Improved high-temperature resistant matrix resins

A study was performed with the objective of developing matrix resins that exhibit improved thermo-oxidative stability over state-of-the-art high temperature resins for use at temperatures up to 644 K (700 F) and air pressures up to 0.7 MPa (100 psia). The work was based upon a TRW discovered family of polyimides currently licensed to and marketed by Ethyl Corporation as EYMYD(R) resins. The approach investigated to provide improved thermo-oxidative properties was to use halogenated derivatives of the diamine, 2, 2-bis (4-(4-aminophenoxy)phenyl) hexafluoropropane (4-BDAF). Polyimide neat resins and Celion(R) 12,000 composites prepared from fluorine substituted 4-BDAF demonstrated unexpectedly lower glass transition temperatures (Tg) and thermo-oxidative stabilities than the baseline 4-BDAF/PMDA polymer

Search For Unresolved Sources In The COBE-DMR Two-Year Sky Maps

We have searched the temperature maps from the COBE Differential Microwave Radiometers (DMR) first two years of data for evidence of unresolved sources. The high-latitude sky (|b| > 30\deg) contains no sources brighter than 192 uK thermodynamic temperature (322 Jy at 53 GHz). The cumulative count of sources brighter than threshold T, N(> T), is consistent with a superposition of instrument noise plus a scale-invariant spectrum of cosmic temperature fluctuations normalized to Qrms-PS = 17 uK. We examine the temperature maps toward nearby clusters and find no evidence for any Sunyaev-Zel'dovich effect, \Delta y < 7.3 x 10^{-6} (95% CL) averaged over the DMR beam. We examine the temperature maps near the brightest expected radio sources and detect no evidence of significant emission. The lack of bright unresolved sources in the DMR maps, taken with anisotropy measurements on smaller angular scales, places a weak constraint on the integral number density of any unresolved Planck-spectrum sources brighter than flux density S, n(> S) < 2 x 10^4 (S/1 Jy)^{-2} sr^{-1}.Comment: 16 pages including 2 figures, uuencoded PostScript, COBE preprint 94-0

Signal-to-Noise Eigenmode Analysis of the Two-Year COBE Maps

To test a theory of cosmic microwave background fluctuations, it is natural to expand an anisotropy map in an uncorrelated basis of linear combinations of pixel amplitudes --- statistically-independent for both the noise and the signal. These $S/N$-eigenmodes are indispensible for rapid Bayesian analyses of anisotropy experiments, applied here to the recently-released two-year COBE {\it dmr} maps and the {\it firs} map. A 2-parameter model with an overall band-power and a spectral tilt $\nu_{\Delta T}$ describes well inflation-based theories. The band-powers for {\it all} the {\it dmr} $53,90,31$ $a$+$b$ GHz and {\it firs} 170 GHz maps agree, $\{(1.1\pm 0.1)\times 10^{-5}\}^{1/2}$, and are largely independent of tilt and degree of (sharp) $S/N$-filtering. Further, after optimal $S/N$-filtering, the {\it dmr} maps reveal the same tilt-independent large scale features and correlation function. The unfiltered {\it dmr} $53$ $a$+$b$ index $\nu_{\Delta T}+1$ is $1.4\pm 0.4$; increasing the $S/N$-filtering gives a broad region at (1.0--1.2)$\pm$0.5, a jump to (1.4--1.6)$\pm$0.5, then a drop to 0.8, the higher values clearly seen to be driven by $S/N$-power spectrum data points that do not fit single-tilt models. These indices are nicely compatible with inflation values ($\sim$0.8--1.2), but not overwhelmingly so.Comment: submitted to Phys.Rev.Letters, 4 pages, uuencoded compressed PostScript; also bdmr2.ps.Z, via anonymous ftp to ftp.cita.utoronto.ca, cd to /pub/dick/yukawa; CITA-94-2

Angular Power Spectrum of the Microwave Background Anisotropy seen by the COBE Differential Microwave Radiometer

The angular power spectrum estimator developed by Peebles (1973) and Hauser & Peebles (1973) has been modified and applied to the 4 year maps produced by the COBE DMR. The power spectrum of the observed sky has been compared to the power spectra of a large number of simulated random skies produced with noise equal to the observed noise and primordial density fluctuation power spectra of power law form, with $P(k) \propto k^n$. The best fitting value of the spectral index in the range of spatial scales corresponding to spherical harmonic indices $3 \leq \ell \lesssim 30$ is an apparent spectral index $n_{app}$ = 1.13 (+0.3) (-0.4) which is consistent with the Harrison-Zel'dovich primordial spectral index $n_{pri} = 1$ The best fitting amplitude for $n_{app} = 1$ is $\langle Q_{RMS}^2\rangle^{0.5}$ = 18 uK.Comment: 17 pages including 3 PostScript figures. Submitted to The Astrophysical Journal (Letters

Power Spectrum of Primordial Inhomogeneity Determined from the 4-Year COBE DMR Sky Maps

Fourier analysis and power spectrum estimation of the cosmic microwave background anisotropy on an incompletely sampled sky developed by Gorski (1994) has been applied to the high-latitude portion of the 4-year COBE DMR 31.5, 53 and 90 GHz sky maps. Likelihood analysis using newly constructed Galaxy cuts (extended beyond |b| = 20deg to excise the known foreground emission) and simultaneously correcting for the faint high latitude galactic foreground emission is conducted on the DMR sky maps pixelized in both ecliptic and galactic coordinates. The Bayesian power spectrum estimation from the foreground corrected 4-year COBE DMR data renders n ~ 1.2 +/- 0.3, and Q_{rms-PS} ~ 15.3^{+3.7}_{-2.8} microK (projections of the two-parameter likelihood). These results are consistent with the Harrison-Zel'dovich n=1 model of amplitude Q_{rms-PS} ~ 18 microK detected with significance exceeding 14sigma (dQ/Q < 0.07). (A small power spectrum amplitude drop below the published 2-year results is predominantly due to the application of the new, extended Galaxy cuts.)Comment: 9 pages of text in LaTeX, 1 postscript Table, 4 postscript figures (2 color plates), submitted to The Astrophysical Journal (Letters

2-Point Correlations in the COBE DMR 4-Year Anisotropy Maps

The 2-point temperature correlation function is evaluated from the 4-year COBE DMR microwave anisotropy maps. We examine the 2-point function, which is the Legendre transform of the angular power spectrum, and show that the data are statistically consistent from channel to channel and frequency to frequency. The most likely quadrupole normalization is computed for a scale-invariant power-law spectrum of CMB anisotropy, using a variety of data combinations. For a given data set, the normalization inferred from the 2-point data is consistent with that inferred by other methods. The smallest and largest normalization deduced from any data combination are 16.4 and 19.6 uK respectively, with a value ~18 uK generally preferred.Comment: Sumbitted to ApJ Letter

Measuring patient-perceived quality of care in US hospitals using Twitter

BACKGROUND: Patients routinely use Twitter to share feedback about their experience receiving healthcare. Identifying and analysing the content of posts sent to hospitals may provide a novel real-time measure of quality, supplementing traditional, survey-based approaches. OBJECTIVE: To assess the use of Twitter as a supplemental data stream for measuring patient-perceived quality of care in US hospitals and compare patient sentiments about hospitals with established quality measures. DESIGN: 404 065 tweets directed to 2349 US hospitals over a 1-year period were classified as having to do with patient experience using a machine learning approach. Sentiment was calculated for these tweets using natural language processing. 11 602 tweets were manually categorised into patient experience topics. Finally, hospitals with ≥50 patient experience tweets were surveyed to understand how they use Twitter to interact with patients. KEY RESULTS: Roughly half of the hospitals in the US have a presence on Twitter. Of the tweets directed toward these hospitals, 34 725 (9.4%) were related to patient experience and covered diverse topics. Analyses limited to hospitals with ≥50 patient experience tweets revealed that they were more active on Twitter, more likely to be below the national median of Medicare patients (p<0.001) and above the national median for nurse/patient ratio (p=0.006), and to be a non-profit hospital (p<0.001). After adjusting for hospital characteristics, we found that Twitter sentiment was not associated with Hospital Consumer Assessment of Healthcare Providers and Systems (HCAHPS) ratings (but having a Twitter account was), although there was a weak association with 30-day hospital readmission rates (p=0.003). CONCLUSIONS: Tweets describing patient experiences in hospitals cover a wide range of patient care aspects and can be identified using automated approaches. These tweets represent a potentially untapped indicator of quality and may be valuable to patients, researchers, policy makers and hospital administrators

Effect of next-nearest neighbor coupling on the optical spectra in bilayer graphene

We investigate the dependence of the optical conductivity of bilayer graphene (BLG) on the intra- and inter-layer interactions using the most complete model to date. We show that the next nearest-neighbor intralayer coupling introduces new features in the low-energy spectrum that are highly sensitive to sample doping, changing significantly the ``universal'' conductance. Further, its interplay with interlayer couplings leads to an anisotropy in conductance in the ultraviolet range. We propose that experimental measurement of the optical conductivity of intrinsic and doped BLG will provide a good benchmark for the relative importance of intra- and inter-layer couplings at different doping levels.Comment: 5 pages, 5 figure

Sky maps without anisotropies in the cosmic microwave background are a better fit to WMAP's uncalibrated time ordered data than the official sky maps

The purpose of this reanalysis of the WMAP uncalibrated time ordered data (TOD) was two fold. The first was to reassess the reliability of the detection of the anisotropies in the official WMAP sky maps of the cosmic microwave background (CMB). The second was to assess the performance of a proposed criterion in avoiding systematic error in detecting a signal of interest. The criterion was implemented by testing the null hypothesis that the uncalibrated TOD was consistent with no anisotropies when WMAP's hourly calibration parameters were allowed to vary. It was shown independently for all 20 WMAP channels that sky maps with no anisotropies were a better fit to the TOD than those from the official analysis. The recently launched Planck satellite should help sort out this perplexing result.Comment: 11 pages with 1 figure and 2 tables. Extensively rewritten to explain the research bette