1,771 research outputs found

    Suppression of 2D superconductivity by the magnetic field: quantum corrections vs superconductor-insulator transition

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    Magnetotransport of superconducting Nd_{2-x}Ce_xCuO_{4+y} (NdCeCuO) films is studied in the temperature interval 0.3-30 K. The microscopic theory of the quantum corrections to conductivity, both in the Cooper and in the diffusion channels, qualitatively describes the main features of the experiment including the negative magnetoresistance in the high field limit. Comparison with the model of the field-induced superconductor-insulator transition (SIT) is included and a crossover between these two theoretical approaches is discussed.Comment: 5 pages, 4 figures. Submitted to JETP Letter

    Lithium Diffusion & Magnetism in Battery Cathode Material LixNi1/3Co1/3Mn1/3O2

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    We have studied low-temperature magnetic properties as well as high-temperature lithium ion diffusion in the battery cathode materials LixNi1/3Co1/3Mn1/3O2 by the use of muon spin rotation/relaxation. Our data reveal that the samples enter into a 2D spin-glass state below TSG=12 K. We further show that lithium diffusion channels become active for T>Tdiff=125 K where the Li-ion hopping-rate [nu(T)] starts to increase exponentially. Further, nu(T) is found to fit very well to an Arrhenius type equation and the activation energy for the diffusion process is extracted as Ea=100 meV.Comment: Submitted to Journal of Physics: Conference Series (2014

    Slow Dynamics in Ion-Conducting Sodium Silicate Melts: Simulation and Mode-Coupling Theory

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    A combination of molecular-dynamics (MD) computer simulation and mode-coupling theory (MCT) is used to elucidate the structure-dynamics relation in sodium-silicate melts (NSx) of varying sodium concentration. Using only the partial static structure factors from the MD as an input, MCT reproduces the large separation in relaxation time scales of the sodium and the silicon/oxygen components. This confirms the idea of sodium diffusion channels which are reflected by a prepeak in the static structure factors around 0.95 A^-1, and shows that it is possible to explain the fast sodium-ion dynamics peculiar to these mixtures using a microscopic theory.Comment: 4 pages, 4 figure

    Matrix controlled channel diffusion of sodium in amorphous silica

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    To find the origin of the diffusion channels observed in sodium-silicate glasses, we have performed classical molecular dynamics simulations of Na2_2O--4SiO2_2 during which the mass of the Si and O atoms has been multiplied by a tuning coefficient. We observe that the channels disappear and that the diffusive motion of the sodium atoms vanishes if this coefficient is larger than a threshold value. Above this threshold the vibrational states of the matrix are not compatible with those of the sodium ions. We interpret hence the decrease of the diffusion by the absence of resonance conditions.Comment: 5 pages, 4 figure

    Normal Inverse Gaussian Approximation for Arrival Time Difference in Flow-Induced Molecular Communications

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    In this paper, we consider molecular communications in one-dimensional flow-induced diffusion channels with a perfectly absorbing receiver. In such channels, the random propagation delay until the molecules are absorbed follows an inverse Gaussian (IG) distribution and is referred to as first hitting time. Knowing the distribution for the difference of the first hitting times of two molecules is very important if the information is encoded by a limited set of molecules and the receiver exploits their arrival time and/or order. Hence, we propose a moment matching approximation by a normal inverse Gaussian (NIG) distribution and we derive an expression for the asymptotic tail probability. Numerical evaluations showed that the NIG approximation matches very well with the exact solution obtained by numerical convolution of the IG density functions. Moreover, the asymptotic tail probability outperforms state-of-the-art tail approximations.Comment: This paper has been submitted to IEEE Transactions on Molecular, Biological and Multi-Scale Communication

    Novel diffusion mechanism on the GaAs(001) surface: the role of adatom-dimer interaction

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    Employing first principles total energy calculations we have studied the behavior of Ga and Al adatoms on the GaAs(001)-beta2 surface. The adsorption site and two relevant diffusion channels are identified. The channels are characterized by different adatom-surface dimer interaction. Both affect in a novel way the adatom migration: in one channel the diffusing adatom jumps across the surface dimers and leaves the dimer bonds intact, in the other one the surface dimer bonds are broken. The two channels are taken into account to derive effective adatom diffusion barriers. From the diffusion barriers we conclude a strong diffusion anisotropy for both Al and Ga adatoms with the direction of fastest diffusion parallel to the surface dimers. In agreement with experimental observations we find higher diffusion barriers for Al than for Ga.Comment: 4 pages, 2 figures, Phys. Rev. Lett. 79 (1997). Other related publications can be found at http://www.rz-berlin.mpg.de/th/paper.htm

    Economic Development and Technology Diffusion

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    I first present a New Economic Geography model and analyze the impact of R&D on economic development of integrating countries. I find that technology diffusion and skilled labor migration stimulates economic development through fix cost reduction on a firm level. As the inclusion of foreign technology matters for structurally backward countries, I second use time series data for Greece, Portugal, Spain and Ireland representing European integration during the 1980s and 1990s. In considering three different technology diffusion channels, estimates, however, reduces to Portugal as test procedures confirm nonstationarity and cointegration only for this country. I find empirical evidence for bilateral trade as a diffusion channel but not for FDI or foreign patents.Economic Geography, Agglomeration, Technology Diffusion, Nonstationary Time Series
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