An MDP decomposition approach for traffic control at isolated signalized intersections

This article presents a novel approach for the dynamic control of a signalized intersection. At the intersection, there is a number of arrival flows of cars, each having a single queue (lane). The set of all flows is partitioned into disjoint combinations of nonconflicting flows that will receive green together. The dynamic control of the traffic lights is based on the numbers of cars waiting in the queues. The problem concerning when to switch (and which combination to serve next) is modeled as a Markovian decision process in discrete time. For large intersections (i.e., intersections with a large number of flows), the number of states becomes tremendously large, prohibiting straightforward optimization using value iteration or policy iteration. Starting from an optimal (or nearly optimal) fixed-cycle strategy, a one-step policy improvement is proposed that is easy to compute and is shown to give a close to optimal strategy for the dynamic proble

Theory of membrane capacitive deionization including the effect of the electrode pore space

Membrane capacitive deionization (MCDI) is a technology for water desalination based on applying an electrical field between two oppositely placed porous electrodes. Ions are removed from the water flowing through a channel in between the electrodes and are stored inside the electrodes. Ion-exchange membranes are placed in front of the electrodes allowing for counterion transfer from the channel into the electrode, while retaining the coions inside the electrode structure. We set up an extended theory for MCDI which includes in the description for the porous electrodes not only the electrostatic double layers (EDLs) formed inside the porous (carbon) particles, but also incorporates the role of the transport pathways in the electrode, i.e., the interparticle pore space. Because in MCDI the coions are inhibited from leaving the electrode region, the interparticle porosity becomes available as a reservoir to store salt, thereby increasing the total salt storage capacity of the porous electrode. A second advantage of MCDI is that during ion desorption (ion release) the voltage can be reversed. In that case the interparticle porosity can be depleted of counterions, thereby increasing the salt uptake capacity and rate in the next cycle. In this work, we compare both experimentally and theoretically adsorption/desorption cycles of MCDI for desorption at zero voltage as well as for reversed voltage, and compare with results for CDI. To describe the EDL-structure a novel modified Donnan model is proposed valid for small pores relative to the Debye length

All-optical coherent population trapping with defect spin ensembles in silicon carbide

Divacancy defects in silicon carbide have long-lived electronic spin states and sharp optical transitions, with properties that are similar to the nitrogen-vacancy defect in diamond. We report experiments on 4H-SiC that investigate all-optical addressing of spin states with the zero-phonon-line transitions. Our magneto-spectroscopy results identify the spin $S=1$ structure of the ground and excited state, and a role for decay via intersystem crossing. We use these results for demonstrating coherent population trapping of spin states with divacancy ensembles that have particular orientations in the SiC crystal.Comment: 28 page document: Pages 1-14 main text (with 3 figures); pages 15-28 supplementary information (with 5 figues). v2 has minor correction

Two-laser dynamic nuclear polarization with semiconductor electrons:Feedback, suppressed fluctuations, and bistability near two-photon resonance

Feedback control is a powerful tool to stabilize systems for which precision control is difficult to impose directly, such as the environment of an open quantum system. Reduction of noise from the environment is a major challenge on the road to harnessing delicate quantum effects such as superposition and entanglement. In particular, spin states of defects and quantum dots in semiconductors display promising coherence properties for future applications, often being limited by disturbance from disordered nuclear spins in their environment. Here we show how optical coherent population trapping (CPT) of the spin of localized semiconductor electrons stabilizes the surrounding nuclear spins via feedback control. We find distinct control regimes for different signs of laser detuning and examine the transition from an unpolarized, narrowed state to a polarized state possessing a bistability. The narrowing of the state protects the electron spin against dephasing and yields self-improving CPT. Our analysis is relevant for a variety of solid-state systems where hyperfine-induced dephasing is a limitation for using electron spin coherence

Snow cover, freeze-thaw, and the retention of nutrients in an oceanic mountain ecosystem

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