Numerical and theoretical models to predict fatigue life in aggressive environments from experimental data

Corrosion fatigue produce sensible effects in the fracture mechanics of structural materials. Aggressive environments in presence of dynamic fatigue load are indeed responsible of multiple effects, regarding crack nucleation and propagation rates. Considering Ti-6Al-4V in air, inert paraffin oil and 3.5 wt.% NaCl mixture, environmental effects are sensible in terms of acceleration of Fatigue Crack Growth Rate – i.e. da/dN vs. stress intensity factor ΔK. Several literature studies dealt with the topic in the past years. However, research has been focused mainly on the FCGR description, and the prediction of number of cycles to failure in aggressive environments is not addressed. In the presented poster, a methodology to obtain a numeric model which reconstruct da/dN vs ΔK from experimental results, including crack length and applied stress, is presented and compared against literature data. Results are related to R = 0.1 axial test involving smooth and notched flat dogbone specimens, with varying notch radius. The proposed model is used to reconstruct the number of cycles to failure of the tested specimens, resulting in a satisfactory correlation with experimental data. Comparison with other literature models highlights the necessity to develop a proper numerical model with each test case. Please click Additional Files below to see the full abstract

Impacts of microalgae pre-treatments for improved anaerobic digestion: Thermal treatment, thermal hydrolysis, ultrasound and enzymatic hydrolysis

Anaerobic digestion (AD) of microalgae is primarily inhibited by the chemical composition of their cell walls containing biopolymers able to resist bacterial degradation. Adoption of pre-treatments such as thermal, thermal hydrolysis, ultrasound and enzymatic hydrolysis have the potential to remove these inhibitory compounds and enhance biogas yields by degrading the cell wall, and releasing the intracellular algogenic organic matter (AOM). This work investigated the effect of four pre-treatments on three microalgae species, and their impact on the quantity of soluble biomass released in the media and thus on the digestion process yields. The analysis of the composition of the soluble COD released and of the TEM images of the cells showed two main degradation actions associated with the processes: (1) cell wall damage with the release of intracellular AOM (thermal, thermal hydrolysis and ultrasound) and (2) degradation of the cell wall constituents with the release of intracellular AOM and the solubilisation of the cell wall biopolymers (enzymatic hydrolysis). As a result of this, enzymatic hydrolysis showed the greatest biogas yield increments (>270%) followed by thermal hydrolysis (60–100%) and ultrasounds (30–60%)

Influence of microalgal N and P composition on wastewater nutrient remediation

Microalgae have demonstrated the ability to remediate wastewater nutrients efficiently, with methods to further enhance performance through species selection and biomass concentration. This work evaluates a freshwater species remediation characteristics through analysis of internal biomass N:P (nitrogen:phosphorus) and presents a relationship between composition and nutrient uptake ability to assist in species selection. Findings are then translated to an optimal biomass concentration, achieved through immobilisation enabling biomass intensification by modifying bead concentration, for wastewaters of differing nutrient concentrations at hydraulic retention times (HRT) from 3 h to 10 d. A HRT <20 h was found suitable for the remediation of secondary effluent by immobilised Scenedesmus obliquus and Chlorella vulgaris at bead concentrations as low as 3.2 and 4.4 bead·mL−1. Increasing bead concentrations were required for shorter HRTs with 3 h possible at influent concentrations <5 mgP L−1

A numerical model to assess the role of crack-tip hydrostatic stress and plastic deformation in Environmental Assisted Fatigue Cracking

To better understand the mechanics of environmentally assisted cracking, and particularly hydrogen embrittlement, a correct description of the hydrostatic stress field is indispensable. The concentration of hydrogen in the proximity of the crack tip is indeed dependent of the hydrostatic stress effect on the microstructural lattice of the material. The overall parameters of the hydrostatic stress, including peak value, its location, gradient and distribution size are fundamental to assess the effect on hydrogen distribution near the crack tip. H concentration show indeed an exponential dependence on hydrostatic stress, so that even a moderate increase in the applied stress is traduced in a dramatic rise of hydrogen concentration. In order to investigate the mechanism beneath hydrogen embrittlement, a proper modelling of the hydrostatic stress is mandatory. Moreover, strain hardening might significantly interfere with the actual stress distribution, thus becoming a relevant parameter. The stress and strain field is also deeply affected by the presence of sharp notches. In the present work, a detailed Finite Element model, based on actual fatigue testing of notched Ti-6Al-4V specimens is proposed, providing a deeply informative tool to assess the hydrostatic stress and the plastic strain in the proximity of the crack tip. The data from the model are compared to available results and experiences in literature. Please click Additional Files below to see the full abstract

Design study of a photon beamline for a soft X-ray FEL driven by high gradient acceleration at EuPRAXIA@SPARC_LAB

We are proposing a facility based on high gradient acceleration via x-band RF structures and plasma acceleration. We plan to reach an electron energy of the order of 1 GeV, suitable to drive a Free Electron Laser for applications in the so called "water window" (2 - 4 nm). A conceptual design of the beamline, from the photon beam from the undulators to the user experimental chamber, mainly focusing on diagnostic, manipulation and transport of the radiation is presented and discussed. We also briefly outline a user end station for coherent imaging, laser ablation and pump-probe experiments

"Electro-clinical Syndromes" with onset in Paediatric Age. the highlights of the clinical-EEG, genetic and therapeutic advances

The genetic causes underlying epilepsy remain largely unknown, and the impact of available genetic data on the nosology of epilepsy is still limited. Thus, at present, classification of epileptic disorders should be mainly based on electroclinical features. Electro-clinical syndrome is a term used to identify a group of clinical entities showing a cluster of electro-clinical characteristics, with signs and symptoms that together define a distinctive, recognizable, clinical disorder. These often become the focus of treatment trials as well as of genetic, neuropsychological, and neuroimaging investigations. They are distinctive disorders identifiable on the basis of a typical age onset, specific EEG characteristics, seizure types, and often other features which, when taken together, permit a specific diagnosis which, in turn, often has implications for treatment, management, and prognosis. Each electro-clinical syndrome can be classified according to age at onset, cognitive and developmental antecedents and consequences, motor and sensory examinations, EEG features, provoking or triggering factors, and patterns of seizure occurrence with respect to sleep. Therefore, according to the age at onset, here we review the more frequently observed paediatric electro-clinical syndrome from their clinical-EEG, genetic and therapeutic point of views

Testing BSM Physics with Gravitational Waves

The Cosmic Gravitational Wave Background (CGWB) is an irreducible background of gravitational waves generated by particle exchange in the early Universe plasma. Standard Model particles contribute to such a stochastic background with a peak at $f\sim 80$ GHz. Any physics beyond the Standard Model (BSM) may modify the CGWB spectrum, making it a potential testing ground for BSM physics. We consider the impact of general BSM scenarios on the CGWB, including an arbitrary number of hidden sectors. We find that the largest amplitude of the CGWB comes from the sector that dominates the energy density after reheating and confirm the dominance of the SM for standard cosmological histories. For non-standard cosmological histories, such as those with a stiff equation of state $\omega >1/3$, like in kination, BSM physics may dominate and modify the spectrum substantially. We conclude that, if the CGWB is detected at lower frequencies and amplitudes compared to that of the SM, it will hint at extra massive degrees of freedom or hidden sectors. If it is instead measured at higher values, it will imply a period with $\omega >1/3$. We argue that for scenarios with periods of kination in the early Universe, a significant fraction of the parameter space can be ruled out from dark radiation bounds at BBN.Comment: 16 pages + appendix, 7 figures v2: minor edits, references added. Matches published versio

The impacts of replacing air bubbles with microspheres for the clarification of algae from low cell-density culture

Dissolved Air Flotation (DAF) is a well-known coagulation–flotation system applied at large scale for microalgae harvesting. Compared to conventional harvesting technologies DAF allows high cell recovery at lower energy demand. By replacing microbubbles with microspheres, the innovative Ballasted Dissolved Air Flotation (BDAF) technique has been reported to achieve the same algae cell removal efficiency, while saving up to 80% of the energy required for the conventional DAF unit. Using three different algae cultures (Scenedesmus obliquus, Chlorella vulgaris and Arthrospira maxima), the present work investigated the practical, economic and environmental advantages of the BDAF system compared to the DAF system. 99% cells separation was achieved with both systems, nevertheless, the BDAF technology allowed up to 95% coagulant reduction depending on the algae species and the pH conditions adopted. In terms of floc structure and strength, the inclusion of microspheres in the algae floc generated a looser aggregate, showing a more compact structure within single cell alga, than large and filamentous cells. Overall, BDAF appeared to be a more reliable and sustainable harvesting system than DAF, as it allowed equal cells recovery reducing energy inputs, coagulant demand and carbon emissions

In-111 octreotide SPECT/CT in the early diagnosis of pulmonary sarcoidosis: A case report

Sarcoidosis is a granulomatous disease of unknown etiology. At present the best diagnostic imaging procedure to assess stage and activity of sarcoidosis is controversial. We report the case of a 50-year-old male admitted with a history of dyspnea and fatigue with past medical history negative for smoking, occupational and environmental risk factors. Physical examination, routine blood tests, and pulmonary function tests were normal except for hypercalciuria. A chest radiograph showed bilateral hilar lymphadenopathy. Single photon emission computed tomography and/or computed tomography (SPECT and/or CT) In-111 Octreotide (Octreoscan) scintigraphy confirmed morphologic involvement of bilateral hilar lymph nodes and a mediastinoscopy biopsy specimen provided diagnosis of pulmonary sarcoidosis (stage 0). This clinical case shows the effectiveness of In-111 Octreotide SPECT and/or CT in the early diagnosis of pulmonary sarcoidosis