Corrosion of alloy 800H and the effect of surface-applied CeO2 in a sulphidizing/oxidizing/carburizing environment at 700°C

The corrosion behavior of a wrought austenitic Fe-20Cr-32Ni steel, Alloy 800H, was studied in a simulated coal-gasification atmosphere at 700°C for exposure times up to 2500 hr. The influence of preoxidation and CeO2-surface application followed by preoxidation on the corrosion resistance of this material was assessed. The improvement in the corrosion resistance due to preoxidation of the blank material was small, whereas the effect of the CeO2-treatment was significant. This difference is thought to be due to better scale adherence in the case of CeO2-surface application

Series Analysis of Tricritical Behavior: Mean-Field Model and Slicewise Pade Approximants

A mean-field model is proposed as a test case for tricritical series analyses methods. Derivation of the 50th order series for the magnetization is reported. As the first application this series is analyzed by the traditional slicewise Pade approximant method popular in earlier studies of tricriticality.Comment: 22 pages in plain TeX; 7 PostScript figs available by e-mai

Universal Amplitude Combinations for Self-Avoiding Walks, Polygons and Trails

We give exact relations for a number of amplitude combinations that occur in the study of self-avoiding walks, polygons and lattice trails. In particular, we elucidate the lattice-dependent factors which occur in those combinations which are otherwise universal, show how these are modified for oriented lattices, and give new results for amplitude ratios involving even moments of the area of polygons. We also survey numerical results for a wide range of amplitudes on a number of oriented and regular lattices, and provide some new ones.Comment: 20 pages, NI 92016, OUTP 92-54S, UCSBTH-92-5

Zeros of the Partition Function for Higher--Spin 2D Ising Models

We present calculations of the complex-temperature zeros of the partition functions for 2D Ising models on the square lattice with spin $s=1$, 3/2, and 2. These give insight into complex-temperature phase diagrams of these models in the thermodynamic limit. Support is adduced for a conjecture that all divergences of the magnetisation occur at endpoints of arcs of zeros protruding into the FM phase. We conjecture that there are $4[s^2]-2$ such arcs for $s \ge 1$, where $[x]$ denotes the integral part of $x$.Comment: 8 pages, latex, 3 uuencoded figure

High-temperature expansions through order 24 for the two-dimensional classical XY model on the square lattice

The high-temperature expansion of the spin-spin correlation function of the two-dimensional classical XY (planar rotator) model on the square lattice is extended by three terms, from order 21 through order 24, and analyzed to improve the estimates of the critical parameters.Comment: 7 pages, 2 figure

Low temperature series expansions for the square lattice Ising model with spin S > 1

We derive low-temperature series (in the variable $u = \exp[-\beta J/S^2]$) for the spontaneous magnetisation, susceptibility and specific heat of the spin-$S$ Ising model on the square lattice for $S=\frac32$, 2, $\frac52$, and 3. We determine the location of the physical critical point and non-physical singularities. The number of non-physical singularities closer to the origin than the physical critical point grows quite rapidly with $S$. The critical exponents at the singularities which are closest to the origin and for which we have reasonably accurate estimates are independent of $S$. Due to the many non-physical singularities, the estimates for the physical critical point and exponents are poor for higher values of $S$, though consistent with universality.Comment: 14 pages, LaTeX with IOP style files (ioplppt.sty), epic.sty and eepic.sty. To appear in J. Phys.

Complex-Temperature Singularities in the d=2d=2 Ising Model. III. Honeycomb Lattice

We study complex-temperature properties of the uniform and staggered susceptibilities $\chi$ and $\chi^{(a)}$ of the Ising model on the honeycomb lattice. From an analysis of low-temperature series expansions, we find evidence that $\chi$ and $\chi^{(a)}$ both have divergent singularities at the point $z=-1 \equiv z_{\ell}$ (where $z=e^{-2K}$), with exponents $\gamma_{\ell}'= \gamma_{\ell,a}'=5/2$. The critical amplitudes at this singularity are calculated. Using exact results, we extract the behaviour of the magnetisation $M$ and specific heat $C$ at complex-temperature singularities. We find that, in addition to its zero at the physical critical point, $M$ diverges at $z=-1$ with exponent $\beta_{\ell}=-1/4$, vanishes continuously at $z=\pm i$ with exponent $\beta_s=3/8$, and vanishes discontinuously elsewhere along the boundary of the complex-temperature ferromagnetic phase. $C$ diverges at $z=-1$ with exponent $\alpha_{\ell}'=2$ and at $v=\pm i/\sqrt{3}$ (where $v = \tanh K$) with exponent $\alpha_e=1$, and diverges logarithmically at $z=\pm i$. We find that the exponent relation $\alpha'+2\beta+\gamma'=2$ is violated at $z=-1$; the right-hand side is 4 rather than 2. The connections of these results with complex-temperature properties of the Ising model on the triangular lattice are discussed.Comment: 22 pages, latex, figures appended after the end of the text as a compressed, uuencoded postscript fil

Osculating and neighbour-avoiding polygons on the square lattice

We study two simple modifications of self-avoiding polygons. Osculating polygons are a super-set in which we allow the perimeter of the polygon to touch at a vertex. Neighbour-avoiding polygons are only allowed to have nearest neighbour vertices provided these are joined by the associated edge and thus form a sub-set of self-avoiding polygons. We use the finite lattice method to count the number of osculating polygons and neighbour-avoiding polygons on the square lattice. We also calculate their radius of gyration and the first area-weighted moment. Analysis of the series confirms exact predictions for the critical exponents and the universality of various amplitude combinations. For both cases we have found exact solutions for the number of convex and almost-convex polygons.Comment: 14 pages, 5 figure

Size and area of square lattice polygons

We use the finite lattice method to calculate the radius of gyration, the first and second area-weighted moments of self-avoiding polygons on the square lattice. The series have been calculated for polygons up to perimeter 82. Analysis of the series yields high accuracy estimates confirming theoretical predictions for the value of the size exponent, $\nu=3/4$, and certain universal amplitude combinations. Furthermore, a detailed analysis of the asymptotic form of the series coefficients provide the firmest evidence to date for the existence of a correction-to-scaling exponent, $\Delta = 3/2$.Comment: 12 pages 3 figure