The Role of Order–Disorder Transitions in the Quest for Molecular Multiferroics: Structural and Magnetic Neutron Studies of a Mixed Valence Iron(II)–Iron(III) Formate Framework

Neutron diffraction studies have been carried out to shed light on the unprecedented order–disorder phase transition (ca. 155 K) observed in the mixed-valence iron­(II)–iron­(III) formate framework compound [NH₂(CH₃)₂]_<i>n</i>[Fe^IIIFe^II(HCOO)₆]_<i>n</i>. The crystal structure at 220 K was first determined from Laue diffraction data, then a second refinement at 175 K and the crystal structure determination in the low temperature phase at 45 K were done with data from the monochromatic high resolution single crystal diffractometer D19. The 45 K nuclear structure reveals that the phase transition is associated with the order–disorder of the dimethylammonium counterion that is weakly anchored in the cavities of the [Fe^IIIFe^II(HCOO)₆]_<i>n</i> framework. In the low-temperature phase, a change in space group from <i>P</i>3̅1<i>c</i> to <i>R</i>3̅<i>c</i> occurs, involving a tripling of the <i>c</i>-axis due to the ordering of the dimethylammonium counterion. The occurrence of this nuclear phase transition is associated with an electric transition, from paraelectric to antiferroelectric. A combination of powder and single crystal neutron diffraction measurements below the magnetic order transition (ca. 37 K) has been used to determine unequivocally the magnetic structure of this Néel N-Type ferrimagnet, proving that the ferrimagnetic behavior is due to a noncompensation of the different Fe^II and Fe^III magnetic moments

The Role of Order–Disorder Transitions in the Quest for Molecular Multiferroics: Structural and Magnetic Neutron Studies of a Mixed Valence Iron(II)–Iron(III) Formate Framework

Neutron diffraction studies have been carried out to shed light on the unprecedented order–disorder phase transition (ca. 155 K) observed in the mixed-valence iron­(II)–iron­(III) formate framework compound [NH₂(CH₃)₂]_<i>n</i>[Fe^IIIFe^II(HCOO)₆]_<i>n</i>. The crystal structure at 220 K was first determined from Laue diffraction data, then a second refinement at 175 K and the crystal structure determination in the low temperature phase at 45 K were done with data from the monochromatic high resolution single crystal diffractometer D19. The 45 K nuclear structure reveals that the phase transition is associated with the order–disorder of the dimethylammonium counterion that is weakly anchored in the cavities of the [Fe^IIIFe^II(HCOO)₆]_<i>n</i> framework. In the low-temperature phase, a change in space group from <i>P</i>3̅1<i>c</i> to <i>R</i>3̅<i>c</i> occurs, involving a tripling of the <i>c</i>-axis due to the ordering of the dimethylammonium counterion. The occurrence of this nuclear phase transition is associated with an electric transition, from paraelectric to antiferroelectric. A combination of powder and single crystal neutron diffraction measurements below the magnetic order transition (ca. 37 K) has been used to determine unequivocally the magnetic structure of this Néel N-Type ferrimagnet, proving that the ferrimagnetic behavior is due to a noncompensation of the different Fe^II and Fe^III magnetic moments

The Role of Order–Disorder Transitions in the Quest for Molecular Multiferroics: Structural and Magnetic Neutron Studies of a Mixed Valence Iron(II)–Iron(III) Formate Framework

Neutron diffraction studies have been carried out to shed light on the unprecedented order–disorder phase transition (ca. 155 K) observed in the mixed-valence iron­(II)–iron­(III) formate framework compound [NH₂(CH₃)₂]_<i>n</i>[Fe^IIIFe^II(HCOO)₆]_<i>n</i>. The crystal structure at 220 K was first determined from Laue diffraction data, then a second refinement at 175 K and the crystal structure determination in the low temperature phase at 45 K were done with data from the monochromatic high resolution single crystal diffractometer D19. The 45 K nuclear structure reveals that the phase transition is associated with the order–disorder of the dimethylammonium counterion that is weakly anchored in the cavities of the [Fe^IIIFe^II(HCOO)₆]_<i>n</i> framework. In the low-temperature phase, a change in space group from <i>P</i>3̅1<i>c</i> to <i>R</i>3̅<i>c</i> occurs, involving a tripling of the <i>c</i>-axis due to the ordering of the dimethylammonium counterion. The occurrence of this nuclear phase transition is associated with an electric transition, from paraelectric to antiferroelectric. A combination of powder and single crystal neutron diffraction measurements below the magnetic order transition (ca. 37 K) has been used to determine unequivocally the magnetic structure of this Néel N-Type ferrimagnet, proving that the ferrimagnetic behavior is due to a noncompensation of the different Fe^II and Fe^III magnetic moments