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unknown
现场拉曼光谱研究非水体系中铂电极上甲醇的解离吸附
Authors
任斌
姚建林
+5 more
孙玉华
曹佩根
曹文东
田中群
顾仁敖
Publication date
15 April 2001
Publisher
Abstract
本文在共焦显微拉曼系统上 ,利用表面增强拉曼散射效应 ( SERS)初步研究了非水体系中甲醇在粗糙铂电极上的解离吸附过程。结果表明 :甲醇在粗糙铂电极上解离吸附后产生了毒性中间物 CO,在较负的电位区间内 ,H与 CO共吸附于电极表面并影响 CO的吸附行为 ,随电位的正移 ,υPt- C和 υC- O的变化可以用电化学 Stark效应来进行解释
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Last time updated on 16/06/2016