39 research outputs found
Quantum noise-induced chaotic oscillations
We examine the weak quantum noise limit of Wigner equation for phase space
distribution functions. It has been shown that the leading order quantum noise
described in terms of an auxiliary Hamiltonian manifests itself as an
additional fluctuational degree of freedom which may induce chaotic and regular
oscillations in a nonlinear oscillator.Comment: minor corrections, new references adde
Numerical simulation of transmission coefficient using c-number Langevin equation
We numerically implement the reactive flux formalism on the basis of a
recently proposed c-number Langevin equation [Barik \textit{et al}, J. Chem.
Phys. {\bf 119}, 680 (2003); Banerjee \textit{et al}, Phys. Rev. E {\bf 65},
021109 (2002)] to calculate transmission coefficient. The Kramers' turnover,
the enhancement of the rate at low temperatures and other related
features of temporal behaviour of the transmission coefficient over a range of
temperature down to absolute zero, noise correlation and friction are examined
for a double well potential and compared with other known results. This simple
method is based on canonical quantization and Wigner quasiclassical phase space
function and takes care of quantum effects due to the system order by order
Noise correlation-induced splitting of Kramers' escape rate from a metastable state
A correlation between two noise processes driving the thermally activated
particles in a symmetric triple well potential, may cause a symmetry breaking
and a difference in relative stability of the two side wells with respect to
the middle one. This leads to an asymmetric localization of population and
splitting of Kramers' rate of escape from the middle well, ensuring a
preferential distribution of the products in the course of a parallel reaction
A semiclassical theory of a dissipative Henon-Heiles system
A semiclassical theory of a dissipative Henon-Heiles system is proposed. Based on ¯h-scaling of an equation for the evolution of the Wigner quasiprobability distribution function in the presence of dissipation and thermal diffusion, we derive a semiclassical equation for quantum fluctuations, governed by the dissipation and the curvature of the classical potential. We show how the initial quantum noise gets amplified by classical chaotic diffusion, which is expressible in terms of a correlation of stochastic fluctuations of the curvature of the potential due to classical chaos, and ultimately settles down to equilibrium under the influence of dissipation. We also establish that there exists a critical limit to the expansion of phase space. The limit is set by chaotic diffusion and dissipation. Our semiclassical analysis is corroborated by numerical simulation of a quantum operator master equation
Quantum Kramers' equation for energy diffusion and barrier crossing dynamics in the low friction regime
Based on a true phase space probability distribution function and an ensemble
averaging procedure we have recently developed [Phys. Rev. E 65, 021109 (2002)]
a non-Markovian quantum Kramers' equation to derive the quantum rate
coefficient for barrier crossing due to thermal activation and tunneling in the
intermediate to strong friction regime. We complement and extend this approach
to weak friction regime to derive quantum Kramers' equation in energy space and
the rate of decay from a metastable well. The theory is valid for arbitrary
temperature and noise correlation. We show that depending on the nature of the
potential there may be a net reduction of the total quantum rate below its
corresponding classical value which is in conformity with earlier observation.
The method is independent of path integral approaches and takes care of quantum
effects to all orders.Comment: 26 pages, RevTe
Approach to Quantum Kramers' Equation and Barrier Crossing Dynamics
We have presented a simple approach to quantum theory of Brownian motion and
barrier crossing dynamics. Based on an initial coherent state representation of
bath oscillators and an equilibrium canonical distribution of quantum
mechanical mean values of their co-ordinates and momenta we have derived a
-number generalized quantum Langevin equation. The approach allows us to
implement the method of classical non-Markovian Brownian motion to realize an
exact generalized non-Markovian quantum Kramers' equation. The equation is
valid for arbitrary temperature and friction. We have solved this equation in
the spatial diffusion-limited regime to derive quantum Kramers' rate of barrier
crossing and analyze its variation as a function of temperature and friction.
While almost all the earlier theories rest on quasi-probability distribution
functions (like Wigner function) and path integral methods, the present work is
based on {\it true probability distribution functions} and is independent of
path integral techniques. The theory is a natural extension of the classical
theory to quantum domain and provides a unified description of thermal
activated processes and tunneling.Comment: RevTex, 18 pages, 2 figures; Minor corrections; To appear in Phys.
Rev.
A simple semiclassical approach to the Kramers' problem
We show that the Wigner-Leggett-Caldeira equation for Wigner phase space distribution function which describes the quantum Brownian motion of a particle in a force field in a high temperature, ohmic environment can be identified as a semiclassical version of Kramers' equation. Based on an expansion in powers of ℏ, we solve this equation to calculate the semiclassical correction to Kramers' rat
Chaos and information entropy production
We consider a general N-degrees-of-freedom nonlinear system which is chaotic and dissipative, and show that the nature of chaotic diffusion is reflected in the correlation of fluctuation of the linear stability matrix for the equation of motion of the dynamical system whose phase space variables behave as stochastic variables in the chaotic regime. Based on a Fokker-Planck description of the system in the associated tangent space and an information entropy balance equation, a relationship between chaotic diffusion and the thermodynamically inspired quantities such as entropy production and entropy flux is established. The theoretical propositions have been verified by numerical experiments
Quantum escape kinetics over a fluctuating barrier
The escape rate of a particle over a fluctuating barrier in a double well
potential exhibits resonance at an optimum value of correlation time of
fluctuation. This has been shown to be important in several variants of kinetic
model of chemical reactions . We extend the analysis of this phenomenon of
resonant activation to quantum domain to show how quantization significantly
enhances resonant activation at low temperature due to tunneling