3 research outputs found
Asymmetric Intermolecular Cobalt-Catalyzed PausonâKhand Reaction Using a PâStereogenic Bis-phosphane
The asymmetric intermolecular and
catalytic PausonâKhand
reaction has remained an elusive goal since Khand and Pauson discovered
this transformation. Using a novel family of P-stereogenic phosphanes,
we developed the first catalytic system with useful levels of enantioselection
for the reaction of norbornadiene and trimethylsilylacetylene. The
results demonstrate that Coâbisphosphane systems are sufficiently
reactive and that they lead to high selectivity in the intermolecular
process
Asymmetric Intermolecular Cobalt-Catalyzed PausonâKhand Reaction Using a PâStereogenic Bis-phosphane
The asymmetric intermolecular and
catalytic PausonâKhand
reaction has remained an elusive goal since Khand and Pauson discovered
this transformation. Using a novel family of P-stereogenic phosphanes,
we developed the first catalytic system with useful levels of enantioselection
for the reaction of norbornadiene and trimethylsilylacetylene. The
results demonstrate that Coâbisphosphane systems are sufficiently
reactive and that they lead to high selectivity in the intermolecular
process
Asymmetric Intermolecular Cobalt-Catalyzed PausonâKhand Reaction Using a PâStereogenic Bis-phosphane
The asymmetric intermolecular and
catalytic PausonâKhand
reaction has remained an elusive goal since Khand and Pauson discovered
this transformation. Using a novel family of P-stereogenic phosphanes,
we developed the first catalytic system with useful levels of enantioselection
for the reaction of norbornadiene and trimethylsilylacetylene. The
results demonstrate that Coâbisphosphane systems are sufficiently
reactive and that they lead to high selectivity in the intermolecular
process