52 research outputs found
RIED. Revista iberoamericana de educación a distancia
Resumen basado en el de la publicaciónTítulo, resumen y palabras clave también en inglésMonográfico con el título: “La integración efectiva del dispositivo móvil en la educación y en el aprendizaje"Se plantea el debate sobre las innovaciones y tecnologías disruptivas, proponiendo que el aprendizaje digital (nueva versión de la educación a distancia) está suponiendo una disrupción educativa porque plantea un cambio drástico de soportes y métodos y porque progresivamente va ganando espacio a los formatos convencionales. Se concluye afirmando que esta tendencia no está agotada, sino que continúa penetrando y ahondando la ruptura con las nuevas tecnologías, como, por ejemplo, las analíticas de aprendizaje, el aprendizaje adaptativo y el aprendizaje móvil.ES
High Sensing Properties of 3 wt % Pd-Doped SmFe<sub>1–<i>x</i></sub>Mg<sub><i>x</i></sub>O<sub>3</sub> Nanocrystalline Powders to Acetone Vapor with Ultralow Concentrations under Light Illumination
Nanocrystalline
powders of 3 wt % Pd-doped SmFe<sub>1–<i>x</i></sub>Mg<sub><i>x</i></sub>O<sub>3</sub> (<i>x</i> =
0, 0.1, 0.2, and 0.3) were prepared by a sol–gel method and
annealed at 750 °C. Pd:SmFe<sub>0.9</sub>Mg<sub>0.1</sub>O<sub>3</sub> has a maximum response at 220 °C. When exposed to 0.5
ppm acetone vapor, the response of undoped SmFeO<sub>3</sub> is 2.26
and the response of Pd:SmFe<sub>0.9</sub>Mg<sub>0.1</sub>O<sub>3</sub> is 7.16. Under light illumination, Pd:SmFe<sub>0.9</sub>Mg<sub>0.1</sub>O<sub>3</sub> has a better sensing performance and lower optimal
operating temperature. The sensor shows good selectivity and stability
for acetone vapor. The high response and good selectivity of Pd:SmFe<sub>0.9</sub>Mg<sub>0.1</sub>O<sub>3</sub> to ultralow concentrations
of acetone vapor indicate its potential for applications in many areas
[[(Ethoxycarbonyl)difluoromethyl]thio]phthalimide: A Shelf-Stable, Electrophilic Reagent with a Convertible Group for the Synthesis of Diversified Fluoroalkylthiolated Compounds
A shelf-stable
and easily convertible reagent for the preparation
of diversified fluoroalkylthiolated compounds, [[(ethoxycarbonyl)difluoromethyl]thio]phthalimide,
was developed. [[(Ethoxycarbonyl)difluoromethyl]thio]phthalimide
is an efficient electrophilic fluoroallylthiolating reagent that reacted
with electron-rich heteroarenes/arenes, β-ketoesters, oxindoles,
benzofuranones, and thiols. More importantly, the ethoxycarbonyl group
of the resulting fluoroalkylthiolated compounds could be easily converted
into various other functional groups such as chloride, alkynyl, hydrocarbonyl,
carbomoyl, hydromethyl, or heteroaryl groups
Nitrogen-Doped Carbon-Based Acidic Ionic Liquid Hollow Nanospheres for Efficient and Selective Conversion of Fructose to 5‑Ethoxymethylfurfural and Ethyl Levulinate
Nitrogen-doped
carbon-based acidic ionic liquid hollow nanospheres,
[C<sub>3</sub>N][SO<sub>3</sub>CF<sub>3</sub>]-HCSs (C<sub>3</sub> = <i>Pr</i>SO<sub>3</sub>H), with different particle sizes
(100–900 nm) and shell thicknesses (5–25 nm) as well
as interesting morphology-dependent porosity properties were successfully
prepared via quaternary ammonization of nitrogen atoms of hollow nitrogen-doped
carbon nanospheres by 1,3-propane sultone followed by anion exchange
with trifluoromethanesulonic acid. The [C<sub>3</sub>N][SO<sub>3</sub>CF<sub>3</sub>]-HCSs were applied in selective conversion
of fructose (FOS) to promising fuel blends, 5-ethoxymethylfurfural
(5-EMF) and ethyl levulinate (EL). It showed the [C<sub>3</sub>N][SO<sub>3</sub>CF<sub>3</sub>]-HCSs exhibited high total yields of 5-EMF
and EL (higher than 90%), regardless of their particle size and shell
thickness, attributed to extremely high selectivity to both compounds,
and thereby, very few side products including soluble oligomers and
humins were produced. Additionally, the product distribution strongly
depended on the morphology and porosity properties of the [C<sub>3</sub>N][SO<sub>3</sub>CF<sub>3</sub>]-HCSs. [C<sub>3</sub>N][SO<sub>3</sub>CF<sub>3</sub>]-HCSs-<b>1</b> with the smallest particle size,
thinnest shell, and largest Brunauer–Emmett–Teller (BET)
surface area possessed the highest EL yield (89.7%), while [C<sub>3</sub>N][SO<sub>3</sub>CF<sub>3</sub>]-HCSs-<b>4</b> with
the smallest particle size, thickest shell, and smallest BET surface
area gave rise to the highest 5-EMF yield (67.2%). More importantly,
the [C<sub>3</sub>N][SO<sub>3</sub>CF<sub>3</sub>]-HCSs can be reused
five times without changes in catalytic activity, Brønsted acid
nature, morphology, and porosity properties
Vertically Aligned Graphene Sheets Membrane for Highly Efficient Solar Thermal Generation of Clean Water
Efficient
utilization of solar energy for clean water is an attractive,
renewable, and environment friendly way to solve the long-standing
water crisis. For this task, we prepared the long-range vertically
aligned graphene sheets membrane (VA-GSM) as the highly efficient
solar thermal converter for generation of clean water. The VA-GSM
was prepared by the antifreeze-assisted freezing technique we developed,
which possessed the run-through channels facilitating the water transport,
high light absorption capacity for excellent photothermal transduction,
and the extraordinary stability in rigorous conditions. As a result,
VA-GSM has achieved average water evaporation rates of 1.62 and 6.25
kg m<sup>–2</sup> h<sup>–1</sup> under 1 and 4 sun illumination
with a superb solar thermal conversion efficiency of up to 86.5% and
94.2%, respectively, better than that of most carbon materials reported
previously, which can efficiently produce the clean water from seawater,
common wastewater, and even concentrated acid and/or alkali solutions
Trifluoromethyl-Substituted Sulfonium Ylide: Rh-Catalyzed Carbenoid Addition to Trifluoromethylthioether
A highly efficient
Rh-catalyzed carbenoid addition to trifluoromethylthioether
for the formation of trifluoromethyl-substituted sulfonium ylide is
described. The trifluoromethyl-substituted sulfonium ylide can
act as an electrophilic trifluoromethylation reagent, as demonstrated
by trifluoromethylation of β-ketoesters and aryl iodides
Comparisons between our method and some state-of-the-art systems.
<p>Comparisons between our method and some state-of-the-art systems.</p
An example of the maximum matching in the bipartite graph.
<p><i>Cona</i> and <i>Conb</i> are two different contexts. The maximal matching between <i>Cona</i> and <i>Conb</i> is flagged with solid lines. Edges with weight 0 are bypassed and all weights are rounding in this figure.</p
The ROC curves of three experiments: the feature-based kernel, the combination of feature-based kernel and DET kernel, and the kernel integrating three individual kernels.
<p>The ROC curves of three experiments: the feature-based kernel, the combination of feature-based kernel and DET kernel, and the kernel integrating three individual kernels.</p
- …