Chemical Freeze-out of Strange Particles and Possible Root of Strangeness Suppression

Two approaches to treat the chemical freeze-out of strange particles in hadron resonance gas model are analyzed. The first one employs their non-equillibration via the usual \gamma_s factor and such a model describes the hadron multiplicities measured in nucleus-nucleus collisions at AGS, SPS and RHIC energies with \chi^2/dof = 1.15. Surprisingly, at low energies we find not the strangeness suppression, but its enhancement. Also we suggest an alternative approach to treat the strange particle freeze-out separately, but with the full chemical equilibration. This approach is based on the conservation laws which allow us to connect the freeze-outs of strange and non-strange hadrons. Within the suggested approach the same set of hadron multiplicities can be described better than within the conventional approach with \chi^2/dof = 1.06. Remarkably, the fully equilibrated approach describes the strange hyperons and antihyperons much better than the conventional one.Comment: 6 pages, 5 figure

Evolution of Baryon-Free Matter Produced in Relativistic Heavy-Ion Collisions

A 3-fluid hydrodynamic model is introduced for simulating heavy-ion collisions at incident energies between few and about 200 AGeV. In addition to the two baryon-rich fluids of 2-fluid models, the new model incorporates a third, baryon-free (i.e. with zero net baryonic charge) fluid which is created in the mid-rapidity region. Its evolution is delayed due to a formation time $\tau$, during which the baryon-free fluid neither thermalizes nor interacts with the baryon-rich fluids. After formation it thermalizes and starts to interact with the baryon-rich fluids. It is found that for $\tau$=0 the interaction strongly affects the baryon-free fluid. However, at reasonable finite formation time, $\tau$=1 fm/c, the effect of this interaction turns out to be substantially reduced although still noticeable. Baryonic observables are only slightly affected by the interaction with the baryon-free fluid.Comment: 17 pages, 3 figures, submitted to the issue of Phys. of Atomic Nuclei dedicated to S.T. Belyaev on the occasion of his 80th birthday, typos correcte

Catalytic hydroboration by an imido-hydrido complex of Mo(IV)

The imido-hydrido complex (ArN)Mo(H)(Cl)(PMe3)3 catalyses a variety of hydroboration reactions, including the first example of catalytic addition of HBCat to nitriles to form the bis(borylated) amines RCH2N(BCat)2. The latter species easily undergoes chemoselective coupling with aldehydes R0C(O)H to yield imines RCH2NQC(H)R

Hadron Resonance Gas Model with Induced Surface Tension

Here we present a physically transparent generalization of the multicomponent Van der Waals equation of state in the grand canonical ensemble. For the one-component case the third and fourth virial coefficients are calculated analytically. It is shown that an adjustment of a single model parameter allows us to reproduce the third and fourth virial coefficients of the gas of hard spheres with small deviations from their exact values. A thorough comparison of the compressibility factor and speed of sound of the developed model with the one and two component Carnahan-Starling equation of state is made. It is shown that the model with the induced surface tension is able to reproduce the results of the Carnahan-Starling equation of state up to the packing fractions 0.2-0.22 at which the usual Van der Waals equation of state is inapplicable. At higher packing fractions the developed equation of state is softer than the gas of hard spheres and, hence, it breaks causality in the domain where the hadronic description is expected to be inapplicable. Using this equation of state we develop an entirely new hadron resonance gas model and apply it to a description of the hadron yield ratios measured at AGS, SPS, RHIC and ALICE energies of nuclear collisions. The achieved quality of the fit per degree of freedom is about 1.08. We confirm that the strangeness enhancement factor has a peak at low AGS energies, while at and above the highest SPS energy of collisions the chemical equilibrium of strangeness is observed. We argue that the chemical equilibrium of strangeness, i.e. $\gamma_s \simeq 1$, observed above the center of mass collision energy 4.3 GeV may be related to the hadronization of quark gluon bags which have the Hagedorn mass spectrum, and, hence, it may be a new signal for the onset of deconfinement

Catalytic hydroboration by an imido-hydrido complex of Mo(IV)

The imido-hydrido complex (ArN)Mo(H)(Cl)(PMe3)3 catalyses a variety of hydroboration reactions, including the first example of catalytic addition of HBCat to nitriles to form the bis(borylated) amines RCH2N(BCat)2. The latter species easily undergoes chemoselective coupling with aldehydes R0C(O)H to yield imines RCH2NQC(H)R