27 research outputs found
Bioinspired, Highly Stretchable, and Conductive Dry Adhesives Based on 1D–2D Hybrid Carbon Nanocomposites for All-in-One ECG Electrodes
Here
we propose a concept of conductive dry adhesives (CDA) combining
a gecko-inspired hierarchical structure and an elastomeric carbon
nanocomposite. To complement the poor electrical percolation of 1D
carbon nanotube (CNT) networks in an elastomeric matrix at a low filler
content (∼1 wt %), a higher dimensional carbon material (<i>i</i>.<i>e</i>., carbon black, nanographite, and graphene
nanopowder) is added into the mixture as an aid filler. The co-doped
graphene and CNT in the composite show the lowest volume resistance
(∼100 ohm·cm) at an optimized filler ratio (1:9, total
filler content: 1 wt %) through a synergetic effect in electrical
percolation. With an optimized conductive elastomer, gecko-inspired
high-aspect-ratio (>3) microstructures over a large area (∼4
in.<sup>2</sup>) are successfully replicated from intaglio-patterned
molds without collapse. The resultant CDA pad shows a high normal
adhesion force (∼1.3 N/cm<sup>2</sup>) even on rough human
skin and an excellent cycling property for repeatable use over 30
times without degradation of adhesion force, which cannot be achieved
by commercial wet adhesives. The body-attachable CDA can be used as
a metal-free, all-in-one component for measuring biosignals under
daily activity conditions (<i>i</i>.<i>e</i>.,
underwater, movements) because of its superior conformality and water-repellent
characteristic
Bioinspired, Highly Stretchable, and Conductive Dry Adhesives Based on 1D–2D Hybrid Carbon Nanocomposites for All-in-One ECG Electrodes
Here
we propose a concept of conductive dry adhesives (CDA) combining
a gecko-inspired hierarchical structure and an elastomeric carbon
nanocomposite. To complement the poor electrical percolation of 1D
carbon nanotube (CNT) networks in an elastomeric matrix at a low filler
content (∼1 wt %), a higher dimensional carbon material (<i>i</i>.<i>e</i>., carbon black, nanographite, and graphene
nanopowder) is added into the mixture as an aid filler. The co-doped
graphene and CNT in the composite show the lowest volume resistance
(∼100 ohm·cm) at an optimized filler ratio (1:9, total
filler content: 1 wt %) through a synergetic effect in electrical
percolation. With an optimized conductive elastomer, gecko-inspired
high-aspect-ratio (>3) microstructures over a large area (∼4
in.<sup>2</sup>) are successfully replicated from intaglio-patterned
molds without collapse. The resultant CDA pad shows a high normal
adhesion force (∼1.3 N/cm<sup>2</sup>) even on rough human
skin and an excellent cycling property for repeatable use over 30
times without degradation of adhesion force, which cannot be achieved
by commercial wet adhesives. The body-attachable CDA can be used as
a metal-free, all-in-one component for measuring biosignals under
daily activity conditions (<i>i</i>.<i>e</i>.,
underwater, movements) because of its superior conformality and water-repellent
characteristic
Tuning the Photoluminescence of Graphene Quantum Dots through the Charge Transfer Effect of Functional Groups
The band gap properties of graphene quantum dots (GQDs) arise from quantum confinement effects and differ from those in semimetallic graphene sheets. Tailoring the size of the band gap and understanding the band gap tuning mechanism are essential for the applications of GQDs in opto-electronics. In this study, we observe that the photoluminescence (PL) of the GQDs shifts due to charge transfers between functional groups and GQDs. GQDs that are functionalized with amine groups and are 1–3 layers thick and less than 5 nm in diameter were successfully fabricated using a two-step cutting process from graphene oxides (GOs). The functionalized GQDs exhibit a redshift of PL emission (<i>ca</i>. 30 nm) compared to the unfunctionalized GQDs. Furthermore, the PL emissions of the GQDs and the amine-functionalized GQDs were also shifted by changes in the pH due to the protonation or deprotonation of the functional groups. The PL shifts resulted from charge transfers between the functional groups and GQDs, which can tune the band gap of the GQDs. Calculations from density functional theory (DFT) are in good agreement with our proposed mechanism for band gap tuning in the GQDs through the use of functionalization
Additional file 1: of Fabrication of Nanoshell-Based 3D Periodic Structures by Templating Process using Solution-derived ZnO
Supplemental information. Figure S1: Cross-sectional SEM images of the structures. (a) 3D polymeric template as a starting structure, (b) sample post-baked at 400 °C for 1 h without pre-baking after precursor infiltration, and (c) the pre-baked template without precursor infiltration. Figure S2: Cross-sectional SEM images and schematic diagrams of the shrinkage models for one-cycle infiltrated structures. (a) After pre-baking, (b) the predicted model after post-baking, which indicates remaining pre-formed ZnO, and (c) after post-baking. Figure S3: Cross-sectional SEM images with lower magnification of 3D inverse structures. The infiltration process was conducted with different cycle numbers from one to six (a–f). Figure S4: A comparison of EDX analysis results. The differences in the results for (a) before and (b) after post-baking are apparent; inset illustrates cross-sectional SEM images of the structures and critical excitation potential for each element. Figure S5: Reflectance spectra of the polymeric template and the nanoshell-based 3D ZnO structure. Figure S6: (αhν)2 vs photon energy (hν) plot of nanoshell-based 3D ZnO structure. (DOCX 1903 kb
Scalable Exfoliation Process for Highly Soluble Boron Nitride Nanoplatelets by Hydroxide-Assisted Ball Milling
The
scalable preparation of two-dimensional hexagonal boron nitride (h-BN)
is essential for practical applications. Despite intense research
in this area, high-yield production of two-dimensional h-BN with large-size
and high solubility remains a key challenge. In the present work,
we propose a scalable exfoliation process for hydroxyl-functionalized
BN nanoplatelets (OH-BNNPs) by a simple ball milling of BN powders
in the presence of sodium hydroxide via the synergetic effect of chemical
peeling and mechanical shear forces. The hydroxide-assisted ball milling
process results in relatively large flakes with an average size of
1.5 μm with little damage to the in-plane structure of the OH-BNNP
and high yields of 18%. The resultant OH-BNNP samples can be redispersed
in various solvents and form stable dispersions that can be used for
multiple purposes. The incorporation of the BNNPs into the polyethylene
matrix effectively enhanced the barrier properties of the polyethylene
due to increased tortuosity of the diffusion path of the gas molecules.
Hydroxide-assisted ball milling process can thus provide simple and
efficient approaches to scalable preparation of large-size and highly
soluble BNNPs. Moreover, this exfoliation process is not only easily
scalable but also applicable to other layered materials
MOESM1 of Analysis of contact resistance in single-walled carbon nanotube channel and graphene electrodes in a thin film transistor
Additional file 1: Figure S1. Additional geometric information of graphene/SWCNT devices
Bifunctional Composite Catalysts Using Co<sub>3</sub>O<sub>4</sub> Nanofibers Immobilized on Nonoxidized Graphene Nanoflakes for High-Capacity and Long-Cycle Li–O<sub>2</sub> Batteries
Designing
a highly efficient catalyst is essential to improve the
electrochemical performance of Li–O<sub>2</sub> batteries for
long-term cycling. Furthermore, these batteries often show significant
capacity fading due to the irreversible reaction characteristics of
the Li<sub>2</sub>O<sub>2</sub> product. To overcome these limitations,
we propose a bifunctional composite catalyst composed of electrospun
one-dimensional (1D) Co<sub>3</sub>O<sub>4</sub> nanofibers (NFs)
immobilized on both sides of the 2D nonoxidized graphene nanoflakes
(GNFs) for an oxygen electrode in Li–O<sub>2</sub> batteries.
Highly conductive GNFs with noncovalent functionalization can facilitate
a homogeneous dispersion in solution, thereby enabling simple and
uniform attachment of 1D Co<sub>3</sub>O<sub>4</sub> NFs on GNFs without
restacking. High first discharge capacity of 10 500 mAh/g and
superior cyclability for 80 cycles with a limited capacity of 1000
mAh/g were achieved by (i) improved catalytic activity of 1D Co<sub>3</sub>O<sub>4</sub> NFs with large surface area, (ii) facile electron
transport via interconnected GNFs functionalized by Co<sub>3</sub>O<sub>4</sub> NFs, and (iii) fast O<sub>2</sub> diffusion through
the ultrathin GNF layer and porous Co<sub>3</sub>O<sub>4</sub> NF
networks
Identification of Metalloporphyrins with High Sensitivity Using Graphene-Enhanced Resonance Raman Scattering
Graphene-enhanced
resonance Raman scattering (GERRS) was performed for the detection
of three different metallo-octaethylporphyrins (M-OEPs; M = 2H, FeCl,
and Pt) homogeneously thermal vapor deposited on a graphene surface.
GERRS of M-OEPs were measured using three different excitation wavelengths,
λ<sub>ex</sub> = 405, 532, and 633 nm, and characterized detail
vibrational bands for the identification of M-OEPs. The GERRS spectra
of Pt-OEP at λ<sub>ex</sub> = 532 nm showed ∼29 and ∼162
times signal enhancement ratio on graphene and on graphene with Ag
nanoclusters, respectively, compared to the spectra from bare SiO<sub>2</sub> substrate. This enhancement ratio, however, was varied with
M-OEPs and excitation wavelengths. The characteristic peaks and band
shapes of GERRS for each M-OEP were measured with high sensitivity
(100 pmol of thermal vapor deposited Pt-OEP), and these facilitate
the selectively recognition of molecules. Also, the peaks shift and
broadening provide the evidence of the interaction between graphene
and M-OEPs through the charge transfer and π-orbital interaction.
The increase of graphene layer induced the decrease of signal intensity
and GERRS effect was almost not observed on the thick graphite flakes.
Further experiments with various substrates demonstrated that the
interaction of single layer of graphene with molecule is the origin
of the Raman signal enhancement of M-OEPs. In this experiment, we
proved the graphene is a good alternative substrate of Raman spectroscopy
for the selective detection of various metalloporphyrins with high
sensitivity
Exfoliation of Non-Oxidized Graphene Flakes for Scalable Conductive Film
The increasing demand for graphene has required a new
route for
its mass production without causing extreme damages. Here we demonstrate
a simple and cost-effective intercalation based exfoliation method
for preparing high quality graphene flakes, which form a stable dispersion
in organic solvents without any functionalization and surfactant.
Successful intercalation of alkali metal between graphite interlayers
through liquid-state diffusion from ternary KCl–NaCl–ZnCl<sub>2</sub> eutectic system is confirmed by X-ray diffraction and X-ray
photoelectric spectroscopy. Chemical composition and morphology analyses
prove that the graphene flakes preserve their intrinsic properties
without any degradation. The graphene flakes remain dispersed in a
mixture of pyridine and salts for more than 6 months. We apply these
results to produce transparent conducting (∼930 Ω/□
at ∼75% transmission) graphene films using the modified Langmuir–Blodgett
method. The overall results suggest that our method can be a scalable
(>1 g/batch) and economical route for the synthesis of nonoxidized
graphene flakes