂过程中固体电解质相界面膜(SEI膜)的电阻、电容以及电荷传递电阻、双电层电容等随电极极化电位的变化规律.The first delithiation of the spinel LiMn2O4 electrode was studied using electrochemical impedance spectroscopy (EIS). Appropriate equivalent circuits were proposed to fit the experimental EIS data. Based on the fitting results, the variation of the capacitance and the resistance of SEI(solid electrolyte interphase) film, the resistance of charge transfer, and the capacitance of double layer along with the increase of polarization potential were quantitatively analyzed. The results demonstrated that the resistance and the thickness of the SEI film formed on the spinel LiMn2O4 electrode were both increased with the increase of polarization potential in the first delithiation of the spinel LiMn2O4 electrode; The charge transfer resistance decreases below 4.15 V and increases above 4.15 V, corresponding to the two-step reversible (de)intercalation of lithium between LiMn2O4 and λ-MnO2; The double layer capacitance was influenced by both the state of the spinel LiMn2O4 electrode(different polarization potential) and the two-step reversible (de)intercalation of lithium.国家重点基础研究发展规划项目(2002CB211804)资
