554 research outputs found

    Accurate determination of tensor network state of quantum lattice models in two dimensions

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    We have proposed a novel numerical method to calculate accurately the physical quantities of the ground state with the tensor-network wave function in two dimensions. We determine the tensor network wavefunction by a projection approach which applies iteratively the Trotter-Suzuki decomposition of the projection operator and the singular value decomposition of matrix. The norm of the wavefunction and the expectation value of a physical observable are evaluated by a coarse grain renormalization group approach. Our method allows a tensor-network wavefunction with a high bond degree of freedom (such as D=8) to be handled accurately and efficiently in the thermodynamic limit. For the Heisenberg model on a honeycomb lattice, our results for the ground state energy and the staggered magnetization agree well with those obtained by the quantum Monte Carlo and other approaches.Comment: 4 pages 5 figures 2 table

    Photo-lability of deep ocean dissolved black carbon

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    Dissolved black carbon (DBC), defined here as condensed aromatics isolated from seawater via PPL solid phase extraction and quantified as benzenepolycarboxylic acid (BPCA) oxidation products, is a significant component of the oceanic dissolved organic carbon (DOC) pool. These condensed aromatics are widely distributed in the open ocean and appear to be tens of thousands of years old. As such DBC is regarded as highly refractory. In the current study, the photo-lability of DBC, DOC and coloured dissolved organic matter (CDOM; ultraviolet-visible absorbance) were determined over the course of a 28 day irradiation of North Atlantic Deep Water under a solar simulator. During the irradiation DBC fell from 1044 ± 164 nM-C to 55 ± 15 nM-C, a 20-fold decrease in concentration. Dissolved black carbon photo-degradation was more rapid and more extensive than for bulk CDOM and DOC. The concentration of DBC correlated with CDOM absorbance and the quality of DBC indicated by the ratios of different BPCAs correlated with CDOM absorbance spectral slope, suggesting the optical properties of CDOM may provide a proxy for both DBC concentrations and quality in natural waters. Further, the photo-lability of components of the DBC pool increased with their degree of aromatic condensation. These trends indicate that a continuum of compounds of varying photo-lability exists within the marine DOC pool. In this continuum, photo-lability scales with aromatic character, specifically the degree of condensation. Scaling the rapid photo-degradation of DBC to rates of DOC photo-mineralisation for the global ocean leads to an estimated photo-chemical half-life for oceanic DBC of less than 800 years. This is more than an order of magnitude shorter than the apparent age of DBC in the ocean. Consequently, photo-degradation is posited as the primary sink for oceanic DBC and the apparent survival of DBC molecules in the oceans for millennia appears to be facilitated not by their inherent inertness but by the rate at which they are cycled through the surface ocean's photic zone

    Chlorin Index: A new parameter for organic matter freshness in sediments

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    Total chlorins, comprising degradation products of chlorophyll, have been used recently to reconstruct paleoproductivity from marine sediment cores. Here, we report on a new index, the Chlorin Index (CI), that proves to be a helpful tool for rapidly estimating organic matter freshness in marine sediments. The CI is a ratio between the fluorescence intensity of a sediment extracted with acetone and treated with hydrochloric acid and the original sediment extract. It represents the ratio of chlorophyll and its degradation products deposited in the sediments that could still be chemically transformed and those that are inert to chemical attack. The ratio is lower in sediments that include freshly deposited phytoplankton material and higher in older, more degraded sediments. We measured this new parameter on surface sediments, and sediments from several short and a long sediment core from different oceanic settings. CI values range from 0.2 for chlorophyll a to 0.36–0.56 for fresh material deposited on the shelf off Namibia to values around 0.67 in sediments off Chile and Peru to values up to 0.97 for sediments in a deep core from the northeastern slope of the Arabian Sea. We have compared the CI to rates of bacterial sulfate reduction, as a direct measure of organic matter reactivity and to other degradation indices based on amino acid composition. We conclude that the CI is a reliable and simple tool for the characterization of organic material freshness in sediments in respect to its degradation state

    Myeloperoxidase and eosinophil cationic protein in serum and sputum during antibiotic treatment in cystic fibrosis patients with Pseudomonas aeruginosa infection

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    I order to study the time-course of myeloperoxidase (MPO) and eosinophil cationic protein (ECP) as parameters for monitoring inflammation in cystic fibrosis (CF), we investigated ten patients during both a 14-day intravenous antibiotic treatment and a corresponding self control. Modified Shwachman-Kulczycki score improved significantly (p < 0.008), C-reactive protein (CRP) levels decreased significantly (p < 0.05) during antibiotic treatment, while in the control phase there were no significant differences. Lung function parameters did not change significantly during antibiotic treatment or control phase. Serum MPO concentration (p < 0.006) and peripheral blood neutrophil granulocyte counts (p < 0.04) decreased significantly during antibiotic treatment, but not during the control phase. Sentm ECP concentration showed a tendency to decrease during antibiotic treatment, but this failed to reach significance. In general, sputum concentrations of MPO and ECP Were 500- to 1000-fold higher than in serum. However, neither MPO nor ECP in sputum showed a significan variation over time during antibiotic treatment or control phase. From our data we conclude that: (1) measurements of MPO, neutrophils and CRP in peripheral blood do correlate with clinical parameters such as the modified Shwachman-Kulczycki score; (2) neutrophils and MPO seem to reflect inflammatory changes induced by antibiotic treatment; (3) eosinophils may play a role in CF by an enhanced ‘releasability’ and (4) Sputum measurements of mediators of inflammation cannot be recommended

    Interleukin-4 (IL-4) enhances and soluble interleukin-4 receptor (sIL-4R) inhibits histamine release from peripheral blood basophils and mast cells in vitro and in vivo

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    The aim of the study was to analyse the effect of interleukin-4 (IL-4) on allergen and anti-IgE mediated histamine release from basophils and human skin mast cells and to assess whether soluble recombinant interleukin-4 receptor (sIL4R) can inhibit these effects. Anti-IgE stimulated histamine release from peripheral blood basophils and mast cells of atopic donors was enhanced after preincubation with IL-4, whereas after preincubation with sIL-4R it was inhibited. These effects were even more pronounced when samples were stimulated with a clinically relevant allergen. In IL-4 preincubated skin mast cells, there was a similar enhancement of anti-IgE stimulated histamine release, which could again be inhibited by sIL-4R. The effects of IL-4 and sIL4R were dose- and time-dependent. Mice sensitized to ovalbumin and treated with soluble recombinant murine sIL-4R showed significantly reduced immediate-type cutaneous hypersensitivity responses compared with untreated mice. These in vivo effects were IgE independent, since there were no significant differences in total and allergen specific IgE/IgG1 antibody titres between treated and untreated mice. This indicates that IL4 exerts priming effects on histamine release by effector cells of the allergic response and that these effects are potently antagonized by soluble IL-4R both in vitro and in vivo

    Biodegradability of hydrothermally altered deep-sea dissolved organic matter

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    Deep-sea dissolved organic matter (DOM) constitutes a huge carbon reservoir in the worlds' oceans that – despite its abundance – is virtually unused as a substrate by marine heterotrophs. Heating within hydrothermal systems induces major molecular modifications of deep-sea DOM. Here, we tested the hypothesis that hydrothermal heating of deep-sea DOM enhances bioavailability. Aliquots of DOM extracted from the deep North Pacific (North Equatorial Pacific Intermediate Water; NEqPIW) were re-dissolved in artificial seawater and subjected to temperatures of 100 and 200 °C (40 MPa) using Dickson-type reactors. In agreement with earlier findings we observed a temperature-related drop in dissolved organic carbon (DOC) concentration (−6.1% at 100 °C, −21.0% at 200 °C) that predominantly affected the solid-phase extractable (SPE-DOC) fraction (−18.2% at 100 °C, −51.4% at 200 °C). Fourier-transform ion cyclotron resonance mass spectrometric (FT-ICR-MS) analysis confirmed a temperature-related reduction of average molecular mass, O/C ratios, double bond equivalents (DBE) and a relative increase in aromaticity (AImod). This thermally altered DOM was added (25 μmol L−1 DOC) to deep-water samples from the South West Pacific (Kermadec Arc, RV Sonne / SO253, 32° 37.706′ S | 179° 38.728′ W) and incubated with the prevailing natural microbial community. After 16 days at 4 °C in the dark, prokaryotic cell counts in incubations containing the full spectrum of thermally-degraded DOM (extractable and non-extractable compounds) had increased considerably (on average 21× for DOM100°C and 27× for DOM200°C). In contrast, prokaryotic growth in incubations to which only solid-phase extractable thermally-altered DOM was added was not enhanced compared to control incubations. The experiments demonstrate that temperature-driven degradation of deep-sea recalcitrant DOM within hydrothermal systems turns fractions of it accessible to microbes. The thermally-produced DOM compounds that stimulate microbial growth are not retained on reversed-phase resins (SPE-DOM) and are likely low-molecular mass organic acids. Despite the comprehensive compositional modifications of the solid-phase extractable (SPE-DOM) fraction through heating, it remains inaccessible to microbes at the investigated concentration levels. The microbial incubation resulted in only minor and mostly insignificant overall changes in SPE-DOM molecular composition and concentration

    Magnetic Properties of Quantum Ferrimagnetic Spin Chains

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    Magnetic susceptibilities of spin-(S,s)(S,s) ferrimagnetic Heisenberg chains are numerically investigated. It is argued how the ferromagnetic and antiferromagnetic features of quantum ferrimagnets are exhibited as functions of (S,s)(S,s). Spin-(S,s)(S,s) ferrimagnetic chains behave like combinations of spin-(S−s)(S-s) ferromagnetic and spin-(2s)(2s) antiferromagnetic chains provided S=2sS=2s.Comment: 4 pages, 7 PS figures, to appear in Phys. Rev. B: Rapid Commu

    A compact and light-weight refractive telescope for the observation of extensive air showers

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    A general purpose instrument for imaging of Cherenkov light or fluorescence light emitted by extensive air showers is presented. Its refractive optics allows for a compact and light-weight design with a wide field-of-view of 12{\deg}. The optical system features a 0.5 m diameter Fresnel lens and a camera with 61 pixels composed of Winston cones and large-sized 6x6 mm photo sensors. As photo sensors, semi conductor light sensors (SiPMs) are utilized. The camera provides a high photon detection efficiency together with robust operation. The enclosed optics permit operation in regions of harsh environmental conditions. The low price of the telescope allows the production of a large number of telescopes and the application of the instrument in various projects, such as FAMOUS for the Pierre Auger Observatory, HAWC's Eye for HAWC or IceAct for IceCube. In this paper the novel design of this telescope and first measurements are presented.Comment: Submitted to JINST, second (minor) revisio

    Self-Consistent Tensor Product Variational Approximation for 3D Classical Models

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    We propose a numerical variational method for three-dimensional (3D) classical lattice models. We construct the variational state as a product of local tensors, and improve it by use of the corner transfer matrix renormalization group (CTMRG), which is a variant of the density matrix renormalization group (DMRG) applied to 2D classical systems. Numerical efficiency of this approximation is investigated through trial applications to the 3D Ising model and the 3D 3-state Potts model.Comment: 12 pages, 6 figure

    Low-Energy Structure of Heisenberg Ferrimagnetic Spin Chains

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    Static and dynamic structure factors of Heisenberg ferrimagnetic spin chains are numerically investigated. There exist two distinct branches of elementary excitations, which exhibit ferromagnetic and antiferromagnetic aspects. The ferromagnetic feature is smeared out with the increase of temperature, whereas the antiferromagnetic one persists up to higher temperatures. The scattering intensity is remarkably large at lower boundaries of the ferromagnetic and antiferromagnetic spectra. All these observations are consistent with the ferromagnetic-to-antiferromagnetic crossover in the thermal behavior which has recently been reported.Comment: 3 pages, 5 PS figures, to appear in J. Phys. Soc. Jpn. Vol. 67, No. 11 (1998
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