6,484 research outputs found
Electric discharge machine for preparation of diamond anvil cell sample chambers
We have designed and constructed a novel electric discharge machine designed primarily for the preparation of sample chambers in rhenium and stainless steel gaskets for diamond anvil cell experiments. Our design combines automatic stage movement with relatively low voltage (100 V) operation and routinely achieves a drilling/erosion speed of approximately 0.4 μms−1. The machine is used for preparing 100 μm diameter sample chambers for diamond anvil cell experiments with 250 μm culets and has also been used to prepare 50 μm diameter sample chambers for diamond anvil cell experiments with 100 μm culets to access a pressure of 165 GPa
The actual pressure and temperature at the melt of elemental vanadium
It is claimed that all of the pressure scales of the reported melting curves
derived by diamond anvil cell experiments require a correction which takes into
account the pressure thermal shift, where vanadium is an illustrative example.
The linear behavior of the thermal pressure (Pth) vs. the temperature, as
predicted by first principles theoretical assumptions is then experimentally
confirmed. This allows extrapolation to determine of the actual pressure and
thermal temperature at the melt. Accounting for the role of the pressure
transmitting media in diamond anvil cell experiments, the analysis of elemental
vanadium melting curve is presented. It is shown that the appropriate
correction of shock waves melting data which takes into account the radiation
absorbed by the LiF window, applies only to vanadium metal. The correct
pressure scale of vanadium metal as derived by diamond anvil cell is presented.Comment: 17 pages, 4 figure
Revealing sub-{\mu}m inhomogeneities and {\mu}m-scale texture in H2O ice at Megabar pressures via sound velocity measurements by time-domain Brillouin scattering
Time-domain Brillouin scattering technique, also known as picosecond
ultrasonic interferometry, which provides opportunity to monitor propagation of
nanometers to sub-micrometers length coherent acoustic pulses in the samples of
sub-micrometers to tens of micrometers dimensions, was applied to
depth-profiling of polycrystalline aggregate of ice compressed in a diamond
anvil cell to Megabar pressures. The technique allowed examination of
characteristic dimensions of elastic inhomogeneities and texturing of
polycrystalline ice in the direction normal to the diamond anvil surfaces with
sub-micrometer spatial resolution via time-resolved measurements of variations
in the propagation velocity of the acoustic pulse traveling in the compressed
sample. The achieved two-dimensional imaging of the polycrystalline ice
aggregate in-depth and in one of the lateral directions indicates the
feasibility of three-dimensional imaging and quantitative characterization of
acoustical, optical and acousto-optical properties of transparent
polycrystalline aggregates in diamond anvil cell with tens of nanometers
in-depth resolution and lateral spatial resolution controlled by pump laser
pulses focusing.Comment: 32 pages, 5 figure
Potassium chlorate decomposition under high pressure
High pressure physics involves placing various substances under high pressure and observing changes in that substance. In this experiment this high amount of pressure is induced using a diamond anvil cell. A diamond anvil cell uses a metal gasket to hold the sample between two diamonds, which will press on the sample to reach high pressures. High pressures are reached with a moderate amount of force by exerting that force over a small area. Diamonds are used for the compression because of their hardness and ability to resist compression. The pressure being exerted on the sample using a diamond anvil cell is often measured using ruby fluorescence. The behavior of ruby under high pressure is well known so the pressure inside the diamond anvil cell can be determined by observing the ruby fluorescence. Ruby is placed inside the gasket along with the sample so that it is always at the same pressure as the sample. Potassium Chlorate is a chemical that is often used as an oxygen producer and as an explosive when mixed with other chemicals. It decomposes under heat to release oxygen gas, which is the reaction we are trying to induce by placing the chemical under pressure. When molecules heat up they begin to vibrate more rapidly and are more likely to collide with each other. When molecules undergo higher pressures they are also more likely to collide as atoms get closer together. The purpose of this experiment is to determine if pressure can induce the same reaction in Potassium Chlorate as heat
Equation of state of bismuth to 222 GPa and comparison of gold and platinum pressure scales to 145 GPa
The equation-of-state (EoS) of bcc-bismuth was determined using the Pt pressure scale. Unit cell volumes of Bi, Pt, and Au were also measured simultaneously to megabar pressures by X-ray powder diffraction using a diamond anvil cell and a synchronus radiation source. The results suggest that Au pressure scale gave lower pressure than the Pt pressure scale
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Phase transition kinetics revealed by <i>in situ</i> x-ray diffraction in laser-heated dynamic diamond anvil cells
We report successful coupling of dynamic loading in a diamond anvil cell and stable laser heating, which enables compression rates up to 500 GPa/s along high-temperature isotherms. Dynamic loading in a diamond-anvil cell allows exploration of a wider range of pathways in the pressure-temperature space compared to conventional dynamic compression techniques. By in situ x-ray diffraction, we are able to characterize and monitor the structural transitions with the appropriate time resolution i.e., millisecond timescales. Using this method, we investigate the γ−ε phase transition of iron under dynamic compression, reaching compression rates of hundreds of GPa/s and temperatures of 2000 K. Our results demonstrate a distinct response of the γ−ε and α− ε transitions to the high compression rates achieved, possibly due to the different transition mechanisms. These findings open up new avenues to study tailored dynamic compression pathways in the pressure-temperature space and highlight the potential of this platform to capture kinetic effects (over ms time scales) in a diamond anvil cell
Combining high pressure and coherent diffraction: a first feasibility test
We present a first experiment combining high pression and coherent X-ray
diffraction. By using a dedicated diamond anvil cell, we show that the degree
of coherence of the X-ray beam is preserved when the X-ray beam passes through
the diamond cell. This observation opens the possibility of studying the
dynamics of slow fluctuations under high pressure.Comment: 3 pages, 2 figures, GHPR 2009 conferenc
Isostructural Phase Transition of TiN Under High Pressure
In situ high-pressure energy dispersive x-ray diffraction experiments on
polycrystalline powder TiN with NaCl-type structure have been conducted with
the pressure up to 30.1 GPa by using the diamond anvil cell instrument with
synchrotron radiation at room tempearture. The experimental results suggested
that an isostructural phase transition might exist at about 7 GPa as revealed
by the discontinuity of V/V0 with pressure.Comment: submitte
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