Circularity of Thermodynamical Material Networks: Indicators, Examples and Algorithms

The transition towards a circular economy has gained importance over the last years since the traditional linear take-make-dispose paradigm is not sustainable in the long term. Recently, thermodynamical material networks (TMNs) [1] have been proposed as an approach to re-design material flows based on the idea that any supply chain can be seen as a set of thermodynamic compartments that can be added, removed, modified or connected differently. In this paper, we develop several circularity indicators of TMNs using a graph-based formalism and demonstrate their calculation through examples. The paper source code is publicly available.Comment: To be added one more exampl

Thermodynamical Material Networks for Modeling, Planning and Control of Circular Material Flows

Waste production, carbon dioxide atmospheric accumulation and dependence on finite natural resources are expressions of the unsustainability of the current industrial networks that supply fuels, energy and manufacturing products. In particular, circular manufacturing supply chains and carbon control networks are urgently needed. To model and design these and, in general, any material networks, we propose to generalize the approach used for traditional networks such as water and thermal power systems using compartmental dynamical systems thermodynamics, graph theory and the force-voltage analogy. The generalized modeling methodology is explained, then challenges and future research directions are discussed. We hope this paper inspires to use dynamical systems and control, which are typically techniques used for industrial automation, for closing material flows, which is an issue of primary concern in industrial ecology and circular economy.Comment: Perspective paper in preparatio

The impacts of replacing air bubbles with microspheres for the clarification of algae from low cell-density culture

Dissolved Air Flotation (DAF) is a well-known coagulation–flotation system applied at large scale for microalgae harvesting. Compared to conventional harvesting technologies DAF allows high cell recovery at lower energy demand. By replacing microbubbles with microspheres, the innovative Ballasted Dissolved Air Flotation (BDAF) technique has been reported to achieve the same algae cell removal efficiency, while saving up to 80% of the energy required for the conventional DAF unit. Using three different algae cultures (Scenedesmus obliquus, Chlorella vulgaris and Arthrospira maxima), the present work investigated the practical, economic and environmental advantages of the BDAF system compared to the DAF system. 99% cells separation was achieved with both systems, nevertheless, the BDAF technology allowed up to 95% coagulant reduction depending on the algae species and the pH conditions adopted. In terms of floc structure and strength, the inclusion of microspheres in the algae floc generated a looser aggregate, showing a more compact structure within single cell alga, than large and filamentous cells. Overall, BDAF appeared to be a more reliable and sustainable harvesting system than DAF, as it allowed equal cells recovery reducing energy inputs, coagulant demand and carbon emissions

Beyond carbon and energy: the challenge in setting guidelines for life cycle assessment of biofuel systems

Life cycle assessment (LCA) is one of the most suitable tool for a uniform assessment methodology of biofuels’ sustainability. However, there are no binding guidelines for LCA of biofuel systems. Published LCAs use a range of methodologies, different system boundaries, impact categories and functional units, various allocation approaches, and assumptions regarding by- and co-products, as well as different reference systems to which the biofuel system is compared. The European Renewable Energy Directive and the US Renewable Fuel Standard focus on greenhouse gas (GHG) emissions. However, previous LCAs of biofuel systems have shown that a reduction of GHG emissions does not lead automatically to a decrease in other environmental impacts, and might in fact be associated with an increase in impacts such as acidification, eutrophication, and land use change. In order to enable effective comparison of biofuel systems, the authors propose a framework for biofuel LCA. System boundaries should be expanded to include the life cycle of by- and co-products. Results should be reported using more than one functional unit. Burden shifting can be avoided by considering an array of impact categories including global warming potential and energy balance, along with eutrophication and acidification potential, and a land use indicator

Infant feeding and the energy transition: A comparison between decarbonising breastmilk substitutes with renewable gas and achieving the global nutrition target for breastfeeding

Highlights: • Breastfeeding and breastfeeding support can contribute to mitigating climate change. • Achieving global nutrition targets will save more emissions than fuel-switching. • Breastfeeding support programmes support a just transition. • This work can support the expansion of mitigation options in energy system models. Abstract: Renewable gas has been proposed as a solution to decarbonise industrial processes, specifically heat demand. As part of this effort, the breast-milk substitutes industry is proposing to use renewable gas as a substitute for fossil natural gas. However, decarbonising the industrial processing of breast-milk substitutes can increase social license for these products, potentially undermining breastfeeding. World Health Organisation nutrition targets aim to increase exclusive breastfeeding to at least 50% globally by 2025 to improve maternal, infant, and young child health and nutrition. This target will have implications for the energy transition. A weakness of existing energy models is that demands for end-use products such as breast-milk substitutes are typically not considered explicitly. This paper develops an analytical framework for explicitly representing infant feeding methods in energy systems models. We compare the emissions saved in Ireland from decarbonising the industrial processing of breast-milk substitutes with renewable gas with the emissions saved by an increase in exclusive breastfeeding to 50% in both Ireland and a key export market, China. We demonstrate that the emissions saved from achieving the minimum global breastfeeding target are greater than when renewable gas is used to displace natural gas in the production of breast-milk substitutes in Ireland. We discuss the decarbonisation of breast-milk substitutes in relation to the principle of justice as non-maleficence, a principle based on the commitment to avoid harm, a novel application of a principle of justice. We conclude that breastfeeding support can be considered a demand-side measure for mitigating climate change by reducing the demand for energy services to produce breast-milk substitutes. A key recommendation is to position breastfeeding support as both a public health and a climate justice issue that is relevant for a just transition. The framework developed for this paper could be applied to support the inclusion of a wider range of mitigation options with social justice outcomes in energy system models. [Open access