Using the soil and water assessment tool to simulate the pesticide dynamics in the data scarce Guayas River Basin, Ecuador

Agricultural intensification has stimulated the economy in the Guayas River basin in Ecuador, but also affected several ecosystems. The increased use of pesticides poses a serious threat to the freshwater ecosystem, which urgently calls for an improved knowledge about the impact of pesticide practices in this study area. Several studies have shown that models can be appropriate tools to simulate pesticide dynamics in order to obtain this knowledge. This study tested the suitability of the Soil and Water Assessment Tool (SWAT) to simulate the dynamics of two different pesticides in the data scarce Guayas River basin. First, we set up, calibrated and validated the model using the streamflow data. Subsequently, we set up the model for the simulation of the selected pesticides (i.e., pendimethalin and fenpropimorph). While the hydrology was represented soundly by the model considering the data scare conditions, the simulation of the pesticides should be taken with care due to uncertainties behind essential drivers, e.g., application rates. Among the insights obtained from the pesticide simulations are the identification of critical zones for prioritisation, the dominant areas of pesticide sources and the impact of the different land uses. SWAT has been evaluated to be a suitable tool to investigate the impact of pesticide use under data scarcity in the Guayas River basin. The strengths of SWAT are its semi-distributed structure, availability of extensive online documentation, internal pesticide databases and user support while the limitations are high data requirements, time-intensive model development and challenging streamflow calibration. The results can also be helpful to design future water quality monitoring strategies. However, for future studies, we highly recommend extended monitoring of pesticide concentrations and sediment loads. Moreover, to substantially improve the model performance, the availability of better input data is needed such as higher resolution soil maps, more accurate pesticide application rate and actual land management programs. Provided that key suggestions for further improvement are considered, the model is valuable for applications in river ecosystem management of the Guayas River basin

Field Evaluations of Herbicides on Vegetable, Small Fruit, and Ornamental Crops, 2000, 2001, & 2002

Field evaluations of herbicides provide the chemical industry, governmental agencies, such as IR-4, and the Arkansas Agricultural Experiment Station with an evaluation of herbicide performance on small fruit, vegetable, and ornamental crops grown under Arkansas conditions. This report provides a means for disseminating information to interested private and public service weed scientists

Field Evaluation of Herbicides on Small Fruit, Vegetable, and Ornamental Crops, 1997

Growers generally use herbicides to efficiently produce high-quality fruit and vegetables for processing or fresh market sales. Due to the smaller acreage of these crops compared to major field crops, fewer herbicides are registered for use in fruit and vegetable crops than for field crops. Each year, new herbicides are evaluated under Arkansas growing conditions with the objective of improving the herbicide technology for the grower, processor, and ultimately the consumer. This report includes studies on the control of many of the more serious weed problems in important crops of this region, including snapbeans, spinach, southern pea, watermelon, cantaloupe, tomato, blackberry, and grape. In addition, the report includes information on the tolerance of selected bedding plants to some effective herbicides

Influence of Rice Production on the Quality of Water in Tailwater Collection Reservoirs

Since maintaining high water quality standards in the state remains a high priority, monitoring for pesticides in water sources must continue. Determining the type, concentration, and characteristics of any pesticides present in water supplies are essential to the overall assessment of water quality. Five independent locations, implementing contained water management systems and recyclable water, were monitored in 1995 and 1996. Irrigation, runoff, and pond water samples were collected every 10 to 14 days between permanent flood establishment and draining. Water samples were transported to the laboratory and extracted for 16 pesticides using solid phase extraction (SPE) techniques. Quantification and confirmation of pesticide residues were obta1ned by HPLC and GC/MS analysis. The lower limit of quantitation for all pesticides was between 1.0 -1.3 pg L-1 in water. Pesticides selected for monitoring were determined after assessing state recommendations and our analytical capabilities. Pesticides included: benomyl, bensulfuron methyl, carbaryl, carbofuran, 2,4-D, fenoxaprop ethyl, propiconazole, malathion, MCPA, methyl parathion, molinate, pendimethalin, propanil, iprodione, quinclorac, triclopyr, and thiobencarb. Since each field location was independently managed, individual results are site specific. 2,4-D, benomyl, molinate, propanil, quinclorac, thiobencarb, and pendimethalin were the pesticides actually applied during the seasons. These pesticides were detected, usually at trace levels, in tailwaters shortly after application but did not appear to buildup in the reservoirs. Quinclorac residues in the tailwaters were more persistent (up to 8 weeks) than the other detected compounds (less than 2 weeks)

Evaluation of herbicides and their combinations for weed control in wheat (Triticum aestivum L.)

The field experiment was conducted at the Student's Research Farm, P.G. Department of Agriculture, Khalsa College, Amritsar, Punjab, to study the evaluation of various herbicides and their combinations on wheat during 2016-17. The experiment was laid out in randomized block design with seven treatments such as weed free, weedy check, pendimethalin 2.5L/ha, pendimethalin 2.5L/ha + clodinofop 400 g/ha, pendimethalin 2.5L/ha + sulfosulfuron 32.5g/ha , pendimethalin 2.5L/ha + pinoxaden 1000 ml/ ha, pendimethalin 2.5L/ha + atlantis 400g/ha and replicated thrice. Results revealed that pendimethalin 2.5 L/ha + atlantis 400g/ha was found effective to control weed population and produced higher number of grains per ear and enhanced grain yield upto 62.3 per cent over weedy check

Structural characterization of phytotoxic terpenoids from Cestrum parqui.

Isolation, chemical characterization and phytotoxicity of nine polyhydroxylated terpenes (five C13 nor-isoprenoids, two sesquiterpenes, a spirostane and a pseudosapogenin) from Cestrum parqui LHerr are reported. In this work we completed the phytochemical investigation of the terpenic fraction of the plant and described the structural elucidation of polar isoprenoids using NMR methods. All the configurations of the compounds have been assigned by NOESY experiments. Four new structures have been identified as (3S,5R,6R,7E,9R)-5,6,9-trihydroxy-3-isopropyloxy-7-megastigmene, 5a-spirostan-3b,12b,15a-triol, and 26-O-(30-isopentanoyl)-b-Dglucopyranosyl- 5a-furost-20(22)-ene-3b,26-diol, and as an unusual tricyclic sesquiterpene. The compounds have been assayed for their phytotoxicity on lettuce at the concentrations ranging between 104 and 107 M. The activities of some compounds were similar to that of the herbicide pendimethalin

Herbicide Evaluation in Arkansas Rice, 1997

Weed control is economically important for production of rice, a major crop in Arkansas. These findings summarize efforts of the team of Arkansas scientists working on weed control strategies for rice during 1997. Various technologies were evaluated in field studies at five locations involving the major weed problems and rice production systems used in the state. Results from these studies will add to the arsenal of weed control options for producers. Highlights include synergists and safeners for herbicides to aid in control of propanil-resistant barnyardgrass; herbicides and flooding techniques for control of red rice and other weeds; and the use of transgenic rice cultivars for broadspectrum weed control. The preliminary results reported here generally warrant further testing for more advanced findings and for the labeling of new technologies, and finally are the basis for updating safe, effective, and economical recommendations to Arkansas rice producers

Probabilistic risk assessment of the environmental impacts of pesticides in the Crocodile (west) Marico catchment, North-West Province

External agricultural inputs, such as pesticides, may pose risks to aquatic ecosystems and affect aquatic populations, communities and ecosystems. To predict these risks, a tiered approach was followed, incorporating both the PRIMET and PERPEST models. The first-tier PRIMET model is designed to yield a relatively worst-case risk assessment requiring a minimum of input data, after which the effects of the risks can be refined using a higher tier PERPEST model. The risk assessment initially depends on data supplied from local landowners, pesticide characteristic, application scheme and physical scenario of the environment under question. Preliminary results are presented, together with ecotoxicological data on several frequently-used pesticides in a section of the Crocodile (west) Marico Water Management Area (WMA) in South Africa. This area is historically known to have a high pesticide usage, with deltamethrin, aldicarb, parathion, cypermethrin and dichlorvos being the main pesticides used. Deltamethrin was indicated as having the highest probability of risks to aquatic organisms occurring in the study area. Cypermethrin, parathion, dichlorvos, carbaryl, romoxynil, linuron, methomyl and aldicarb were all indicated as having possible risks (ETR 1-100) to the aquatic environment. Pesticides posing no risk included fenamiphos, abamectin, pendimethalin, captan, endosulfan, alachlor, bentazone and cyromazine (ET

Herbicide Evaluation in Arkansas Cotton, 1999

Herbicidal weed control is economically important for production of cotton. Field experiments are conducted annually in Arkansas to evaluate the activity of developmental and commercial herbicides for selective control of weeds in cotton. These experiments serve both industry and Arkansas agriculture by providing information on the selectivity of herbicides still in the developmental stage and by comparing the activity of these new herbicides with that of recommended herbicides