1,226 research outputs found

    Synthesis of ultrathin platinum nanoplates for enhanced oxygen reduction activity.

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    Ultrathin Pt nanostructures exposing controlled crystal facets are highly desirable for their superior activity and cost-effectiveness in the electrocatalytic oxygen reduction reaction (ORR), and they are conventionally synthesized by epitaxial growth of Pt on a limited range of templates, such as Pd nanocrystals, resulting in a high cost and less structural diversity of the ultrathin Pt nanostructures. To solve this problem, we demonstrate that ultrathin Pt nanostructures can be synthesized by templating conveniently available Ag nanocrystals without involving galvanic replacement, which enables a much-reduced cost and controllable new morphologies, such as ultrathin Pt nanoplates that expose the {111} facets. The resulting ultrathin Pt nanoplates are ∼1-2 nm in thickness, which show an ∼22-fold increase in specific activity (5.3 mA cm-2), an ∼9.5-fold increase in mass activity (1.62 A mg-1) and significantly enhanced catalytic stability in the ORR, compared with the commercial Pt/C catalyst. We believe this strategy opens a door to a highly extendable family of ultrathin noble metal nanostructures, thus promising excellent activity and stability in a broad range of catalytic applications

    On a diffuse interface model for incompressible viscoelastic two-phase flows

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    This paper concerns a diffuse interface model for the flow of two incompressible viscoelastic fluids in a bounded domain. More specifically, the fluids are assumed to be macroscopically immiscible, but with a small transition region, where the two components are partially mixed. Considering the elasticity of both components, one ends up with a coupled Oldroyd-B/Cahn--Hilliard type system, which describes the behavior of two-phase viscoelastic fluids. We prove the existence of weak solutions to the system in two dimensions for general (unmatched) mass densities, variable viscosities, different shear moduli, and a class of physically relevant and singular free energy densities that guarantee that the order parameter stays in the physically reasonable interval. The proof relies on a combination of a novel regularization of the original system and a new hybrid implicit time discretization for the regularized system together with the analysis of an Oldroyd-B type equation.Comment: 52 pages. Comments are welcome

    Low Mach Number Limit of a Diffuse Interface Model for Two-Phase Flows of Compressible Viscous Fluids

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    In this paper, we consider a singular limit problem for a diffuse interface model for two immiscible compressible viscous fluids. Via a relative entropy method, we obtain a convergence result for the low Mach number limit to a corresponding system for incompressible fluids in the case of well-prepared initial data and same densities in the limit.Comment: 15 page

    Algorithms for Object Detection in Substations

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    Inspection of high-voltage power equipment is an effective way to ensure power supply reliability. Object recognition, one of the key technologies in automatic power equipment inspection, attracts attention of many researchers and engineers. Although quite a few existing models have some their own advantages, object relationship between equipment which is very important in this task is scarcely considered. This paper combining object relationship modeling and Transformer Model proposes a Relation Transformer Model. It has four parts -- backbone, encoder, decoder and prediction heads. With this structure, the proposed method shows in experiments a much better performance than other three commonly used models in object recognition in substation, largely promoting the development of automatic power equipment inspection
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