Silica-supported perchloric acid and potassium bisulfate as reusable green catalysts for nitration of aromatics under solvent-free microwave conditions

<p>Silica-supported perchloric acid and bisulfate (SiO₂/HClO₄ and SiO₂/KHSO₄) have been developed as reusable green catalysts for nitration of aromatic compounds using NaNO₂ in acetonitrile medium under conventional and solvent-free microwave conditions. The reaction times under microwave irradiation are significantly shorter than conventional method even though the yields obtained in microwave-assisted reactions are comparable with those obtained under reflux conditions.</p

Ultrasonic and microwave effects in polyethylene glycol-bound metal nitrate initiated nitration of aromatic compounds under acid free conditions

<div><p>ABSTRACT</p><p>Ultrasonic and microwave-assisted practical methods have been developed for the nitration of phenols using metal nitrates in aqueous polyethylene glycol (PEG) media. Solvent is recycled three times for reproducibility. It was recycled with minimum loss and decomposition. Developed protocols were cost effective, simple and efficient, which afforded nitration products in good to excellent yields. The observed hyperchromic/hypochromic shifts in the UV/VIS spectra of metal nitrates in PEG solutions could be due to the plausible <i>in situ</i> formation of “PEG-bound M(II) nitrate” and thereby the release of nitronium ion () during the course of reaction when metal nitrate [M(II)nitrate] is added to PEG. Nitronium thus formed most likely is captured by aromatic compound to afforded nitro aromatics.</p></div