26 research outputs found
Halogen-free pyrrolidinium bis(mandelato)borate ionic liquids: Some physicochemical properties and lubrication performance as additives to polyethylene glycol
This work reports on the synthesis and physicochemical characterisation of novel halogen-free boron containing ionic liquids (hf-BILs) with dialkylpyrrolidinium cations [CnC1Pyrr]+, n = 4-14, and bis(mandelato)borate anion [BMB]-. All the synthesised compounds are liquids at room temperature. It was found that the thermal properties and density of these hf-BILs are affected by the length of the longest alkyl chain connected to the nitrogen atom in the pyrrolidinium cations. Differential scanning calorimetry measurements revealed that glass transition temperatures of these ionic liquids are in the temperature range from 218 to 241 K. Interestingly, the glass transition temperatures follow the "odd-even" effect related to the number of carbons (n) in one of the alkyl chains of [CnC1Pyrr]+. It was also found that hf-BILs' density decreases with an increase in the alkyl chain length of [CnC1Pyrr]+. It is suggested that the "odd-even" effect is associated with the difference in packing and specific interactions of cations and anions of this class of hf-BILs. Their lubricating properties, as 3 wt% additives in polyethylene glycol (PEG), were evaluated in steel-steel contacts. PEG with hf-BILs additive provided significantly lower wear and friction compared to the neat PEG and 5W40 engine oil. It was found that shortening the length of the longest alkyl chain in the cations of [CnC1Pyrr][BMB] significantly reduces frictional losses. Antiwear properties of [CnC1Pyrr][BMB] in PEG follow the same trend. This journal is © the Partner Organisations 2014
Self-diffusion and interactions in mixtures of imidazolium bis(mandelato)borate ionic liquids with polyethylene glycol: <sup>1</sup>H NMR study
Copyright © 2015 John Wiley & Sons, Ltd. We used 1H nuclear magnetic resonance pulsed-field gradient to study the self-diffusion of polyethylene glycol (PEG) and ions in a mixture of PEG and imidazolium bis(mandelato)borate ionic liquids (ILs) at IL concentrations from 0 to 10 and temperatures from 295 to 370. PEG behaves as a solvent for these ILs, allowing observation of separate lines in 1H NMR spectra assigned to the cation and anion as well as to PEG. The diffusion coefficients of PEG, as well as the imidazolium cation and bis(mandelato)borate (BMB) anion, differ under all experimental conditions tested. This demonstrates that the IL in the mixture is present in at least a partially dissociated state, while the lifetimes of the associated states of the ions and ions with PEG are less than 30ms. Generally, increasing the concentration of the IL leads to a decrease in the diffusion coefficients of PEG and both ions. The diffusion coefficient of the anion is less than that of the cation; the molecular mass dependence of diffusion of ions can be described by the Stokes-Einstein model. NMR chemical shift alteration analysis showed that the presence of PEG changes mainly the chemical shifts of protons belonging to imidazole ring of the cation, while chemical shifts of protons of anions and PEG remain unchanged. This demonstrated that the imidazolium cation interacts mainly with PEG, which most probably occurs through the oxygen of PEG and the imidazole ring. The BMB anion does not strongly interact with PEG, but it may be indirectly affected by PEG through interaction with the cation, which directly interacts with PEG
Self-diffusion and interactions in mixtures of imidazolium bis(mandelato)borate ionic liquids with polyethylene glycol: 1H NMR study
© 2015 John Wiley & Sons, Ltd. We used 1H nuclear magnetic resonance pulsed-field gradient to study the self-diffusion of polyethylene glycol (PEG) and ions in a mixture of PEG and imidazolium bis(mandelato)borate ionic liquids (ILs) at IL concentrations from 0 to 10wt% and temperatures from 295 to 370K. PEG behaves as a solvent for these ILs, allowing observation of separate lines in 1H NMR spectra assigned to the cation and anion as well as to PEG. The diffusion coefficients of PEG, as well as the imidazolium cation and bis(mandelato)borate (BMB) anion, differ under all experimental conditions tested. This demonstrates that the IL in the mixture is present in at least a partially dissociated state, while the lifetimes of the associated states of the ions and ions with PEG are less than ~30ms. Generally, increasing the concentration of the IL leads to a decrease in the diffusion coefficients of PEG and both ions. The diffusion coefficient of the anion is less than that of the cation; the molecular mass dependence of diffusion of ions can be described by the Stokes-Einstein model. NMR chemical shift alteration analysis showed that the presence of PEG changes mainly the chemical shifts of protons belonging to imidazole ring of the cation, while chemical shifts of protons of anions and PEG remain unchanged. This demonstrated that the imidazolium cation interacts mainly with PEG, which most probably occurs through the oxygen of PEG and the imidazole ring. The BMB anion does not strongly interact with PEG, but it may be indirectly affected by PEG through interaction with the cation, which directly interacts with PEG
Halogen-free pyrrolidinium bis(mandelato)borate ionic liquids: Some physicochemical properties and lubrication performance as additives to polyethylene glycol
This work reports on the synthesis and physicochemical characterisation of novel halogen-free boron containing ionic liquids (hf-BILs) with dialkylpyrrolidinium cations [CnC1Pyrr]+, n = 4-14, and bis(mandelato)borate anion [BMB]-. All the synthesised compounds are liquids at room temperature. It was found that the thermal properties and density of these hf-BILs are affected by the length of the longest alkyl chain connected to the nitrogen atom in the pyrrolidinium cations. Differential scanning calorimetry measurements revealed that glass transition temperatures of these ionic liquids are in the temperature range from 218 to 241 K. Interestingly, the glass transition temperatures follow the "odd-even" effect related to the number of carbons (n) in one of the alkyl chains of [CnC1Pyrr]+. It was also found that hf-BILs' density decreases with an increase in the alkyl chain length of [CnC1Pyrr]+. It is suggested that the "odd-even" effect is associated with the difference in packing and specific interactions of cations and anions of this class of hf-BILs. Their lubricating properties, as 3 wt% additives in polyethylene glycol (PEG), were evaluated in steel-steel contacts. PEG with hf-BILs additive provided significantly lower wear and friction compared to the neat PEG and 5W40 engine oil. It was found that shortening the length of the longest alkyl chain in the cations of [CnC1Pyrr][BMB] significantly reduces frictional losses. Antiwear properties of [CnC1Pyrr][BMB] in PEG follow the same trend. This journal is © the Partner Organisations 2014
Halogen-free pyrrolidinium bis(mandelato)borate ionic liquids: Some physicochemical properties and lubrication performance as additives to polyethylene glycol
This work reports on the synthesis and physicochemical characterisation of novel halogen-free boron containing ionic liquids (hf-BILs) with dialkylpyrrolidinium cations [CnC1Pyrr]+, n = 4-14, and bis(mandelato)borate anion [BMB]-. All the synthesised compounds are liquids at room temperature. It was found that the thermal properties and density of these hf-BILs are affected by the length of the longest alkyl chain connected to the nitrogen atom in the pyrrolidinium cations. Differential scanning calorimetry measurements revealed that glass transition temperatures of these ionic liquids are in the temperature range from 218 to 241 K. Interestingly, the glass transition temperatures follow the "odd-even" effect related to the number of carbons (n) in one of the alkyl chains of [CnC1Pyrr]+. It was also found that hf-BILs' density decreases with an increase in the alkyl chain length of [CnC1Pyrr]+. It is suggested that the "odd-even" effect is associated with the difference in packing and specific interactions of cations and anions of this class of hf-BILs. Their lubricating properties, as 3 wt% additives in polyethylene glycol (PEG), were evaluated in steel-steel contacts. PEG with hf-BILs additive provided significantly lower wear and friction compared to the neat PEG and 5W40 engine oil. It was found that shortening the length of the longest alkyl chain in the cations of [CnC1Pyrr][BMB] significantly reduces frictional losses. Antiwear properties of [CnC1Pyrr][BMB] in PEG follow the same trend. This journal is © the Partner Organisations 2014
Self-diffusion and interactions in mixtures of imidazolium bis(mandelato)borate ionic liquids with polyethylene glycol: <sup>1</sup>H NMR study
Copyright © 2015 John Wiley & Sons, Ltd. We used 1H nuclear magnetic resonance pulsed-field gradient to study the self-diffusion of polyethylene glycol (PEG) and ions in a mixture of PEG and imidazolium bis(mandelato)borate ionic liquids (ILs) at IL concentrations from 0 to 10 and temperatures from 295 to 370. PEG behaves as a solvent for these ILs, allowing observation of separate lines in 1H NMR spectra assigned to the cation and anion as well as to PEG. The diffusion coefficients of PEG, as well as the imidazolium cation and bis(mandelato)borate (BMB) anion, differ under all experimental conditions tested. This demonstrates that the IL in the mixture is present in at least a partially dissociated state, while the lifetimes of the associated states of the ions and ions with PEG are less than 30ms. Generally, increasing the concentration of the IL leads to a decrease in the diffusion coefficients of PEG and both ions. The diffusion coefficient of the anion is less than that of the cation; the molecular mass dependence of diffusion of ions can be described by the Stokes-Einstein model. NMR chemical shift alteration analysis showed that the presence of PEG changes mainly the chemical shifts of protons belonging to imidazole ring of the cation, while chemical shifts of protons of anions and PEG remain unchanged. This demonstrated that the imidazolium cation interacts mainly with PEG, which most probably occurs through the oxygen of PEG and the imidazole ring. The BMB anion does not strongly interact with PEG, but it may be indirectly affected by PEG through interaction with the cation, which directly interacts with PEG
Halogen-free pyrrolidinium bis(mandelato)borate ionic liquids: Some physicochemical properties and lubrication performance as additives to polyethylene glycol
This work reports on the synthesis and physicochemical characterisation of novel halogen-free boron containing ionic liquids (hf-BILs) with dialkylpyrrolidinium cations [CnC1Pyrr]+, n = 4-14, and bis(mandelato)borate anion [BMB]-. All the synthesised compounds are liquids at room temperature. It was found that the thermal properties and density of these hf-BILs are affected by the length of the longest alkyl chain connected to the nitrogen atom in the pyrrolidinium cations. Differential scanning calorimetry measurements revealed that glass transition temperatures of these ionic liquids are in the temperature range from 218 to 241 K. Interestingly, the glass transition temperatures follow the "odd-even" effect related to the number of carbons (n) in one of the alkyl chains of [CnC1Pyrr]+. It was also found that hf-BILs' density decreases with an increase in the alkyl chain length of [CnC1Pyrr]+. It is suggested that the "odd-even" effect is associated with the difference in packing and specific interactions of cations and anions of this class of hf-BILs. Their lubricating properties, as 3 wt% additives in polyethylene glycol (PEG), were evaluated in steel-steel contacts. PEG with hf-BILs additive provided significantly lower wear and friction compared to the neat PEG and 5W40 engine oil. It was found that shortening the length of the longest alkyl chain in the cations of [CnC1Pyrr][BMB] significantly reduces frictional losses. Antiwear properties of [CnC1Pyrr][BMB] in PEG follow the same trend. This journal is © the Partner Organisations 2014
Halogen-free pyrrolidinium bis(mandelato)borate ionic liquids: Some physicochemical properties and lubrication performance as additives to polyethylene glycol
This work reports on the synthesis and physicochemical characterisation of novel halogen-free boron containing ionic liquids (hf-BILs) with dialkylpyrrolidinium cations [CnC1Pyrr]+, n = 4-14, and bis(mandelato)borate anion [BMB]-. All the synthesised compounds are liquids at room temperature. It was found that the thermal properties and density of these hf-BILs are affected by the length of the longest alkyl chain connected to the nitrogen atom in the pyrrolidinium cations. Differential scanning calorimetry measurements revealed that glass transition temperatures of these ionic liquids are in the temperature range from 218 to 241 K. Interestingly, the glass transition temperatures follow the "odd-even" effect related to the number of carbons (n) in one of the alkyl chains of [CnC1Pyrr]+. It was also found that hf-BILs' density decreases with an increase in the alkyl chain length of [CnC1Pyrr]+. It is suggested that the "odd-even" effect is associated with the difference in packing and specific interactions of cations and anions of this class of hf-BILs. Their lubricating properties, as 3 wt% additives in polyethylene glycol (PEG), were evaluated in steel-steel contacts. PEG with hf-BILs additive provided significantly lower wear and friction compared to the neat PEG and 5W40 engine oil. It was found that shortening the length of the longest alkyl chain in the cations of [CnC1Pyrr][BMB] significantly reduces frictional losses. Antiwear properties of [CnC1Pyrr][BMB] in PEG follow the same trend. This journal is © the Partner Organisations 2014