Synthesis and crystal structures of palladium complexes based on α\alpha -amino-oximes derived from (RR)-limonene and their application in allylic alkylation of 1,3-dioxo compounds

Coordination compounds Pd(L1)Cl$_{2}$, Pd(L2)Cl$_{2}$, and Pd(L3)Cl$_{2}$ have been synthesized from optically pure $\alpha$-amino-oxime ligands L1–L3 based on $(R)$-limonene. Structures of the new palladium complexes are characterized and described by NMR spectroscopy and X-rays. These $\alpha$-amino-oxime ligands were then evaluated in the palladium-catalysed allylation of 1,3-dioxo compounds

Synthesis and crystal structures of palladium complexes based on α\alpha -amino-oximes derived from (RR)-limonene and their application in allylic alkylation of 1,3-dioxo compounds

Coordination compounds Pd(L1)Cl$_{2}$, Pd(L2)Cl$_{2}$, and Pd(L3)Cl$_{2}$ have been synthesized from optically pure $\alpha$-amino-oxime ligands L1–L3 based on $(R)$-limonene. Structures of the new palladium complexes are characterized and described by NMR spectroscopy and X-rays. These $\alpha$-amino-oxime ligands were then evaluated in the palladium-catalysed allylation of 1,3-dioxo compounds

Nickel catalyzed allylation reactions with allylic alcohols and dienes

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Homogeneous catalysis for lignin functionalization

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Catalyse couplée hétérogène/homogène: Synthèse et transformation du bio-butadiène pour la préparation d’éthers insaturés dérivés de polyols

National audienc

Catalyse / chimie organique et fonctionnalisation propre de lignines

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Nickel Catalyzed Allylation reactions

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Allylation with allylic alcohols : The point of view of nickel catalysis

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Valorisation de la biomasse – Nouveaux matériaux à base de lignine

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