Water vapor and gas transport through polymeric membranes

Water vapor transport through polymeric materials plays an important role in a large number of applications such as: food packaging, breathable clothing, roofing membranes, diapers, and the removal of water vapor from gas streams (e.g. dehydration of natural gas or the drying of compressed air). Depending on the application a high or low permeability or selectivity is preferable. This thesis investigates the transport of water vapor and various gases through polyethylene oxide (PEO) polybutylene terephthalate (PBT) block copolymers and\ud asymmetric polyether sulfone (PES) polyimide (PI) blend hollow fiber membranes

Selective recovery of metal salts from aqueous streams using ionic liquids

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Salt extraction versus ion exchange

Abstract onl

IN-SITU DEFECT DETECTION FOR LASER POWDER BED FUSION WITH ACTIVE LASER THERMOGRAPHY

Defects are still common in metal components built with Additive Manufacturing (AM). Process monitoring methods for laser powder bed fusion (PBF-LB/M) are used in industry, but relationships between monitoring data and defect formation are not fully understood yet. Additionally, defects and deformations may develop with a time delay to the laser energy input. Thus, currently, the component quality is only determinable after the finished process. Here, active laser thermography, a nondestructive testing method, is adapted to PBF-LB/M, using the defocused process laser as heat source. The testing can be performed layer by layer throughout the manufacturing process. We study our proposed testing method along experiments carried out on a custom research PBF-LB/M machine using infrared (IR) cameras. Our work enables a shift from post-process testing of components towards in-situ testing during the AM process. The actual component quality is evaluated in the process chamber and defects can be detected between layers.Mechanical Engineerin

Punctuated equilibria and 1/f noise in a biological coevolution model with individual-based dynamics

We present a study by linear stability analysis and large-scale Monte Carlo simulations of a simple model of biological coevolution. Selection is provided through a reproduction probability that contains quenched, random interspecies interactions, while genetic variation is provided through a low mutation rate. Both selection and mutation act on individual organisms. Consistent with some current theories of macroevolutionary dynamics, the model displays intermittent, statistically self-similar behavior with punctuated equilibria. The probability density for the lifetimes of ecological communities is well approximated by a power law with exponent near -2, and the corresponding power spectral densities show 1/f noise (flicker noise) over several decades. The long-lived communities (quasi-steady states) consist of a relatively small number of mutualistically interacting species, and they are surrounded by a ``protection zone'' of closely related genotypes that have a very low probability of invading the resident community. The extent of the protection zone affects the stability of the community in a way analogous to the height of the free-energy barrier surrounding a metastable state in a physical system. Measures of biological diversity are on average stationary with no discernible trends, even over our very long simulation runs of approximately 3.4x10^7 generations.Comment: 20 pages RevTex. Minor revisions consistent with published versio

Real and Virtual Compton Scattering off the Nucleon

A review is given of the very recent developments in the fields of real and virtual Compton scattering off the nucleon. Both real and virtual Compton scattering reactions are discussed at low outgoing photon energy where one accesses polarizabilities of the nucleon. The real Compton scattering at large momentum transfer is discussed which is asymptotically a tool to obtain information on the valence quark wave function of the nucleon. The rapid developments in deeply virtual Compton scattering and associated meson electroproduction reactions at high energy, high photon virtuality and small momentum transfer to the nucleon are discussed. A unified theoretical description of those processes has emerged over the last few years, which gives access to new, generalized parton distributions. The experimental status and perspectives in these fields are also discussed.Comment: 25 pages, 17 figure

Estimate of the Collins fragmentation function in a chiral invariant approach

We predict the features of the Collins function, which describes the fragmentation of a transversely polarized quark into an unpolarized hadron, by modeling the fragmentation process at a low energy scale. We use the chiral invariant approach of Manohar and Georgi, where constituent quarks and Goldstone bosons are considered as effective degrees of freedom in the non-perturbative regime of QCD. To test the approach we calculate the unpolarized fragmentation function and the transverse momentum distribution of a produced hadron, both of which are described reasonably well. In the case of semi-inclusive deep-inelastic scattering, our estimate of the Collins function in connection with the transversity distribution gives rise to a transverse single spin asymmetry of the order of 10%, supporting the idea of measuring the transversity distribution of the nucleon in this way. In the case of e+ e- annihilation into two hadrons, our model predicts a Collins azimuthal asymmetry of about 5%.Comment: 12 pages, 15 figures. Figs. 11-14 changed, minor changes in discussion, few typos fixed and some references added. Final version to appear in PR

A mechanism for the T-odd pion fragmentation function

We consider a simple rescattering mechanism to calculate a leading twist $T$-odd pion fragmentation function, a favored candidate for filtering the transversity properties of the nucleon. We evaluate the single spin azimuthal asymmetry for a transversely polarized target in semi-inclusive deep inelastic scattering (for HERMES kinematics). Additionally, we calculate the double $T$-odd $\cos2\phi$ asymmetry in this framework.Comment: 6 pages revtex, 7 eps figures, references added and updated in this published versio

Transverse Momentum Dependent Parton Distribution/Fragmentation Functions at an Electron-Ion Collider

We present a summary of a recent workshop held at Duke University on Partonic Transverse Momentum in Hadrons: Quark Spin-Orbit Correlations and Quark-Gluon Interactions. The transverse momentum dependent parton distribution functions (TMDs), parton-to-hadron fragmentation functions, and multi-parton correlation functions, were discussed extensively at the Duke workshop. In this paper, we summarize first the theoretical issues concerning the study of partonic structure of hadrons at a future electron-ion collider (EIC) with emphasis on the TMDs. We then present simulation results on experimental studies of TMDs through measurements of single spin asymmetries (SSA) from semi-inclusive deep-inelastic scattering (SIDIS) processes with an EIC, and discuss the requirement of the detector for SIDIS measurements. The dynamics of parton correlations in the nucleon is further explored via a study of SSA in D (`D) production at large transverse momenta with the aim of accessing the unexplored tri-gluon correlation functions. The workshop participants identified the SSA measurements in SIDIS as a golden program to study TMDs in both the sea and valence quark regions and to study the role of gluons, with the Sivers asymmetry measurements as examples. Such measurements will lead to major advancement in our understanding of TMDs in the valence quark region, and more importantly also allow for the investigation of TMDs in the sea quark region along with a study of their evolution.Comment: 44 pages 23 figures, summary of Duke EIC workshop on TMDs accepted by EPJ