170 research outputs found
Mechanistic Analysis of Gold(I)-Catalyzed Intramolecular Allene Hydroalkoxylation Reveals an Off-Cycle Bis(gold) Vinyl Species and Reversible CâO Bond Formation
Mechanistic investigation of gold(I)-catalyzed intramolecular allene hydroalkoxylation established a mechanism involving rapid and reversible CâO bond formation followed by turnover-limiting protodeauration from a mono(gold) vinyl complex. This on-cycle pathway competes with catalyst aggregation and formation of an off-cycle bis(gold) vinyl complex
Mechanistic Studies of Ethylene Hydrophenylation Catalyzed by Bipyridyl Pt(II) Complexes
This article discusses mechanistic studies of ethylene hydrophenylation catalyzed by bipyridyl Pt(II) complexes
Arylpalladium Phosphonate Complexes as Reactive Intermediates in PhosphorusâCarbon Bond Forming Reactions
Room Temperature Hydroamination of Alkynes Catalyzed by Gold Clusters in Interfacially Cross-Linked Reverse Micelles
Use of Pentamethyldisiloxane in the Palladium-Catalyzed Cyclization/Hydrosilylation of Functionalized Dienes
Investigations on GoldâCatalyzed Thioalkyne Activation Toward Facile Synthesis of Ketene Dithioacetals
PhotoâOrganocatalytic Enantioselective Radical Cascade Enabled by SingleâElectron Transfer Activation of Allenes
Mechanistic Analysis of Gold(I)-Catalyzed Intramolecular Allene Hydroalkoxylation Reveals an Off-Cycle Bis(gold) Vinyl Species and Reversible CâO Bond Formation
Mechanistic investigation of goldÂ(I)-catalyzed intramolecular
allene
hydroalkoxylation established a mechanism involving rapid and reversible
CâO bond formation followed by turnover-limiting protodeauration
from a monoÂ(gold) vinyl complex. This on-cycle pathway competes with
catalyst aggregation and formation of an off-cycle bisÂ(gold) vinyl
complex
Mechanistic Analysis of Gold(I)-Catalyzed Intramolecular Allene Hydroalkoxylation Reveals an Off-Cycle Bis(gold) Vinyl Species and Reversible CâO Bond Formation
Mechanistic investigation of goldÂ(I)-catalyzed intramolecular
allene
hydroalkoxylation established a mechanism involving rapid and reversible
CâO bond formation followed by turnover-limiting protodeauration
from a monoÂ(gold) vinyl complex. This on-cycle pathway competes with
catalyst aggregation and formation of an off-cycle bisÂ(gold) vinyl
complex
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