143,818 research outputs found
Odd tensor electric transitions in high-spin Sn-isomers and generalized seniority
The similar behavior of the B(E1) values of the recently observed 13- odd
tensor E1 isomers and the B(E2) values of the 10+ and 15- even tensor E2
isomers in the Sn-isotopes has been understood in terms of the generalized
seniority for multi-j orbits by using the quasi-spin scheme. This simple
approach proves to be quite successful in explaining the measured transition
probabilities and the corresponding half-lives in the high-spin isomers of the
semi-magic Sn-isotopes. Hence, we show for the first time the occurrence of
seniority isomers in the 13- Sn-isomers, which decay by odd-tensor E1
transitions to the same seniority states.Comment: 4 pages, 3 figure
Ab initio density functional investigation of B_24 cluster: Rings, Tubes, Planes, and Cages
We investigate the equilibrium geometries and the systematics of bonding in
various isomers of a 24-atom boron cluster using Born-Oppenheimer molecular
dynamics within the framework of density functional theory. The isomers studied
are the rings, the convex and the quasiplanar structures, the tubes and, the
closed structures. A staggered double-ring is found to be the most stable
structure amongst the isomers studied. Our calculations reveal that a 24-atom
boron cluster does form closed 3-d structures. All isomers show staggered
arrangement of nearest neighbor atoms. Such a staggering facilitates
hybridization in boron cluster. A polarization of bonds between the peripheral
atoms in the ring and the planar isomers is also seen. Finally, we discuss the
fusion of two boron icosahedra. We find that the fusion occurs when the
distance between the two icosahedra is less than a critical distance of about
6.5a.u.Comment: 8 pages, 9 figures in jpeg format Editorially approved for
publication in Phys. Rev.
Glycolaldehyde, methyl formate and acetic acid adsorption and thermal desorption from interstellar ices
We have undertaken a detailed investigation of the adsorption, desorption and thermal processing of the astrobiologically significant isomers glycolaldehyde, acetic acid and methyl formate. Here, we present the results of laboratory infrared and temperature programmed desorption (TPD) studies of the three isomers from model interstellar ices adsorbed on a carbonaceous dust grain analogue surface. Laboratory infrared data show that the isomers can be clearly distinguished on the basis of their infrared spectra, which has implications for observations of interstellar ice spectra. Laboratory TPD data also show that the three isomers can be distinguished on the basis of their thermal desorption behaviour. In particular, TPD data show that the isomers cannot be treated the same way in astrophysical models of desorption. The desorption of glycolaldehyde and acetic acid from water-dominated ices is very similar, with desorption being mainly dictated by water ice. However, methyl formate also desorbs from the surface of the ice, as a pure desorption feature, and therefore desorbs at a lower temperature than the other two isomers. This is more clearly indicated by models of the desorption on astrophysical time-scales corresponding to the heating rate of 25 and 5 M⊙ stars. For a 25 M⊙ star, our model shows that a proportion of the methyl formate can be found in the gas phase at earlier times compared to glycolaldehyde and acetic acid. This has implications for the observation and detection of these molecules, and potentially explains why methyl formate has been observed in a wider range of astrophysical environments than the other two isomers
Surface reconstruction induced geometries of Si clusters
We discuss a generalization of the surface reconstruction arguments for the
structure of intermediate size Si clusters, which leads to model geometries for
the sizes 33, 39 (two isomers), 45 (two isomers), 49 (two isomers), 57 and 61
(two isomers). The common feature in all these models is a structure that
closely resembles the most stable reconstruction of Si surfaces, surrounding a
core of bulk-like tetrahedrally bonded atoms. We investigate the energetics and
the electronic structure of these models through first-principles density
functional theory calculations. These models may be useful in understanding
experimental results on the reactivity of Si clusters and their shape as
inferred from mobility measurements.Comment: 9 figures (available from the author upon request) Submitted to Phys.
Rev.
Isomeric states close to doubly magic Sn studied with JYFLTRAP
The double Penning trap mass spectrometer JYFLTRAP has been employed to
measure masses and excitation energies for isomers in Cd,
Cd, Cd and Te, for isomers in In and
In, and for isomers in Sn and Sb. These first
direct mass measurements of the Cd and In isomers reveal deviations to the
excitation energies based on results from beta-decay experiments and yield new
information on neutron- and proton-hole states close to Sn. A new
excitation energy of 144(4) keV has been determined for Cd. A good
agreement with the precisely known excitation energies of Cd,
Sn, and Sb has been found.Comment: 10 pages, 6 figures, submitted to Phys. Rev.
Erasable holographic medium using cis-trans isomerization
Photochemical process has been developed for recording of erasable holograms by utilizing reversible transformation of two isomers of molecule upon exposure to light. Hologram system records, reads, and erases in response to changes in refractive index of mixture of isomers
Generation of Long-Lived Isomeric States via Bremsstrahlung Irradiation
A method to generate long-lived isomeric states effectively for Mossbauer
applications is reported. We demonstrate that this method is better and easier
to provide highly sensitive Mossbauer effect of long-lived isomers (>1ms) such
as 103Rh. Excitation of (gamma,gamma) process by synchrotron radiation is
painful due mainly to their limited linewidth. Instead,(gamma,gamma') process
of bremsstrahlung excitation is applied to create these long-lived isomers.
Isomers of 45Sc, 107Ag, 109Ag, and 103Rh have been generated from this method.
Among them, 103Rh is the only one that we have obtained the gravitational
effect at room temperature.Comment: ICAME 05 conference repor
Optical Absorption in B Cluster: A Time-Dependent Density Functional Approach
The linear optical absorption spectra of three isomers of planar boron
cluster B are calculated using time-dependent spin-polarized density
functional approach. The geometries of these cluster are optimized at the
B3LYP/6-311+G* level of theory. Even though the isomers are almost degenerate,
the calculated spectra are quite different, indicating a strong
structure-property relationship. Therefore, these computed spectra can be used
in the photo-absorption experiments to distinguish between different isomers of
a cluster.Comment: Version2: Latex and hyperref enabled. Minor typos corrected. 4
figures, 2 pages. Accepted manuscript. To appear in AIP Conference
Proceeding
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