2 research outputs found
Formation and Cleavage of C鈭扝, C鈭扖, and C鈭扥 Bonds of ortho-Methyl-Substituted Anisoles by Late Transition Metals
No full text2 p谩ginas, esquemas.2,6-Dimethyl-substituted anisoles can be converted into the corresponding 2-ethyl-6-methylphenols in a several-step reaction mediated by a TpMe2Ir(III) complex; use of the 13C-enriched anisoles, ArO13CH3, shows that the 13C label distributes across the two ethyl sites with a preference for the terminal position.Financial support from the DGI (Project CTQ 2004-00409/BQU, FEDER support), the Junta de Andaluc铆a, and cooperation project CSIC-CONACyT are gratefully acknowledged. L.L.S. and P.L. thank the MEC for research grants.Peer reviewe
Formation and Cleavage of C鈭扝, C鈭扖, and C鈭扥 Bonds of ortho-Methyl-Substituted Anisoles by Late Transition Metals
No full text2 p谩ginas, esquemas.2,6-Dimethyl-substituted anisoles can be converted into the corresponding 2-ethyl-6-methylphenols in a several-step reaction mediated by a TpMe2Ir(III) complex; use of the 13C-enriched anisoles, ArO13CH3, shows that the 13C label distributes across the two ethyl sites with a preference for the terminal position.Financial support from the DGI (Project CTQ 2004-00409/BQU, FEDER support), the Junta de Andaluc铆a, and cooperation project CSIC-CONACyT are gratefully acknowledged. L.L.S. and P.L. thank the MEC for research grants.Peer reviewe
