323,635 research outputs found
High quality anti-relaxation coating material for alkali atom vapor cells
We present an experimental investigation of alkali atom vapor cells coated
with a high quality anti-relaxation coating material based on alkenes. The
prepared cells with single compound alkene based coating showed the longest
spin relaxation times which have been measured up to now with room temperature
vapor cells. Suggestions are made that chemical binding of a cesium atom and an
alkene molecule by attack to the C=C bond plays a crucial role in such
improvement of anti-relaxation coating quality
Broadband Relaxation-Optimized Polarization Transfer in Magnetic Resonance
Many applications of magnetic resonance are limited by rapid loss of spin
coherence caused by large transverse relaxation rates. In nuclear magnetic
resonance (NMR) of large proteins, increased relaxation losses lead to poor
sensitivity of experiments and increased measurement time. In this paper we
develop broadband relaxation optimized pulse sequences (BB-CROP) which approach
fundamental limits of coherence transfer efficiency in the presence of very
general relaxation mechanisms that include cross-correlated relaxation. These
broadband transfer schemes use new techniques of chemical shift refocusing
(STAR echoes) that are tailored to specific trajectories of coupled spin
evolution. We present simulations and experimental data indicating significant
enhancement in the sensitivity of multi-dimensional NMR experiments of large
molecules by use of these methods
Spin and density overlaps in the frustrated Ising lattice gas
We perform large scale simulations of the frustrated Ising lattice gas, a
three-dimensional lattice model of a structural glass, using the parallel
tempering technique. We evaluate the spin and density overlap distributions,
and the corresponding non-linear susceptibilities, as a function of the
chemical potential. We then evaluate the relaxation functions of the spin and
density self-overlap, and study the behavior of the relaxation times. The
results suggest that the spin variables undergo a transition very similar to
the one of the Ising spin glass, while the density variables do not show any
sign of transition at the same chemical potential. It may be that the density
variables undergo a transition at a higher chemical potential, inside the phase
where the spins are frozen.Comment: 7 pages, 10 figure
Effect of phase relaxation on quantum superpositions in complex collisions
We study the effect of phase relaxation on coherent superpositions of
rotating clockwise and anticlockwise wave packets in the regime of strongly
overlapping resonances of the intermediate complex. Such highly excited
deformed complexes may be created in binary collisions of heavy ions, molecules
and atomic clusters. It is shown that phase relaxation leads to a reduction of
the interference fringes, thus mimicking the effect of decoherence. This
reduction is crucial for the determination of the phase--relaxation width from
the data on the excitation function oscillations in heavy--ion collisions and
bimolecular chemical reactions. The difference between the effects of phase
relaxation and decoherence is discussed.Comment: Extended revised version; 9 pages and 3 colour ps figure
Relaxation of Chemical Reactions to Stationary States in the Chemical Affinities Space
Using the mass balance equations for chemical reactions, we show how the
system relaxes towards a steady state in and out of the Onsager region. In the
chemical affinities space, after fast transients, the relaxation process is a
straight line when operating in the Onsager region, while out of this regime,
the evolution of the system is such that the projections of the evolution
equations for the forces and the shortest path on the flows coincide. For
spatially-extended systems, similar results are valid for the evolution of the
thermodynamic mode (i.e., the mode with wave-number k = 0). These results allow
us to obtain the expression for the affine connection of the space covered by
the thermodynamic forces, close to the steady states. Through the affine
connection, the nonlinear closure equations are derived.Comment: 23 pages
Viscoelastic properties of addition-cured polyimides used in high temperature polymer matrix composites
Viscoelastic properties of the addition cured polyimide, PMR-15, were studied using dynamic mechanical and stress relaxation tests. For temperatures below the glass transition temperature, T sub g, the dynamic mechanical properties measured using a temperature scan rate of 10 C/min were strongly affected by the presence of absorbed moisture in the resin. Dynamic mechanical properties measured as a function of time during an isothermal hold provided an indication of chemical changes occurring in the resin. For temperatures above (T sub g + 20 C), the storage modulus increased continuously as a function of time indicating that additional crosslinking is occurring in the resin. Because of these changes in chemical structures, the stress relaxation modulus could not be measured over any useful time interval for temperatures above T sub g. For temperatures below T sub g, dynamic mechanical properties appeared to be unaffected by chemical changes for times exceeding 1 hr. Since the duration of the stress relaxation tests was less than 1 hr, the stress relaxation modulus could be measured. As long as the moisture content of the resin was less than 2 pct, stress relaxation curves measured at different temperatures could be superimposed using horizontal shifts along the log(time) axis with only small shifts along the vertical axis
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