5 research outputs found
PSPB_Supplementary_Materials_v2 – Supplemental material for The Power in Being Yourself: Feeling Authentic Enhances the Sense of Power
<p>Supplemental material, PSPB_Supplementary_Materials_v2 for The Power in Being Yourself: Feeling Authentic Enhances the Sense of Power by Muping Gan, Daniel Heller and Serena Chen in Personality and Social Psychology Bulletin</p
heller_online_appendix – Supplemental material for The Power in Being Yourself: Feeling Authentic Enhances the Sense of Power
<p>Supplemental material, heller_online_appendix for The Power in Being Yourself: Feeling Authentic Enhances the Sense of Power by Muping Gan, Daniel Heller and Serena Chen in Personality and Social Psychology Bulletin</p
Comparing the UV/Monochloramine and UV/Free Chlorine Advanced Oxidation Processes (AOPs) to the UV/Hydrogen Peroxide AOP Under Scenarios Relevant to Potable Reuse
Utilities incorporating the potable
reuse of municipal wastewater
are interested in converting from the UV/H<sub>2</sub>O<sub>2</sub> to the UV/free chlorine advanced oxidation process (AOP). The AOP
treatment of reverse osmosis (RO) permeate often includes the de facto
UV/chloramine AOP because chloramines applied upstream permeate RO
membranes. Models are needed that accurately predict oxidant photolysis
and subsequent radical reactions. By combining radical scavengers
and kinetic modeling, we have derived quantum yields for radical generation
by the UV photolysis of HOCl, OCl<sup>–</sup>, and NH<sub>2</sub>Cl of 0.62, 0.55, and 0.20, respectively, far below previous estimates
that incorporated subsequent free chlorine or chloramine scavenging
by the <sup>•</sup>Cl and <sup>•</sup>OH daughter radicals.
The observed quantum yield for free chlorine loss actually decreased
with increasing free chlorine concentration, suggesting scavenging
of radicals participating in free chlorine chain decomposition and
even free chlorine reformation. Consideration of reactions of <sup>•</sup>ClO and its daughter products (e.g., ClO<sub>2</sub><sup>–</sup>), not included in previous models, were critical
for modeling free chlorine loss. Radical reactions (indirect photolysis)
accounted for ∼50% of chloramine decay and ∼80% of free
chlorine loss or reformation. The performance of the UV/chloramine
AOP was comparable to the UV/H<sub>2</sub>O<sub>2</sub> AOP for degradation
of 1,4-dioxane, benzoate and carbamazepine across pH 5.5–8.3.
The UV/free chlorine AOP was more efficient at pH 5.5, but only by
30% for 1,4-dioxane. At pH 7.0–8.3, the UV/free chlorine AOP
was less efficient. <sup>•</sup>Cl converts to <sup>•</sup>OH. The modeled <sup>•</sup>Cl:<sup>•</sup>OH ratio
was ∼20% for the UV/free chlorine AOP and ∼35% for the
UV/chloramine AOP such that <sup>•</sup>OH was generally more
important for contaminant degradation
Additional file 3: Figure S1. of Evaluating genetic ancestry and self-reported ethnicity in the context of carrier screening
Plot of the first and second principal components obtained by Principal Component Analysis on 44 geographic groups (described in Additional file 2: Table S1) and 1142 AIMs. Each geographic group is shown as a point and is colored according to the continental group to which it belongs. The plot illustrates that the AIMs separate most continental groups well, but the Middle Eastern and Central Asian groups do not form distinct clusters. (PNG 49 kb
Additional file 2: of Evaluating genetic ancestry and self-reported ethnicity in the context of carrier screening
Supplementary tables. (XLSX 39181 kb