8 research outputs found
Very long optical path-length from a compact multi-pass cell
The multiple-pass optical cell is an important tool for laser absorption
spectroscopy and its many applications. For most practical applications, such
as trace-gas detection, a compact and robust design is essential. Here we
report an investigation into a multi-pass cell design based on a pair of
cylindrical mirrors, with a particular focus on achieving very long optical
paths. We demonstrate a path-length of 50.31 m in a cell with 40 mm diameter
mirrors spaced 88.9 mm apart - a 3-fold increase over the previously reported
longest path-length obtained with this type of cell configuration. We
characterize the mechanical stability of the cell and describe the practical
conditions necessary to achieve very long path-lengths
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Cavity-enhanced absorption: detection of nitrogen dioxide and iodine monoxide using a violet laser diode
We present an application of cavity-enhanced absorption spectroscopy with an off-axis alignment of the cavity formed by two spherical mirrors and with time integration of the cavity-output intensity for detection of nitrogen dioxide (NO2) and iodine monoxide (IO) radicals using a violet laser diode at lambda = 404.278 nm. A noise-equivalent (1sigma = root-mean-square variation of the signal) fractional absorption for one optical pass of 4.5x10(-8) was demonstrated with a mirror reflectivity of similar to0.99925, a cavity length of 0.22 m and a lock-in-amplifier time constant of 3 s. Noise-equivalent detection sensitivities towards nitrogen dioxide of 1.8x10(10) molecule cm(-3) and towards the IO radical of 3.3x10(9) molecule cm(-3) were achieved in flow tubes with an inner diameter of 4 cm for a lock-in-amplifier time constant of 3 s. Alkyl peroxy radicals were detected using chemical titration with excess nitric oxide (RO2 + NO --> RO + NO2). Measurement of oxygen-atom concentrations was accomplished by determining the depletion of NO2 in the reaction NO2 + O --> NO + O-2. Noise-equivalent concentrations of alkyl peroxy radicals and oxygen atoms were 3x10(10) molecule cm(-3) in the discharge-flow-tube experiments