Nuclear resonant scattering of synchrotron radiation by physisorbed Kr on TiO2_{2}(110) surfaces in multilayer and monolayer regimes

Physisorbed Kr layers on TiO$_{2}$(110) surfaces were investigated by means of nuclear resonant scattering (NRS) of synchrotron radiation at Kr thicknesses ranging from multilayer to monolayer. The NRS intensity was measured as a function of the Kr exposure, from which the NRS signal corresponding to monolayer was estimated as 0.23 cps. The time spectra measured at various thicknesses showed a monotonous decay without any quantum beat features. The recoiless fraction $f$ evaluated from the analysis of the time spectrum revealed a substantial reduction upon temperature rise from 19 to 25 K. As its origin, an order-disorder phase transition of the monolayer Kr is proposed.Comment: 7 pages, 6 figure

Nuclear resonant scattering of synchrotron radiation by physisorbed Kr on TiO2(110) surfaces in multilayer and monolayer regimes

Physisorbed Kr layers on TiO2(110) surfaces were investigated by means of nuclear resonant scattering (NRS) of synchrotron radiation at Kr thicknesses ranging from multilayer to monolayer. The NRS intensity was measured as a function of the Kr exposure, from which the NRS signal corresponding to monolayer was estimated as 0.23 cps. The time spectra measured at various thicknesses showed a monotonous decay without any quantum beat features. The recoilless fraction f evaluated from the analysis of the time spectrum revealed a substantial reduction upon temperature rise from 19 to 25 K. As its origin, an order-disorder phase transition of the monolayer Kr is proposed

Photostimulated desorption of Xe from Au(001) surfaces via transient Xe− formation

Photostimulated desorption (PSD) of Xe atoms from the Au(001) surface in thermal and nonthermal regimes was investigated by the time-of-flight measurement at photon energies of 6.4 and 2.3 eV. Xe was desorbed in a thermal way at high laser fluence, which was in good agreement with theoretical simulations. At a low laser fluence, on the other hand, desorption was induced only at a photon energy of 6.4 eV by a nonthermal one-photon process. We argue that the nonthermal PSD occurs via transient formation of Xe− on Au(001). The lifetime of Xe− is estimated to be ∼15 fs with a classical model calculation. Whereas the electron affinity of Xe is negative in the isolated state, it is stabilized by the metal proximity effect

Knudsen layer formation in laser induced thermal desorption

Laser induced thermal desorption of Xe atoms into vacuum from a metal surface following the nano-second pulsed laser heating was investigated by the time-of-flight (TOF) measurement. The desorption flow was studied at a wide range of desorption flux by varying the initially prepared Xe coverage Θ (1 ML = 4.5 × 1018 atoms/m2). At Θ = 0.3 ML, the TOF of Xe was well represented by a Maxwell-Boltzmann velocity distribution, which is in good agreement with thermal desorption followed by collision-free flow. At Θ > 0.3 ML, the peak positions of the TOF spectra were shifted towards the smaller values and became constant at large Θ, which were well fitted with a shifted Maxwell-Boltzmann velocity distribution with a temperature T D and a stream velocity u. With T D fixed at 165 K, u was found to increase from 80 to 125 m/s with increasing Θ from 1.2 to 4 ML. At Θ > 4 ML, the value of u becomes constant at 125 m/s. The converging feature of u was found to be consistent with analytical predictions and simulated results based on the Knudsen layer formation theory. We found that the Knudsen layer formation in laser desorption is completed at Knudsen number Kn <0.39

Photostimulated desorption of Xe from Au(001) surfaces via transient Xe− formation

Photostimulated desorption (PSD) of Xe atoms from the Au(001) surface in thermal and nonthermal regimes was investigated by the time-of-flight measurement at photon energies of 6.4 and 2.3 eV. Xe was desorbed in a thermal way at high laser fluence, which was in good agreement with theoretical simulations. At a low laser fluence, on the other hand, desorption was induced only at a photon energy of 6.4 eV by a nonthermal one-photon process. We argue that the nonthermal PSD occurs via transient formation of Xe− on Au(001). The lifetime of Xe− is estimated to be ∼15 fs with a classical model calculation. Whereas the electron affinity of Xe is negative in the isolated state, it is stabilized by the metal proximity effect