The phase separation behavior of poly(vinyl methyl ether)/polystyrene semi-IPN/

The effect of crosslinking on the phase stability and phase separation behavior of poly(vinyl methyl ether)/polystyrene semi-IPN was studied by light scattering. The cloud point temperature was measured as a function of degree of crosslinking and found to be constant within experimental precision. The result of this experiment was combined with a theoretical prediction of the phase diagram to determine conditions for the following experiment. Wide angle light scattering was used to quantitatively analyze the mechanism and dynamics of the thermally induced phase separation with respect to the crosslinking density and the thermal condition. An apparatus with a one dimensional diode array was used to simultaneously monitor a wide range of scattering angles. Analysis of the early stages of phase separation indicates that the spinodal temperature remained virtually constant whether or not crosslinks were present in the system. This was demonstrated to be consistent with theoretical prediction. However, the apparent diffusion coefficient decreased dramatically with the introduction of crosslinks thus the initial phase separation was slowed down significantly. The final scattering intensity was shown to decrease with increasing crosslinking density. The scattering vector dependence of the scattering intensity was negligible compared with its overall time dependence. A plateau region was observed for some of the scattering intensity data of the semi-IPN systems with respect to time. This indicates that the crosslinks restrict terminal phase contrast and not the size of phase

Optical Evidence of Itinerant-Localized Crossover of 4f4f Electrons in Cerium Compounds

Cerium (Ce)-based heavy-fermion materials have a characteristic double-peak structure (mid-IR peak) in the optical conductivity [$\sigma(\omega)$] spectra originating from the strong conduction ($c$)--$f$ electron hybridization. To clarify the behavior of the mid-IR peak at a low $c$-$f$ hybridization strength, we compared the $\sigma(\omega)$ spectra of the isostructural antiferromagnetic and heavy-fermion Ce compounds with the calculated unoccupied density of states and the spectra obtained from the impurity Anderson model. With decreasing $c$-$f$ hybridization intensity, the mid-IR peak shifts to the low-energy side owing to the renormalization of the unoccupied $4f$ state, but suddenly shifts to the high-energy side owing to the $f$-$f$ on-site Coulomb interaction at a slight localized side from the quantum critical point (QCP). This finding gives us information on the change in the electronic structure across QCP.Comment: 6 pages, 4 figures. To appear in JPSJ (Letters

Little IIB Matrix Model

We study the zero-dimensional reduced model of D=6 pure super Yang-Mills theory and argue that the large N limit describes the (2,0) Little String Theory. The one-loop effective action shows that the force exerted between two diagonal blocks of matrices behaves as 1/r^4, implying a six-dimensional spacetime. We also observe that it is due to non-gravitational interactions. We construct wave functions and vertex operators which realize the D=6, (2,0) tensor representation. We also comment on other "little" analogues of the IIB matrix model and Matrix Theory with less supercharges.Comment: 17 pages, references adde

Fans and polytopes in tilting theory II: gg-fans of rank 2

The $g$-fan of a finite dimensional algebra is a fan in its real Grothendieck group defined by tilting theory. We give a classification of complete $g$-fans of rank 2. More explicitly, our first main result asserts that every complete sign-coherent fan of rank 2 is a $g$-fan of some finite dimensional algebra. Our proof is based on three fundamental results, Gluing Theorem, Rotation Theorem and Subdivision Theorem, which realize basic operations on fans in the level of finite dimensional algebras. For each of 16 convex sign-coherent fans $\Sigma$ of rank 2, our second main result gives a characterization of algebras $A$ of rank 2 satisfying $\Sigma(A)=\Sigma$. As a by-product of our method, we prove that for each positive integer $N$, there exists a finite dimensional algebra $A$ of rank 2 such that the Hasse quiver of the poset of 2-term silting complexes of $A$ has precisely $N$ connected components.Comment: 37 pages, v2: Fixed typos, updated references and added section

Fans and polytopes in tilting theory

For a finite dimensional algebra $A$ over a field $k$, the 2-term silting complexes of $A$ gives a simplicial complex $\Delta(A)$ called the $g$-simplicial complex. We give tilting theoretic interpretations of the $h$-vectors and Dehn-Sommerville equations of $\Delta(A)$. Using $g$-vectors of 2-term silting complexes, $\Delta(A)$ gives a nonsingular fan $\Sigma(A)$ in the real Grothendieck group $K_0(\mathrm{proj } A)_\mathbb{R}$ called the $g$-fan. For example, the fan of $g$-vectors of a cluster algebra is given by the $g$-fan of a Jacobian algebra of a non-degenerate quiver with potential. We give several properties of $\Sigma(A)$ including idempotent reductions, sign-coherence, Jasso reductions and a connection with Newton polytopes of $A$-modules. Moreover, $\Sigma(A)$ gives a (possibly infinite and non-convex) polytope $P(A)$ in $K_0(\mathrm{proj } A)_\mathbb{R}$ called the $g$-polytope of $A$. We call $A$ $g$-convex if $P(A)$ is convex. In this case, we show that it is a reflexive polytope, and that the dual polytope is given by the 2-term simple minded collections of $A$. We give an explicit classification of $g$-convex algebras of rank $2$. We classify algebras whose $g$-polytopes are smooth Fano. We classify classical and generalized preprojective algebras which are $g$-convex, and also describe their $g$-polytope as the dual polytopes of short root polytopes of type $A$ and $B$. We also classify Brauer graph algebras which are $g$-convex, and describe their $g$-polytopes as root polytopes of type $A$ and $C$.Comment: 70 page