Mechanism of Ni1–xZnxO Formation by Thermal Treatments on NiO Nanoparticles Dispersed over ZnO

9 figurasThe formation of Ni1–xZnxO rock salt solid solution is obtained by thermal treatments applied to NiO nanoparticles supported on ZnO micrometric particles. The high vapor pressure of ZnO produces a Zn-rich atmosphere during thermal treatment. The Zn ions tend to be adsorbed by the highly reactive NiO nanoparticles. When heated to temperatures high enough, over 500 °C, the Zn ions react with the NiO nanoparticles forming the rock salt material. By variation of the treatment temperature, the composition of this rock salt structure can be varied through the whole solubility range.The authors express their thanks to the MICINN (Spain)projects MAT 2010-21088-C03-01, MICINN ACI PLAN E (JAPON) ref: PLE2009-0073, and to the European Comission ERC-2008-Stg: 240497 for their financial support.Peer reviewe