203,453 research outputs found
Effect of distribution of stickers along backbone on temperature-dependent structural properties in associative polymer solutions
Effect of distribution of stickers along the backbone on structural
properties in associating polymer solutions is studied using self-consistent
field lattice model. Only two inhomogeneous morphologies, i.e.,
microfluctuation homogenous (MFH) and micelle morphologies, are observed. If
the system is cooled, the solvent content within the aggregates decreases. When
the spacing of stickers along the backbone is increased the
temperature-dependent range of aggregation in MFH morphology and half-width of
specific heat peak for homogenous solutions-MFH transition increase, and the
symmetry of the peak decreases. However, with increasing spacing of stickers,
the above three corresponding quantities related to micelles behave
differently. It is demonstrated that the broad nature of the observed
transitions can be ascribed to the structural changes which accompany the
replacement of solvents in aggregates by polymer, which is consistent with the
experimental conclusion. It is found that different effect of spacing of
stickers on the two transitions can be interpreted in terms of intrachain and
interchain associations.Comment: 10 pages, 4 figures. arXiv admin note: text overlap with
arXiv:1202.459
Possible and Molecular states in a chiral quark model
We perform a systematic study of the bound state problem of and
systems by using effective interaction in our chiral quark model.
Our results show that both the interactions of and states
are attractive, which consequently result in
and bound states.Comment: arXiv admin note: substantial text overlap with arXiv:1204.395
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