Formation of rectifier with gold nanoclusters

Gold nanoclusters encapsulated with organic molecules are of great interest for its possible applications in the fields of molecular electronics, catalysis and medical science. Here we demonstrate that monolayer and bilayer films of thiol-capped gold nanoclusters can exhibit diode-like properties provided controlled spatial asymmetry exist between two tunnel junctions used to connect a thiol capped gold nanoclusters. Current-voltage characteristics of this rectifier were obtained from conducting probe atomic force microscopy measurements and also from conventional two probe resistance measurements. Systematic x-ray reflectivity and atomic force microscopy measurements were carried out to characterize the spatial asymmetry introduced by a monolayer of fatty acid salt gadolinium stearate used to deposit thiol-capped gold nanocluster molecules on hydrophilic SiO2-Si(001) substrate by Langmuir Blodgett technique. This information was used to explain prominent rectification observed in these nano-structured films.Comment: 13 pages, 3 figure

Amorphization of Vortex Matter and Reentrant Peak Effect in YBa2_2Cu3_3O7−δ_{7-\delta}

The peak effect (PE) has been observed in a twinned crystal of YBa$_2$Cu$_3$O$_{7-\delta}$ for H$\parallel$c in the low field range, close to the zero field superconducting transition temperature (T$_c$(0)) . A sharp depinning transition succeeds the peak temperature T$_p$ of the PE. The PE phenomenon broadens and its internal structure smoothens out as the field is increased or decreased beyond the interval between 250 Oe and 1000 Oe. Moreover, the PE could not be observed above 10 kOe and below 20 Oe. The locus of the T$_p$(H) values shows a reentrant characteristic with a nose like feature located at T$_p$(H)/T$_c$(0)$\approx$0.99 and H$\approx$100 Oe (where the FLL constant a$_0$$\approx$penetration depth $\lambda$). The upper part of the PE curve (0.5 kOe$<$H$<$10 kOe) can be fitted to a melting scenario with the Lindemann number c$_L$$\approx$0.25. The vortex phase diagram near T$_c$(0) determined from the characteristic features of the PE in YBa$_2$Cu$_3$O$_{7-\delta}$(H$\parallel$c) bears close resemblance to that in the 2H-NbSe$_2$ system, in which a reentrant PE had been observed earlier.Comment: 15 pages and 7 figure

QPO Evolution in 2005 Outburst of the Galactic Nano Quasar GRO J1655-40

GRO J1655-40 showed significant X-ray activity in the last week of February, 2005 and remained active for the next 260 days. The rising and the decline phases of this particular outburst show evidence for systematic movements of the Comptonizing region, assumed to be a CENBOL, which causes the Quasi-periodic Oscillations or QPOs. We present both the spectral and the timing results of the RXTE/PCA data taken from these two hard spectral states. Assuming that the QPOs originate from an oscillating shock CENBOL, we show how the shock slowly moves in through the accretion flow during the rising phase at a constant velocity and accelerate away outward during the later part of the decline phase. By fitting the observed frequencies with our solution, we extract time variation of various disk parameters such as the shock locations, velocity etc.Comment: 5 Pages, 2 Figures, Proceeding of the 2nd Kolkata Conference on "Observational Evidence for the Black Holes in the Universe", Published in AIP, 200

Phase transitions in Lu2_2Ir3_3Si5_5

We report the results of our investigations on a polycrystalline sample of Lu$_2$Ir$_3$Si$_5$ which crystallizes in the U$_2$Co$_3$Si$_5$ type structure (Ibam). These investigations comprise powder X-ray diffraction, magnetic susceptibility, electrical resistivity and high temperature (120-300 K) heat capacity studies. Our results reveal that the sample undergoes a superconducting transition below 3.5 K. It also undergoes a first order phase transition between 150-250 K as revealed by an upturn in the resistivity, a diasmagnetic drop in the magnetic susceptibility and a large anomaly (20-30 J/mol K) in the specific heat data. We observe a huge thermal hysteresis of almost 45 K between the cooling and warming data across this high temperature transition in all our measurements. Low temperature X-ray diffraction measurements at 87 K reveals that the compound undergoes a structural change at the high temperature transition. Resistivity data taken in repeated cooling and warming cycles indicate that at the high temperature transition, the system goes into a highly metastable state and successive heating/cooling curves are found to lie above the previous one and the resistance keeps increasing with every thermal cycle. The room temperature resistance of a thermaly cycled piece of the sample decays exponentialy with time with a decay time constant estimated to be about 10$^4$ secs. The anomaly (upturn) in the resistivity and the large drop (almost 45%) in the susceptibility across the high temperature transition suggest that the observed structural change is accompanied or induced by an electronic transition.Comment: 7 figures, 1 table and 18 reference

Feasibility of a Carbon Consumption Tax for Sustainable Development – a Case Study of India

Global climate change is a major issue confronting policymakers worldwide, and there is widespread scientific acceptance of the reality of climate change and its adverse consequences In terms of economic analysis, greenhouse gas emissions (GHG), which cause planetary climate changes, represent both an environmental externality and the overuse of a common property resource. The paper is premised around the hypothesis that tax policy can be used to address climate concerns by making less Green House Gas intensive purchases and investments more financially attractive. However, in the absence of an International framework capping GHG emissions, countries adopting mitigation policies incur costs that would not exist under global cooperation such as the loss of competitiveness and emissions leakage. A consumption tax based on the carbon footprint of a product levied on all products at the point of purchase by the final end-user, regardless of where the goods are produced using a Credit-method would be capable of addressing these concerns of emissions leakage and loss of competitiveness, while being WTO compliant. The author intends to test the feasibility and effectiveness of such a carbon consumption tax in the Indian Context. The author shall test the feasibility of levy of such a consumption tax in the context of India and evaluate the effectiveness in mitigating climate change and catering to the goal of sustainable development