221,913 research outputs found
Boron: a Hunt for Superhard Polymorphs
Boron is a unique element, being the only element, all known polymorphs of
which are superhard, and all of its crystal structures are distinct from any
other element. The electron-deficient bonding in boron explains its remarkable
sensitivity to even small concentrations of impurity atoms and allows boron to
form peculiar chemical compounds with very different elements. These
complications made the study of boron a great challenge, creating also a unique
and instructive chapter in the history of science. Strange though it may sound,
the discovery of boron in 1808 was ambiguous, with pure boron polymorphs
established only starting from the 1950s-1970s, and only in 2007 was the stable
phase at ambient conditions determined. The history of boron research from its
discovery to the latest discoveries pertaining to the phase diagram of this
element, the structure and stability of beta-boron, and establishment of a new
high-pressure polymorph, gamma-boron, is reviewed
Removal of Boron from aqueous solutions by adsorption using fly ash, zeolite and demineralized lignite
In the present study for the purpose of removal of boron from water by adsorption using adsorbents like fly ash, natural zeolite and demineralized lignite was investigated. Boron in water was removed with fly ash, zeolite and demineralized lignite with different capacities. 94% boron was removed using fly ash. Batch experiments were conducted to test removal capacity, to obtain adsorption isotherms, thermodynamic and kinetic parameters.
Boron removal by all adsorbents was affected by pH of solution; maximum adsorption was achieved at pH 10. Adsorption of boron on fly ash was investigated by Langmuir, Freundlich, Dubinin-Radushkevich models. Standard entropy and enthalpy changes of adsorption of boron on fly ash were, =S0 = -0.69 kJ/mol K and =H0 = -215.34 kJ/mol, respectively. The negative value of S0 indicated decreased randomness at the solid/solution interface during
the adsorption boron on the fly ash sample. Negative values of H0 showed the exothermic nature of the process. The negative values of G0 implied that the adsorption of boron on fly ash samples was spontaneous. Adsorption of boron on fly ash occurred with a pseudo-second order kinetic model, intraparticle diffusion of boron species had also some effect in adsorption kinetics
Boron Fullerenes: A First-Principles Study
A family of unusually stable boron cages was identified and examined using
first-principles local density functional method. The structure of the
fullerenes is similar to that of the B12 icosahedron and consists of six
crossing double-rings. The energetically most stable fullerene is made up of
180 boron atoms. A connection between the fullerene family and its precursors,
boron sheets, is made. We show that the most stable boron sheets are not
necessarily precursors of very stable boron cages. Our finding is a step
forward in the understanding of the structure of the recently produced boron
nanotubes.Comment: 10 pages, 4 figures, 1 tabl
Novel Precursors for Boron Nanotubes: The Competition of Two-Center and Three-Center Bonding in Boron Sheets
We present a new class of boron sheets, composed of triangular and hexagonal
motifs, that are more stable than structures considered to date and thus are
likely to be the precursors of boron nanotubes. We describe a simple and clear
picture of electronic bonding in boron sheets and highlight the importance of
three-center bonding and its competition with two-center bonding, which can
also explain the stability of recently discovered boron fullerenes. Our
findings call for reconsideration of the literature on boron sheets, nanotubes,
and clusters.Comment: 4 pages, 4 figures, 1 tabl
First Principles Simulations of Boron Diffusion in Graphite
Boron strongly modifies electronic and diffusion properties of graphite. We report the first ab initio study of boron interaction with the point defects in graphite, which includes structures, thermodynamics, and diffusion. A number of possible diffusion mechanisms of boron in graphite are suggested. We conclude that boron diffuses in graphite by a kick-out mechanism. This mechanism explains the common activation energy, but large magnitude difference, for the rate of boron diffusion parallel and perpendicular to the basal plane. © 2007 The American Physical Society
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