605,231 research outputs found

    A Microscopic Model of Gemini Surfactants: Self-assemblies in Water and at Air-Water Interface

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    We report the results of large scale Monte Carlo (MC) simulations of novel microscopic models of gemini surfactants to elucidate (i) their spontaneous aggregation in bulk water and (ii) their spatial organization in a system where water is separated from the air above it by a sharp well defined interface. We study the variation of the critical micellar concentration (CMC) with the variation of the (a) length of the spacer, (b) length of the hydrophobic tail and (c) the bending rigidity of the hydrocarbon chains forming the spacer and the tail; some of the trends of variation are counter-intuitive but are in excellent agreement with the available experimental results. Our simulations elucidate the effects of the geometrical shape, size and density of the surfactant molecules, the ionic nature of the heads and hydrophobicity/hydrophilicity of the spacer not only on the shapes of the micellar aggregates and the magnitude of the CMC, but also on their conformations close to the air-water interface.Comment: 19 pages in REVTEX, 25 Postscript Figures (now included

    Invariants of Welded Virtual Knots Via Crossed Module Invariants of Knotted Surfaces

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    We define an invariant of welded virtual knots from each finite crossed module by considering crossed module invariants of ribbon knotted surfaces which are naturally associated with them. We elucidate that the invariants obtained are non trivial by calculating explicit examples. We define welded virtual graphs and consider invariants of them defined in a similar way.Comment: New results. A perfected version will appear in Compositio Mathematic

    On Exchangeability in Network Models

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    We derive representation theorems for exchangeable distributions on finite and infinite graphs using elementary arguments based on geometric and graph-theoretic concepts. Our results elucidate some of the key differences, and their implications, between statistical network models that are finitely exchangeable and models that define a consistent sequence of probability distributions on graphs of increasing size.Comment: Dedicated to the memory of Steve Fienber

    Symmetries and novel universal properties of turbulent hydrodynamics in a symmetric binary fluid mixture

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    We elucidate the universal properties of the nonequilibrium steady states (NESS) in a driven symmetric binary fluid mixture, an example of active advection, in its miscible phase. We use the symmetries of the equations of motion to establish the appropriate form of the structure functions which characterise the statistical properties of the NESS of a driven symmetric binary fluid mixture. We elucidate the universal properties described by the scaling exponents and the amplitude ratios. Our results suggest that these exponents and amplitude ratios vary continuously with the degree of crosscorrelations between the velocity and the gradient of the concentration fields. Furthermore, we demonstrate, in agreement with Celani et al, Phys. Rev. Lett., 89, 234502 (2002, that the conventional structure functions as used in passive scalar turbulence studies exhibit only simple scaling in the problem of symmetric binary fluid mixture even in the weak concentration limit. We also discuss possible experimental verifications of our results.Comment: To appear in JSTAT (letters) (2005

    Antinucleus Production at RHIC

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    Light antinuclei may be formed in relativistic heavy ion collisions via final state coalescence of antinucleons. The yields of antinuclei are sensitive to primordial antinucleon production, the volume of the system at kinetic freeze-out, and space-momentum correlations among antinucleons at freeze-out. We report here preliminary STAR results on antideuteron and antihelion production in 130A GeV Au+Au collisions. These results are examined in a coalescence framework to elucidate the space-time structure of the antinucleon source.Comment: 4 pages, 3 figures, talk given at Quark Matter 200
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