作者简介:袁友珠(1963-),男,研究员.[中文文摘]概述了烯烃氢甲酰化水溶性铑膦配合物催化剂分子设计的发展和水平 ,讨论有关水溶性铑膦配合物的结构、性能和在氢甲酰化催化反应中的应用 ,内容包括水溶性铑膦配合物催化剂和负载型水溶性铑膦配合物催化剂的设计、制备及其催化剂失活机理 ,并藉以说明水溶性配体和催化剂的合成、两相催化的应用开拓以及新型催化体系的设计乃将是今后研究的重点。[英文文摘]The development of biphasic catalysis involving water soluble phosphine rhodium complexes catalyzed olefin hydroformylation was discussed, as illustrated by the synthesis, structure stability and deactivation mechanism of water soluble phosphine ligand coordinated rhodium complexes and supported aqueous phase catalysts. With this discussion, it is shown that for the biphasic catalysis system, the molecular design of novel ligand and water soluble complexes associated with the exploration of new cataly remains as key issues in the near future.国家自然科学基金(29792075;29873037);国家重点基础发展规划(G2000048008)资助项
