Determination of metabolite profiles in tropical wines by 1H NMR spectroscopy and chemometrics.

The aim of this work was to determine metabolite profiles of tropical wines produced in northeast Brazil, by using 1H NMR spectroscopy in comoination with chemometric methods to analyze and discrirninate wine samples from 2007 vintages produced by different wineries

Use of chemometrics to characterize tropical wines from different vintages and grape cultivars according to the 1H NMR spectroscopy data.

Resumo

Use of chemometrics to characterize tropical wines from different vintages and grape cultivars according to the 1H NMR spectroscopy data.

Tropical wines have been produced in Northeast of Brazil since 1980's, between the 8° and 9° S latitude, in a region called Sub-rniddle São Francisco river Valley. This area presents an intra-annual climate variability and wines can be elaborated in different months of the year, according to the winery, with different analytical characteristics due to the climatic conditions. NMR spectroscopy is an interesting tool that allows to determine in a single analysis many analytical compounds of the wines. PCA and PLS rnultivariate statistical analyses applied on NMR data allow to discriminate samples and to identify the responsible compounds for the clustering. The aim of this work was to use chemometrics, PCA and PLS, applied on IH NMR spectroscopy data, to characterize tropical wines from different vintages and grape cultivars, in Northeast of Brazil. Wines were elaborated by using traditional winemaking process with control of the fermentations temperature and use of antioxidants. Before statistical analyses, IHNMR spectra were segmented, normalized, converted to Excel software format and further processed for PCA and PLS analyses. Statistical analyses applied on NMR spectra data were not satisfactory to discriminate between different vintages of white and red wines together, but they were able to separate each one according to different vintages and cultivars. Metabolic compounds were found to explain wine clusters, and fingerprints are discussed

Tailoring the thermal Casimir force with graphene

The Casimir interaction is omnipresent source of forces at small separations between bodies, which is difficult to change by varying external conditions. Here we show that graphene interacting with a metal can have the best known force contrast to the temperature and the Fermi level variations. In the distance range 50–300 nm the force is measurable and can vary a few times for graphene with a bandgap much larger than the temperature. In this distance range the main part of the force is due to the thermal fluctuations. We discuss also graphene on a dielectric membrane as a technologically robust configuration

Metabolic profiles of Brazilian tropical wines determined by H NMR spectroscopy and chemometrics.

Tropical wines are a new concept of vitiviniculture that is being developped principally in Brazil

Avaliação da qualidade de semente de soja produzida nas safras de 1976/77 e 1978/79 no Estado do Paraná.

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Antecipação de colheita de sementes de soja através do uso de dessecantes.

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Competition between excitonic gap generation and disorder scattering in graphene

We study the disorder effect on the excitonic gap generation caused by strong Coulomb interaction in graphene. By solving the self-consistently coupled equations of dynamical fermion gap $m$ and disorder scattering rate $\Gamma$, we found a critical line on the plane of interaction strength $\lambda$ and disorder strength $g$. The phase diagram is divided into two regions: in the region with large $\lambda$ and small $g$, $m \neq 0$ and $\Gamma = 0$; in the other region, $m = 0$ and $\Gamma \neq 0$ for nonzero $g$. In particular, there is no coexistence of finite fermion gap and finite scattering rate. These results imply a strong competition between excitonic gap generation and disorder scattering. This conclusion does not change when an additional contact four-fermion interaction is included. For sufficiently large $\lambda$, the growing disorder may drive a quantum phase transition from an excitonic insulator to a metal.Comment: 8 pages, 1 figur

Influence of pre-slaughter management on cortisol level in lambs

This study aimed to verify the influence of the transport in open or closed compartments, followed by two resting periods (1 and 3 hours) for the slaughter process on the levels of cortisol as a indicative of stress level in lambs. The slaughterhouse was located 85 km away from the place of confinement and the transportation of the lambs was carried out in a cage truck type, each cage had a divider in the middle making the front without external visual access to the environment, and the back portion of the cages with visual access to the road. At the slaughterhouse, blood samples were taken from 86 lambs after the transport and before slaughter (1 or 3 hours of resting) for plasma cortisol analysis. Variables were evaluated through the PROC GLM procedure from the Statistical Analysis System ©, version 9.1.3 software.The method of transport influenced in the cortisol concentration (P<0.01), the animals transported in the closed compartment had a lower level. After the resting period in the slaughterhouse, there was a decline in the plasmatic cortisol concentration, with the animals subjected to three hours of rest presenting the lower average cortisol value (P<0.05). It can be inferred that the lambs that remained three hours in standby before slaughter had more time to recover from the stress of the transportation than those that waited just one hour. Visual access to the external environment during the transport of the lambs is a stressful factor changing the level of plasmatic cortisol, and the resting period before slaughter was effective in lowering stress, reducing the plasmatic cortisol in the lambs