80 research outputs found
Additional file 1: Figure S1. a of A Resumable Fluorescent Probe BHN-Fe3O4@SiO2 Hybrid Nanostructure for Fe3+ and its Application in Bioimaging
Magnetization curve of BHN-Fe3O4@SiO2. b UV-Vis spectra of BHN-IPTES, Fe3O4@SiO2, and BHN-Fe3O4@SiO2. (PDF 57 kb
Flow chart from the identification of studies.
<p><b>LC, leptin concentration.</b></p
<i>r</i> between LC and age in PW in the included studies.
*<p>N: no correction.</p
Forest plot indicating the <i>r</i> between LC and body mass index (BMI) of postmenopausal women (PW).
<p>Horizontal lines denote 95% confidence interval (CIs); the diamond indicates the combined r with the corresponding 95% CI.</p
Inhibition of Marine Biofouling by Use of Degradable and Hydrolyzable Silyl Acrylate Copolymer
Silyl
acrylate copolymers are promising materials for marine antibiofouling.
However, their structures need optimizing to improve their erosion
and mechanical properties. We have prepared copolymer of 2-methylene-1,3-dioxepane
(MDO), tributylsilyl methacrylate (TBSM) and methyl methacrylate (MMA)
via radical ring-opening copolymerization. Such polymer has a degradable
backbone and hydrolyzable side groups. Our study demonstrates that
as the ester units in the backbone increase, the degradation rate
increases but the swelling decreases in seawater. The degradation
is controlled by the polymer composition or the molar ratio of the
ester units in the backbone to the silyl ester side groups. Moreover,
such polymer can serve as a carrier and controlled release system
for organic antifoulants. Marine field tests show that the system
consisting of the copolymer and organic antifoulant has good antifouling
performance depending on the polymer composition. It can effectively
inhibit the colonization and growth of marine organisms when MDO content
is above 20 wt %
Understanding the Formation of Pentagonal Cyclic Twinned Crystal from the Solvent Dependent Assembly of Au Nanocrystals into Their Colloidal Crystals
Due
to the presence of high-density twinned-defects and diffuse
elastic strain, pentagonal cyclic twinning (PCT) structures may have
more fascinating properties than the corresponding single crystalline
structure. Although there are a lot of reports concerning the PCT
nanocrystals of many monometals and bimetal alloys, the established
growth mechanisms of PCT structures are still not straightforward
and usually inconsistent with each other. In this Letter, using dodecanethiol-capped
Au nanocrystals (NCs) as building blocks, taking self-assembly of
Au NCs into their colloidal crystals as the crystallization model,
we found the competition of crystal cohesive energy and surface free
energy plays an important role in the formation of PCT colloidal crystal.
By rationally selecting the solvent to tailor the crystal cohesive
energy, the structure of the colloidal crystals can be tuned. PCT
structures are more likely to form when the interaction between building
blocks is weak, while the single crystal structure is formed when
the interaction is strong. The results demonstrate that the thermodynamic
factors are the origin of pentagonal cyclic twinning
Facile Synthesis of Molecularly Imprinted Graphene Quantum Dots for the Determination of Dopamine with Affinity-Adjustable
A facilely prepared fluorescence
sensor was developed for dopamine (DA) determination based on polyindole/graphene
quantum dots molecularly imprinted polymers (PIn/GQDs@MIPs). The proposed
sensor exhibits a high sensitivity with a linear range of 5 ×
10<sup>–10</sup> to 1.2 × 10<sup>–6</sup> M and
the limit of detection as low as 1 × 10<sup>–10</sup> M
in the determination of DA, which is probably due to the tailor-made
imprinted cavities for binding DA thought hydrogen bonds between amine
groups of DA and oxygen-containing groups of the novel composite.
Furthermore, the prepared sensor can rebind DA in dual-type: a low
affinity type (noncovalent interaction is off) and a high affinity
type (noncovalent interaction is on), and the rebinding interaction
can be adjusted by tuning the pH, which shows a unique potential for
adjusting the binding interaction while keeping the specificity, allowing
for wider applications
Range of LCs of PW in the included studies.
<p>Range of LCs of PW in the included studies.</p
LC in healthy PW and HRT users in the included studies.
*<p>N: no difference.</p
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