Peak effect in twinned superconductors

A sharp maximum in the critical current $J_c$ as a function of temperature just below the melting point of the Abrikosov flux lattice has recently been observed in both low and high temperature superconductors. This peak effect is strongest in twinned crystals for fields aligned with the twin planes. We propose that this peak signals the breakdown of the collective pinning regime and the crossover to strong pinning of single vortices on the twin boundaries. This crossover is very sharp and can account for the steep drop of the differential resistivity observed in experiments.Comment: 4 pages, revtex 3.0, no figure

Plasticity in current-driven vortex lattices

We present a theoretical analysis of recent experiments on current-driven vortex dynamics in the Corbino disk geometry. This geometry introduces controlled spatial gradients in the driving force and allows the study of the onset of plasticity and tearing in clean vortex lattices. We describe plastic slip in terms of the stress-driven unbinding of dislocation pairs, which in turn contribute to the relaxation of the shear, yielding a nonlinear response. The steady state density of free dislocations induced by the applied stress is calculated as a function of the applied current and temperature. A criterion for the onset of plasticity at a radial location $r$ in the disk yields a temperature-dependent critical current that is in qualitative agreement with experiments.Comment: 11 pages, 4 figure

An exploration of the reactivity of singlet oxygen with biomolecular constituents

The thermal reaction between biomolecules and singlet oxygen (1O2) is important for rendering the genetic material within toxic cells inactive. Here we present results obtained from state-of-the-art multi-reference computational methods that reveal the mechanistic details of the reaction between 1O2 and two exemplary biomolecular systems: guanine (Gua) and histidine (His). The results highlight the splitting of the doubly degenerate 1Δg state of O2 upon complexation and the essentially barrierless potential energy profile of the thermally allowed cycloaddition reaction when the O2 molecule is in its lower energy 1Δg state.</p

Synthesis, variable temperature NMR investigations and solid state characterisation of novel octafluorofluorene compounds

The preparation of a number of new 9-substituted octafluorofluorene derivatives, solution NMR studies, and the first examples of solid state structures of octafluorofluorenes [1,2,3,4,5,6,7,8-octafluorofluorene, C13H2F8, 1; 1,2,3,4,5,6,7,8-octafluoro-9-(pentafluoro)phenylfluorene, C19HF13, 8; 1,1′,2,2′,3,3′,4,4′,5,5′,6,6′,7,7′,8,8′-hexadecafluoro-9,9′-bifluorenyl, C26H2F16, 11] are reported. Variable temperature 19F NMR investigations have been performed on the 9-aryl substituted compounds 1,2,3,4,5,6,7,8-octafluoro-9-(pentafluoro)phenyl-9-hydroxyfluorene, C19HF13O, 4, 1,2,3,4,5,6,7,8-octafluoro-9-(nonafluoro-4′-biphenylyl)-9-hydroxyfluorene, C25HF17O, 5, and 8, and the energetic barriers to rotation of the aryl have been determined. A lower rotational barrier is observed for compound 4 with respect to compound 8, while 5 does not show fluxional behaviour below 338 K. The results of the variable temperature experiments performed on 8 have been rationalized by 2D NMR studies, and compared to the solid state data resulting from the X-ray structural analysis

Supersolidity in electron-hole bilayers with a large density imbalance

We consider an electron-hole bilayer in the limit of extreme density imbalance, where we have a single particle in one layer interacting attractively with a Fermi liquid in the other parallel layer. Using an appropriate variational wave function for the dressed exciton, we provide strong evidence for the existence of the Fulde-Ferrell-Larkin-Ovchinnikov (FFLO) phase in electron-hole bilayers with a large density imbalance. Furthermore, within this unusual limit of FFLO, we find that a dilute gas of minority particles forms excitons that condense into a two-dimensional "supersolid".Comment: 6 pages, 2 figure

Driven depinning of strongly disordered media and anisotropic mean-field limits

Extended systems driven through strong disorder are modeled generically using coarse-grained degrees of freedom that interact elastically in the directions parallel to the driving force and that slip along at least one of the directions transverse to the motion. A realization of such a model is a collection of elastic channels with transverse viscous couplings. In the infinite range limit this model has a tricritical point separating a region where the depinning is continuous, in the universality class of elastic depinning, from a region where depinning is hysteretic. Many of the collective transport models discussed in the literature are special cases of the generic model.Comment: 4 pages, 2 figure