Interpretation of the exergy equation for steady-flow processes

We define and discuss the terms in exergy equations, with particular reference to the role of chemical terms in the exergy loss for steady-flow processes. Although there is a chemical contribution to exergy, exergy losses of steady-flow processes may be calculated by using a simple expression for the specific exergy, namely, b = h − T*s. No restrictions are found in the material flows involved. The necessity of prescribing a standard chemical reference environment is considered and rejected. Instead, a sign convention for material flows is proposed. Finally, some results of Brzustowski's calculations are reviewed and discussed

General methodology for exergy balance in ProSimPlus® process simulator

This paper presents a general methodology for exergy balance in chemical and thermal processes integrated in ProSimPlus® as a well-adopted process simulator for energy efficiency analysis. In this work, as well as using the general expressions for heat and work streams, all of exergy balance is presented within only one software in order to fully automate exergy analysis. In addition, after exergy balance, the essential elements such as source of irreversibility for exergy analysis are presented to help the user for modifications on either process or utility system. The applicability of the proposed methodology in ProSimPlus® is shown through a simple scheme of Natural Gas Liquids (NGL) recovery process and its steam utility system. The methodology does not only provide the user with necessary exergetic criteria to pinpoint the source of exergy losses, it also helps the user to find the way to reduce the exergy losses. These features of the proposed exergy calculator make it preferable for its implementation in ProSimPlus® to define the most realistic and profitable retrofit projects on the existing chemical and thermal plants

Exergy analysis of a solar photovoltaic module

PV energy is the direct conversion of solar radiation into electricity. In this paper, an analysis of the influence of parameters such as global irradiance or temperature in the performance of a PV installation has been carried out. A PV module was installed in a building at the University of Málaga, and these parameters were experimentally determined for different days and different conditions of irradiance and temperature. Moreover, IV curves were obtained under these conditions to know the open-circuit voltage and the short-circuit current of the module. With this information, and using the first law of thermodynamics, an energy analysis was performed to determine the energy efficiency of the installation. Similarly, using the second law of thermodynamics, an exergy analysis is used to obtain the exergy efficiency. The results show that the energy efficiency varies between 10% and 12% and the exergy efficiency between 14% and 17%. It was concluded that the exergy analysis is more suitable for studying the performance, and that only electric exergy must be considered as useful exergy. This exergy efficiency can be improved if heat is removed from the PV module surface, and an optimal temperature is reached.Universidad de Málaga. Campus de Excelencia Internacional Andalucía Tech

“Exergy based analysis of economic sustainability”

Exergy is presented here as the physical prime-mover of economic systems, and an exergy based concept of value is proposed in this paper. The main exergy fluxes are identified as those carried by raw exergy (primary sources), raw materials, usable exergy and exergy embodied in manufactured commodities. It is shown how efficiency of exergy use is the physical basis for competitiveness and how exergy content (value)can be assigned to skillfulness and expertise. Sustainability of economic systems is analyzed in the light of competitiveness and ability to take extra exergy taken from markets. It is also shown that in competitive economies the ratio (raw exergy)/(total value) tends to decrease, therefore indicating extra exergy from the markets, and this trend is illustrated with the case of the US economy. Finally, the average electricity price in the markets was proposed as a provisional correspondence between exergy content and price of commodities

Advanced Exergy Analysis in the Dynamic Framework for Assessing Building Thermal Systems

This work applies the Dynamic Advanced Exergy Analysis (DAEA) to a heating and domestic hot water (DHW) facility supplied by a Stirling engine and a condensing boiler. For the first time, an advanced exergy analysis using dynamic conditions is applied to a building energy system. DAEA provides insights on the components’ exergy destruction (ED) by distinguishing the inefficiencies that can be prevented by improving the quality (avoidable ED) and the ones constrained because of technical limitations (unavoidable ED). ED is related to the inherent inefficiencies of the considered element (endogenous ED) and those coming from the interconnections (exogenous ED). That information cannot be obtained by any other approach. A dynamic calculation within the experimental facility has been performed after a component characterization driven by a new grey-box modelling technique, through TRNSYS and MATLAB. Novel solutions and terms of ED are assessed for the rational implementation of the DAEA in building energy installations. The influence of each component and their interconnections are valuated in terms of exergy destruction for further diagnosis and optimization purposes.BMWi, 03ET1218B, Anwendung exergiebasierter Methoden zur Verbesserung von Gebäudeenergiesysteme

Exergy analysis of a PWR nuclear steam supply system - II part: a case study

The paper shows the results of the exergetic analysis of the Nuclear Steam Supply System (NSSS) of the MARS Pressurized Light Water Reactor using the theoretical methodology described in the authors’ previous works [1] and [2]. The analysis firstly aims at a novel assessment of the irreversibilities occurred in the nuclear reactor vessel to compare the results, in terms of Exergy Destruction and exergetic Efficiency, with those obtained adopting one of the most employed methodology as reference. The comparison showed that a detailed exergetic analysis, mainly aimed to strictly assess the fission temperature, can lead to a higher estimate of the PWR exergetic Efficiency values

Multiobjective genetic algorithm strategies for electricity production from generation IV nuclear technology

Development of a technico-economic optimization strategy of cogeneration systems of electricity/hydrogen, consists in finding an optimal efficiency of the generating cycle and heat delivery system, maximizing the energy production and minimizing the production costs. The first part of the paper is related to the development of a multiobjective optimization library (MULTIGEN) to tackle all types of problems arising from cogeneration. After a literature review for identifying the most efficient methods, the MULTIGEN library is described, and the innovative points are listed. A new stopping criterion, based on the stagnation of the Pareto front, may lead to significant decrease of computational times, particularly in the case of problems involving only integer variables. Two practical examples are presented in the last section. The former is devoted to a bicriteria optimization of both exergy destruction and total cost of the plant, for a generating cycle coupled with a Very High Temperature Reactor (VHTR). The second example consists in designing the heat exchanger of the generating turbomachine. Three criteria are optimized: the exchange surface, the exergy destruction and the number of exchange modules

Exergy analysis of a PWR nuclear steam supply system – Part I, general theoretical model

The paper provides an alternative, novel methodology to perform the exergetic analysis of a Pressurized Nuclear Reactor (PWR) based on the strictest definition of fission temperature to get to a careful evaluation of Exergy Destruction and exergetic Efficiency of the component. Up today, the exegetic analyses of Nuclear Power Plants (NPP) have been based on the assumption that Fission Exergy and Fission Energy are almost the same having assumed Carnot Factor almost equal to 1 as Tfiss >>T0. This assumption is based on some simplified hypotheses concerning fission temperature as applied in the definition of the Fission Exergy itself, whose value, to the best knowledge of the authors, was never modeled. On the contrary, in the first part of the paper, the authors present the results of an ongoing research, just aimed at evaluating the Exergy efficiency of the heat exchange in a PWR reactor, whose first results were already presented in [1], based on the most detailed modeling of Tfiss. The modeling, referring to a steady-state operational mode of the Reactor, takes into account all heat transfer phenomena between nuclear fuel UO2, its Zircaloy clad, cooling water, vessel material and the external environment. In the second part of the paper, the Exergy analysis is extended to all main Reactor Cooling System components (Vertical recirculating type Steam Generator, primary coolant pump and piping) with the aim to compare the Exergy Destructions and exergetic Efficiencies of the RPV with those of the other components of the Nuclear Steam Supply System, NSSS. In the Part II of the same paper,, "Exergy Analysis of a PWR Nuclear Steam Supply System - II part: a case study ", a test case is exemplified with the aim to compare the results obtained applying the methodology in question with those obtained applying the most established methodology adopted by other authors

Analysis of the Behaviour of Biofuel-Fired Gas Turbine Power Plants

The utilisation of biofuels in gas turbines is a promising alternative to fossil fuels for power generation. It would lead to significant reduction of CO2 emissions using an existing combustion technology, although significant changes seem to be needed and further technological development is necessary. The goal of this work is to perform energy and exergy analyses of the behaviour of gas turbines fired with biogas, ethanol and synthesis gas (bio-syngas), compared with natural gas. The global energy transformation process (i.e. from biomass to electricity) has also been studied. Furthermore, the potential reduction of CO2 emissions attained by the use of biofuels has been determined, considering the restrictions regarding biomass availability. Two different simulation tools have been used to accomplish the aims of this work. The results suggest a high interest and the technical viability of the use of Biomass Integrated Gasification Combined Cycle (BIGCC) systems for large scale power generation