A small scale regularly packed circulating fluidized bed. Part II: Mass transfer

The underlying objective of the present study is to increase gas¿solids contact in a circulating fluidized bed by the introduction of obstacles in the riser portion. The presence of such obstacles leads to suppression of radial inhomogeneities in the solids mass flux and concentration, and break-up of solids clusters. At ambient conditions, gas¿solids mass transfer was investigated for cocurrent upward flow of air and microsize solid particles (FCC, 70 ¿m diameter) over a regularly structured inert packing introduced into the riser part of a circulating fluidized bed unit. The packed section has a height of 0.48 m, a cross-sectional area of 0.06 × O.06 m2, and contains regularly stacked 0.01 m diameter Perspex bars as the obstacles meant to enhance the gas¿solids contact. Gas mass fluxes used were 1.4 and 2.7 kg m¿2 s¿1. Solids mass fluxes were varied in the range 0Gs 12 kg m¿2 s¿1. Experimental mass transfer data were obtained by applying the method of adsorption of naphthalene vapor on FCC particles. A conservative estimate of the apparent gas¿solids mass transfer coefficient kg* could be derived from the naphthalene vapor concentration profile along the packed section on the basis of a plug-flow-model interpretation, while assuming single-particle behaviour and neglecting intraparticle diffusion effects. Such kg* values appear to increase with increasing gas mass flux, but decrease with increasing solids mass flux (and consequently increasing solids volume fraction) probably due to the corresponding increase in particle shielding. Comparison of the present results with available literature data for similar solid materials suggests that the effect of the packing inserted into the CFB is significant: the Sherwood numbers derived from the present study are relatively high

Theory of amorphous ices

We derive a phase diagram for amorphous solids and liquid supercooled water and explain why the amorphous solids of water exist in several different forms. Application of large-deviation theory allows us to prepare such phases in computer simulations. Along with nonequilibrium transitions between the ergodic liquid and two distinct amorphous solids, we establish coexistence between these two amorphous solids. The phase diagram we predict includes a nonequilibrium triple point where two amorphous phases and the liquid coexist. While the amorphous solids are long-lived and slowly-aging glasses, their melting can lead quickly to the formation of crystalline ice. Further, melting of the higher density amorphous solid at low pressures takes place in steps, transitioning to the lower density glass before accessing a nonequilibrium liquid from which ice coarsens.Comment: revision following review comment

Electrokinetic Treatment of Sludge

Disposal of sludge has become a major issue in the pulp and paper industry because of the decreased space in landfills and the possibility of pollution from the sludge. By increasing the amount of solids in the sludge (dewatering), the sludge could be disposed of using less land or by incineration, composting, or other method. The dewatered sludge is easier to handle also because of its decreased volume. The method of dewatering which was used for the experiment was by electrokinetics. Electrokinetics is the technology of separating solids and liquids from suspensions of finely divided solids or colloidal particles using an electrical potential. Using four different power levels, a final solids level of 5.9% was reached and a decreased volume of almost 50%. This data showed that electrokinetics does have the potential to greatly reduce the volume of material which needs to be disposed of. It may also be able to increase the solids level to a higher level with further modification

Operation of an activated sludge plant for fellmongery wastewater treatment : a thesis submitted in partial fulfilment of the requirements of the degree of Master of Technology in Environmental Engineering at Massey University, Palmerston North, New Zealand

Activated sludge is one of the most common wastewater-treatment processes used to reduce pollutant loads on the receiving environment. For efficient operation, there must be an effective process control and operation strategy in place to ensure that process problems are avoided. This research is a case study into the process control and operation of an activated sludge plant used for fellmongery wastewater treatment. Analysis of the pretreated fellmongery wastewater showed that it is characterised by high total and volatile suspended solids concentrations, and high organic nitrogen concentrations. The plant was experiencing frequent problems that were attributed to the high influent suspended solids load coupled with ineffective solids management. Operation of bench-scale simulations showed that solids retention time (SRT) control at 5 or 10 days will produce acceptable effluent suspended solids concentrations and soluble chemical oxygen demand (COD) removal. Soluble COD removal for both 5 and 10 days was high at 85 and 80 % respectively at a hydraulic retention time of 6.4 days. Effluent suspended solids concentrations were 100 and 157 g/m 3 respectively. A steady state control model was developed based on, mass balances of biochemical oxygen demand (BOD) and volatile suspended solids (VSS), process performance equations, and the solids retention time (SRT). The model used three control points, the clarifier underflow pump, the clarifier influent pump and the waste sludge pump. The model was incorporated into an off-line Activated Sludge Operation Program (ASOP) to provide a user-friendly interface between the plant and operator. The main output from ASOP includes values for the three control points and suggestions to help avoid problems. A process control and operation strategy was developed using ASOP, the knowledge gained in this research, and an operation manual developed from accepted operation practises

Structural lubricity: Role of dimension and symmetry

When two chemically passivated solids are brought into contact, interfacial interactions between the solids compete with intrabulk elastic forces. The relative importance of these interactions, which are length-scale dependent, will be estimated using scaling arguments. If elastic interactions dominate on all length scales, solids will move as essentially rigid objects. This would imply superlow kinetic friction in UHV, provided wear was absent. The results of the scaling study depend on the symmetry of the surfaces and the dimensionalities of interface and solids. Some examples are discussed explicitly such as contacts between disordered three-dimensional solids and linear bearings realized from multiwall carbon nanotubes.Comment: 7 pages, 1 figur

Role of surface roughness in superlubricity

We study the sliding of elastic solids in adhesive contact with flat and rough interfaces. We consider the dependence of the sliding friction on the elastic modulus of the solids. For elastically hard solids with planar surfaces with incommensurate surface structures we observe extremely low friction (superlubricity), which very abruptly increases as the elastic modulus decreases. We show that even a relatively small surface roughness may completely kill the superlubricity state.Comment: 11 pages, 17 figures, format revte

Processing for obtaining good quality water from sewage

Sewage treatment method incorporates aqueous slurry of activated carbon and ash. Process eliminates smell and greatly reduces amounts of solids requiring disposal. Solids consist only of sterile ash

Controlled Synthesis of Organic/Inorganic van der Waals Solid for Tunable Light-matter Interactions

Van der Waals (vdW) solids, as a new type of artificial materials that consist of alternating layers bonded by weak interactions, have shed light on fascinating optoelectronic device concepts. As a result, a large variety of vdW devices have been engineered via layer-by-layer stacking of two-dimensional materials, although shadowed by the difficulties of fabrication. Alternatively, direct growth of vdW solids has proven as a scalable and swift way, highlighted by the successful synthesis of graphene/h-BN and transition metal dichalcogenides (TMDs) vertical heterostructures from controlled vapor deposition. Here, we realize high-quality organic and inorganic vdW solids, using methylammonium lead halide (CH3NH3PbI3) as the organic part (organic perovskite) and 2D inorganic monolayers as counterparts. By stacking on various 2D monolayers, the vdW solids behave dramatically different in light emission. Our studies demonstrate that h-BN monolayer is a great complement to organic perovskite for preserving its original optical properties. As a result, organic/h-BN vdW solid arrays are patterned for red light emitting. This work paves the way for designing unprecedented vdW solids with great potential for a wide spectrum of applications in optoelectronics

Do solids flow?

Are solids intrinsically different from liquids? Must a finite stress be applied in order to induce flow? Or, instead, do all solids only look rigid on some finite timescales and eventually flow if an infinitesimal shear stress is applied? Surprisingly, these simple questions are a matter of debate and definite answers are still lacking. Here we show that solidity is only a time-scale dependent notion: equilibrium states of matter that break spontaneously translation invariance, e.g. crystals, flow if even an infinitesimal stress is applied. However, they do so in a way inherently different from ordinary liquids since their viscosity diverges for vanishing shear stress with an essential singularity. We find an ultra-slow decrease of the shear stress as a function of the shear rate, which explains the apparent yield stress identified in rheological flow curves. Furthermore, we suggest that an alternating shear of frequency $\omega$ and amplitude $\gamma$ should lead to a dynamic phase transition line in the ($\omega$,$\gamma$) plane, from a 'flowing' to a 'non-flowing' phase. Finally, we apply our results to crystals, show the corresponding microscopic process leading to flow and discuss possible experimental investigations.Comment: to be published in J. Stat. Phy