Survival of carbon grains in shocks

Supernova shocks play a significant part in the life of an interstellar grain. In a typical 10 to the 9th power year lifetime, a grain will be hit by an average of 10 shocks of 100 km s(sup -1) or greater velocity, and even more shocks of lower velocity. Evaluation of the results of this frequent shock processing is complicated by a number of uncertainties, but seems to give about 10 percent destruction of silicate grains and about half that for graphite grains. Because of the frequency of shocking, the mineralogy and sizes of the grain population is predominately determined by shock processing effects, and not by the initial grain nucleation and growth environment. One consequence of the significant role played by interstellar shocks is that a certain fraction (up to 5 percent) of the carbon should be transformed into the diamond phase. Diamond transformation is observed in the laboratory at threshold shock pressures easily obtainable in grain-grain collisions in supernova shocks. Yields for transforming graphite, amorphous carbon, glassy carbon, and other nearly pure carbon solids into diamond are quite high. Impurities up to at least the 10 percent level (for oxygen) are tolerated in the process. The typical size diamond expected from shock transformation agrees well with the observed sizes in the Lewis et al. findings in meteoritic material. Isotropic anomalies already contained in the grain are likely to be retained through the conversion process, while others may be implanted by the shock if the grain is close to the supernova. The meteoritic diamonds are likely to be the results of transformation of carbon grains in grain-grain collisions in supernova shock waves

Diffuse band profiles in the Rho Ophiuchi cloud

High-resolution, high signal-to-noise ratio line profiles are presented for the 5780 and 5797 A diffuse interstellar bands toward six stars in the Rho Oph dark cloud. Target stars were chosen to exhibit a wide range of interstellar grain properties, as measured by grain polarization and far-UV extinction. The extreme case of the heavily reddened star HD 147889 is included; this star has one of the highest known lambdamax values, indicative of unusually large grains. Despite the differences in the grain properties, the line profiles and central wavelengths for the 5780 A band were found to be essentially identical for all lines of sight. This finding is in contradiction to the results of the embedded cavity grain model for diffuse bands, which predicts changes in both profile and central wavelength with grain size and impurity concentration. Results therefore support a molecular origin for the diffuse bands

Diffuse band profiles in the Rho Ophiuchi cloud

High-resolution, high signal-to-noise ratio line profiles are presented for the 5780 and 5797 A diffuse interstellar bands toward six stars in the Rho Oph dark cloud. Target stars were chosen to exhibit a wide range of interstellar grain properties, as measured by grain polarization and far-UV extinction. The extreme case of the heavily reddened star HD 147889 is included; this star has one of the highest known lambdamax values, indicative of unusually large grains. Despite the differences in the grain properties, the line profiles and central wavelengths for the 5780 A band were found to be essentially identical for all lines of sight. This finding is in contradiction to the results of the embedded cavity grain model for diffuse bands, which predicts changes in both profile and central wavelength with grain size and impurity concentration. Results therefore support a molecular origin for the diffuse bands

On the size distribution of newly formed grains in red supergiant atmospheres

Theoretical ultraviolet extinction curves have been calculated for comparison with observed curves for circumstellar dust in M supergiants. The theoretical curves assumed a silicate grain composition, because silicate grains are expected in the oxygen-rich environments that are observed. Calculations were performed with and without the inclusion of scattering into the beam, with largely similar results. A comparison of the computed curves with the observed ultraviolet extinction curve for circumstellar dust in Scorpii indicates that the size distribution of the circumstellar grains must cut off near 800 Å that is, there are few or no grains smaller than this. Our conclusion is that smaller interstellar silicate grains, where they exist, must come from other sources such as grain fragmentation in shocks

Predicting peculiar interstellar extinction from gaseous abundances

Molecular and atomic abundances are examined for 19 lines of sight through dense clouds, each with a peculiar selective extinction curve. The interstellar clouds in the present study appear to fall into two distinct categories: CN-rich, with relatively small amounts of neutral iron, or CN-poor, with large amounts of neutral iron. Lines of sight, having a CN/(Fe i) abundance ratio about two (~ 0.3 dex) or greater, are found to have a shallow (2.57 ± 0.55 mag) 2175 Å feature relative to the underlying extinction, while the strength of the bump is 3.60 ± 0.36 for the other dense clouds in the present study. The difference in the strength of the extinction bump between these two ensembles is 1.03 ± 0.23. Several atomic abundances are examined as potential indicators of peculiar extinction. Mn i abundances in particular are sought at 10 times greater sensitivity than previous studies because of a possible empirical connection between a small (Mn ii)/(Fe ii) abundance ratio and a weak 2175 Å bump reported in the literature. Unfortunately, the abundances of the neutral atoms do not appear to scale with the abundance of CN, reducing the effectiveness of Mn i as a diagnostic tool. Nevertheless, the Mn i upper limits in the present study support Mn being preferentially depleted. Fe i is underabundant relative to K i by 0.7 (dex) in the large (CN)/(Fe i) compared to the small (CN)/(Fe i) lines of sight. In addition, the data suggest that potassium is substantially depleted in both types of dense cloud

Predicting peculiar interstellar extinction from gaseous abundances

Molecular and atomic abundances are examined for 19 lines of sight through dense clouds, each with a peculiar selective extinction curve. The interstellar clouds in the present study appear to fall into two distinct categories: CN-rich, with relatively small amounts of neutral iron, or CN-poor, with large amounts of neutral iron. Lines of sight, having a CN/(Fe i) abundance ratio about two (~ 0.3 dex) or greater, are found to have a shallow (2.57 ± 0.55 mag) 2175 Å feature relative to the underlying extinction, while the strength of the bump is 3.60 ± 0.36 for the other dense clouds in the present study. The difference in the strength of the extinction bump between these two ensembles is 1.03 ± 0.23. Several atomic abundances are examined as potential indicators of peculiar extinction. Mn i abundances in particular are sought at 10 times greater sensitivity than previous studies because of a possible empirical connection between a small (Mn ii)/(Fe ii) abundance ratio and a weak 2175 Å bump reported in the literature. Unfortunately, the abundances of the neutral atoms do not appear to scale with the abundance of CN, reducing the effectiveness of Mn i as a diagnostic tool. Nevertheless, the Mn i upper limits in the present study support Mn being preferentially depleted. Fe i is underabundant relative to K i by 0.7 (dex) in the large (CN)/(Fe i) compared to the small (CN)/(Fe i) lines of sight. In addition, the data suggest that potassium is substantially depleted in both types of dense cloud