Experimental techniques and numerical models to detect pollutant emission in the transport sector

25th International Conference on Urban Transport and the Environment, Urban Transport 2019; Aveiro; Portugal; 25 June 2019 through 27 June 2019; Code 155807In recent years, the growth of fossil fuel use and greenhouse gases emissions (GHGs) has been promoted by the population increase and development of the industry sector. Due to the increasing attention towards the effects of climate changes on quality of life, recent researches on pollutant formation processes have been developed in different sectors, especially in transportation. The last emission standards on pollutants impose limits on the dimensions and on the particle number of the particulate matter emissions, because of the highly dangerous effect on human health. To fight high concentrations of particulate matter (PM) emissions, a wide number of studies are addressed towards the definition of the most important parameters in effective production of particulate matter, especially in spark ignition engines. Physical processes such as mixture formation, engine operating parameters and fuel chemical properties strongly affect the soot formation in gasoline engines. The heat transfer process between the piston hot surface and the fuel gasoline during the post-injection phase is a key aspect of soot emissions for an engine. This paper is devoted to analyzing the fundamental parameters that are responsible for pollutant formation in the transport sector and the actual experimental and numerical techniques used to predict the environmental impact of engines

Oscillatory processes in the theory of particulate formation in supersaturated chemical solutions

We study a nonlinear problem which occurs in the theory of particulate formation in supersaturated chemical solutions. Mathematically, the problem involves the bifurcation of time-periodic solutions in an initial-boundary value problem involving a nonlinear integro-differential equation. The mechanism controlling the oscillatory states is revealed by combining the theory of characteristics for first order partial differential equations with the multi-time scale perturbation analysis of a certain third order system of nonlinear ordinary differential equations

Sediment and particulate carbon removal by pipe erosion increase over time in blanket peatlands as a consequence of land drainage

Land drainage is common in peatlands. Artificially drained blanket peat catchments have been shown to have a significantly greater soil pipe density than intact catchments. This paper investigates the role of surface land drains in the enhancement of soil piping in blanket peats. The density of piping was found to significantly increase in a linear fashion with the age of the drainage. Thirty-five years after drains were cut, slopes would be expected to have twice the density of soil piping than would an undrained blanket peat catchment. The rate of pipe erosion increases exponentially over time, so that particulate carbon loss from subsurface pipes is greatest where drains are oldest

Hydro-mechanical network modelling of particulate composites

Differential shrinkage in particulate quasi-brittle materials causes microcracking which reduces durability in these materials by increasing their mass transport properties. A hydro-mechanical three-dimensional periodic network approach was used to investigate the influence of particle and specimen size on the specimen permeability. The particulate quasi-brittle materials studied here consist of stiff elastic particles, and a softer matrix and interfacial transition zones between matrix and particles exhibiting nonlinear material responses. An incrementally applied uniform eigenstrain, along with a damage-plasticity constitutive model, are used to describe the shrinkage and cracking processes of the matrix and interfacial transition zones. The results showed that increasing particle diameter at constant volume fraction increases the crack widths and, therefore, permeability, which confirms previously obtained 2D modelling results. Furthermore, it was demonstrated that specimen thickness has, in comparison to the influence of particle size, a small influence on permeability increase due to microcracking

The vertical distribution of iron stable isotopes in the North Atlantic near Bermuda

Seawater dissolved iron isotope ratios (δ^(56)Fe) have been measured in the North Atlantic near Bermuda. In a full-depth profile, seawater dissolved δ^(56)Fe is isotopically heavy compared to crustal values throughout the water column (δ^(56)Fe_(IRMM-014) = +0.30‰ to +0.71‰). Iron isotope ratios are relatively homogenous in the upper water column (between +0.30‰ to +0.45‰ above 1500 m), and δ^(56)Fe increases below this to a maximum of +0.71‰ at 2500 m, decreasing again to +0.35‰ at 4200 m. The δ^(56)Fe profile is very different from the iron concentration profile; in the upper water column [Fe] is variable while δ^(56)Fe is relatively constant, and in the deeper water column δ^(56)Fe varies while [Fe] remains relatively constant. The δ^(56)Fe profile is also not well correlated with other hydrographic tracers in the North Atlantic such as temperature, salinity, or the concentrations of oxygen, phosphate, silica, and CFC-11. The dissimilarity between δ^(56)Fe profiles and profiles of [Fe] and other hydrographic tracers shows that Fe isotope ratios provide a unique sort of information about ocean chemistry, and they suggest that Fe isotopes may therefore be a valuable new tool for tracing the global sources, sinks, and biogeochemical cycling of Fe

Particle Size Distribution in Aluminum Manufacturing Facilities.

As part of exposure assessment for an ongoing epidemiologic study of heart disease and fine particle exposures in aluminum industry, area particle samples were collected in production facilities to assess instrument reliability and particle size distribution at different process areas. Personal modular impactors (PMI) and Minimicro-orifice uniform deposition impactors (MiniMOUDI) were used. The coefficient of variation (CV) of co-located samples was used to evaluate the reproducibility of the samplers. PM2.5 measured by PMI was compared to PM2.5 calculated from MiniMOUDI data. Mass median aerodynamic diameter (MMAD) and concentrations of sub-micrometer (PM1.0) and quasi-ultrafine (PM0.56) particles were evaluated to characterize particle size distribution. Most of CVs were less than 30%. The slope of the linear regression of PMI_PM2.5 versus MiniMOUDI_PM2.5 was 1.03 mg/m3 per mg/m3 (± 0.05), with correlation coefficient of 0.97 (± 0.01). Particle size distribution varied substantively in smelters, whereas it was less variable in fabrication units with significantly smaller MMADs (arithmetic mean of MMADs: 2.59 μm in smelters vs. 1.31 μm in fabrication units, p = 0.001). Although the total particle concentration was more than two times higher in the smelters than in the fabrication units, the fraction of PM10 which was PM1.0 or PM0.56 was significantly lower in the smelters than in the fabrication units (p < 0.001). Consequently, the concentrations of sub-micrometer and quasi-ultrafine particles were similar in these two types of facilities. It would appear, studies evaluating ultrafine particle exposure in aluminum industry should focus on not only the smelters, but also the fabrication facilities

Treading in Mortimer's footsteps: the geochemical cycling of iron and manganese in Esthwaite water

A study of the geochemical cycling of iron and manganese in a seasonally stratified lake, Esthwaite water is described. This work is based on speculative ideas on environmental redox chemistry of iron which were proposed by C.H. Mortimer in the 1940's. These observations have been verified and some speculations confirmed, along with a new understanding of the manganese cycle, and detailed information on the particulate forms of both iron and manganese. Details on the mechanisms and transformations of iron have also emerged

WRF-Chem model predictions of the regional impacts of N2O5 heterogeneous processes on night-time chemistry over north-western Europe

Abstract. Chemical modelling studies have been conducted over north-western Europe in summer conditions, showing that night-time dinitrogen pentoxide (N2O5) heterogeneous reactive uptake is important regionally in modulating particulate nitrate and has a~modest influence on oxidative chemistry. Results from Weather Research and Forecasting model with Chemistry (WRF-Chem) model simulations, run with a detailed volatile organic compound (VOC) gas-phase chemistry scheme and the Model for Simulating Aerosol Interactions and Chemistry (MOSAIC) sectional aerosol scheme, were compared with a series of airborne gas and particulate measurements made over the UK in July 2010. Modelled mixing ratios of key gas-phase species were reasonably accurate (correlations with measurements of 0.7–0.9 for NO2 and O3). However modelled loadings of particulate species were less accurate (correlation with measurements for particulate sulfate and ammonium were between 0.0 and 0.6). Sulfate mass loadings were particularly low (modelled means of 0.5–0.7 μg kg−1air, compared with measurements of 1.0–1.5 μg kg−1air). Two flights from the campaign were used as test cases – one with low relative humidity (RH) (60–70%), the other with high RH (80–90%). N2O5 heterogeneous chemistry was found to not be important in the low-RH test case; but in the high-RH test case it had a strong effect and significantly improved the agreement between modelled and measured NO3 and N2O5. When the model failed to capture atmospheric RH correctly, the modelled NO3 and N2O5 mixing ratios for these flights differed significantly from the measurements. This demonstrates that, for regional modelling which involves heterogeneous processes, it is essential to capture the ambient temperature and water vapour profiles. The night-time NO3 oxidation of VOCs across the whole region was found to be 100–300 times slower than the daytime OH oxidation of these compounds. The difference in contribution was less for alkenes (× 80) and comparable for dimethylsulfide (DMS). However the suppression of NO3 mixing ratios across the domain by N2O5 heterogeneous chemistry has only a very slight, negative, influence on this oxidative capacity. The influence on regional particulate nitrate mass loadings is stronger. Night-time N2O5 heterogeneous chemistry maintains the production of particulate nitrate within polluted regions: when this process is taken into consideration, the daytime peak (for the 95th percentile) of PM10 nitrate mass loadings remains around 5.6 μg kg−1air, but the night-time minimum increases from 3.5 to 4.6 μg kg−1air. The sustaining of higher particulate mass loadings through the night by this process improves model skill at matching measured aerosol nitrate diurnal cycles and will negatively impact on regional air quality, requiring this process to be included in regional models. </jats:p