CO diffusion into amorphous H2O ices

The mobility of atoms, molecules, and radicals in icy grain mantles regulates ice restructuring, desorption, and chemistry in astrophysical environments. Interstellar ices are dominated by H2O, and diffusion on external and internal (pore) surfaces of H2O-rich ices is therefore a key process to constrain. This study aims to quantify the diffusion kinetics and barrier of the abundant ice constituent CO into H2O-dominated ices at low temperatures (15–23 K), by measuring the mixing rate of initially layered H2O(:CO2)/CO ices. The mixed fraction of CO as a function of time is determined by monitoring the shape of the infrared CO stretching band. Mixing is observed at all investigated temperatures on minute timescales and can be ascribed to CO diffusion in H2O ice pores. The diffusion coefficient and final mixed fraction depend on ice temperature, porosity, thickness, and composition. The experiments are analyzed by applying Fick's diffusion equation under the assumption that mixing is due to CO diffusion into an immobile H2O ice. The extracted energy barrier for CO diffusion into amorphous H2O ice is ~160 K. This is effectively a surface diffusion barrier. The derived barrier is low compared to current surface diffusion barriers in use in astrochemical models. Its adoption may significantly change the expected timescales for different ice processes in interstellar environments.Astronom

Desorption Kinetics and Binding Energies of Small Hydrocarbons

Small hydrocarbons are an important organic reservoir in protostellar and protoplanetary environments. Constraints on desorption temperatures and binding energies of such hydrocarbons are needed for accurate predictions of where these molecules exist in the ice versus gas phase during the different stages of star and planet formation. Through a series of temperature programmed desorption experiments, we constrain the binding energies of 2- and 3-carbon hydrocarbons (C_2H_2—acetylene, C_2H_4—ethylene, C_2H_6—ethane, C_3H_4—propyne, C_3H_6—propene, and C_3H_8—propane) to 2200–4200 K in the case of pure amorphous ices, to 2400–4400 K on compact amorphous H_2O, and to 2800–4700 K on porous amorphous H_2O. The 3-carbon hydrocarbon binding energies are always larger than the 2-carbon hydrocarbon binding energies. Within the 2- and 3-carbon hydrocarbon families, the alkynes (i.e., least-saturated) hydrocarbons exhibit the largest binding energies, while the alkane and alkene binding energies are comparable. Binding energies are ~5%–20% higher on water ice substrates compared to pure ices, which is a small increase compared to what has been measured for other volatile molecules such as CO and N_2. Thus in the case of hydrocarbons, H_2O has a less pronounced effect on sublimation front locations (i.e., snowlines) in protoplanetary disks

Condensed-Phase Photochemistry in the Absence of Radiation Chemistry

We report post-irradiation photochemistry studies of condensed ammonia using photons of energies below condensed ammonia’s ionization threshold of ~ 9 eV. Hydrazine (N2H4), diazene (also known as diimide and diimine) (N2H2), triazane (N3H5), and one or more isomers of N3H3 are detected as photochemistry products during temperature-programmed desorption. Product yields increase monotonically with (1) photon fluence and (2) film thickness. In the studies reported herein, the energies of photons responsible for product formation are constrained to less than 7.4 eV. Previous post-irradiation photochemistry studies of condensed ammonia employed photons sufficiently energetic to ionize condensed ammonia and initiate radiation chemistry. Such studies typically involve ion-molecule reactions and electron-induced reactions in addition to photochemistry. Although photochemistry is cited as a dominant mechanism for the synthesis of prebiotic molecules in interstellar ices, to the best of our knowledge, ours is one of the first astrochemically-relevant studies that has found unambiguous evidence for condensed-phase chemical synthesis induced by photons in the absence of ionization

Giant magnetoresistance in manganese oxides

Giant magnetoresistance (GMR) was known to occur in metallic bilayers and granular materials. In 1993, GMR was also found to occur in thin films of manganates of the formula $La_{1-x}A_xMnO_3$ (A=alkaline earth metal). Since then, there has been intense research activity relating to the GMR of rare earth manganates and other oxides

Giant magnetoresistance in manganese oxides

Giant magnetoresistance (GMR) was known to occur in metallic bilayers and granular materials. In 1993, GMR was also found to occur in thin films of manganates of the formula La1−xAxMnO3 (A=alkaline earth metal). Since then, there has been intense research activity relating to the GMR of rare earth manganates and other oxides