Matrix isolation technique for the study of some factors affecting the partitioning of trace elements

The factors that affect the preferred positions of cations in ionic solid solutions were investigated utilizing vibrational spectroscopy. Solid solutions of the sulfate and chromate ions codoped with La(+3) and Ca(+2) in a KBr host lattice were examined as a function of the polyvalent cation concentration. The cation-anion pairing process was found to be random for Ca(+2), whereas the formation of La(+3)-SO4(-2) ion pairs with a C2 sub v bonding geometry is highly preferential to any type of La(+3)-CrO4(-2) ion pair formation. The relative populations of ion pair site configurations are discussed in terms of an energy-entropy competition model which can be applied to the partition of trace elements during magmatic processes

RELIABILITY OF PROGRAMMING SOFTWARE: COMPARISON OF SHAZAM AND SAS

Research Methods/ Statistical Methods,

Nanoindentation of virus capsids in a molecular model

A molecular-level model is used to study the mechanical response of empty cowpea chlorotic mottle virus (CCMV) and cowpea mosaic virus (CPMV) capsids. The model is based on the native structure of the proteins that consitute the capsids and is described in terms of the C-alpha atoms. Nanoindentation by a large tip is modeled as compression between parallel plates. Plots of the compressive force versus plate separation for CCMV are qualitatively consistent with continuum models and experiments, showing an elastic region followed by an irreversible drop in force. The mechanical response of CPMV has not been studied, but the molecular model predicts an order of magnitude higher stiffness and a much shorter elastic region than for CCMV. These large changes result from small structural changes that increase the number of bonds by only 30% and would be difficult to capture in continuum models. Direct comparison of local deformations in continuum and molecular models of CCMV shows that the molecular model undergoes a gradual symmetry breaking rotation and accommodates more strain near the walls than the continuum model. The irreversible drop in force at small separations is associated with rupturing nearly all of the bonds between capsid proteins in the molecular model while a buckling transition is observed in continuum models.Comment: 18 figure

Phonon spectral function for an interacting electron-phonon system

Using exact diagonalzation techniques, we study a model of interacting electrons and phonons. The spectral width of the phonons is found to be reduced as the Coulomb interaction U is increased. For a system with two modes per site, we find a transfer of coupling strength from the upper to the lower mode. This transfer is reduced as U is increased. These results give a qualitative explanation of differences between Raman and photoemission estimates of the electron-phonon coupling constants for A3C60 (A= K, Rb).Comment: 4 pages, RevTeX, 2 eps figur

Multiphoton resonance in a three-level system with nearly degenerate excited states

An analytic study is presented of the efficient multiphoton excitation and strong harmonic generation in three-level systems specified by a pair of nearly degenerate, strongly dipole-coupled excited states. Such systems are physically formed by the three lowest states in, e.g., the hydrogen atom or evenly charged homonuclear diatomic molecular ions under reasonably chosen laser intensities. As a detailed analytic result, we found that the laser pulse of photon energy $2{.}05\text{eV}$, duration $0{.}23\text{ps}$ and intensity $5\cdot 10^{13}\,\frac{\text{W}}{\text{cm}^2}$ is able to produce complete inversion of the initial population in the hydrogen atom through the 5-photon excitation. At the same photon energy, the pulse of duration $0{.}41\text{ps}$ and intensity $3{.}44\cdot 10^{14}\,\frac{\text{W}}{\text{cm}^2}$ was found to produce the same effect in the molecular ion but through the 9-photon excitation. We show that the accompanying scattering of light has very rich spectrum differing substantially from that of the two-level system.Comment: 9 pages, 5 figures,submitted to Phys. Rev. A, comments welcom

AN EXAMINATION OF THE EMPIRICAL PROPERTIES OF DUALITY BETWEEN THE RESTRICTED PROFIT, UNRESTRICTED PROFIT, AND PRODUCTION FUNCTIONS

This research examines the empirical properties of duality theory. A comparison of the Hessian matrices calculated from the normalized unrestricted and restricted profit, and production functions indicate that duality is highly sensitive to measurement error and relative price variability. Keywords: duality, restricted and unrestricted profit functionsduality, restricted and unrestricted profit functions, Demand and Price Analysis, Production Economics,

Agricultural Health and Safety: A Research Agenda for Agricultural Economists

Replaced with revised version of paper 01/26/06.Health Economics and Policy, Teaching/Communication/Extension/Profession,

Polarisation rotation of slow light with orbital angular momentum in ultracold atomic gases

We consider the propagation of slow light with an orbital angular momentum (OAM) in a moving atomic medium. We have derived a general equation of motion and applied it in analysing propagation of slow light with an OAM in a rotating medium, such as a vortex lattice. We have shown that the OAM of slow light manifests itself in a rotation of the polarisation plane of linearly polarised light. To extract a pure rotational phase shift, we suggest to measure a difference in the angle of the polarisation plane rotation by two consecutive light beams with opposite OAM. The differential angle $\Delta\alpha_{\ell}$ is proportional to the rotation frequency of the medium $\omega_{\mathrm{rot}}$ and the winding number $\ell$ of light, and is inversely proportional to the group velocity of light. For slow light the angle $\Delta\alpha_{\ell}$ should be large enough to be detectable. The effect can be used as a tool for measuring the rotation frequency $\omega_{\mathrm{rot}}$ of the medium.Comment: 5 pages, 1 figur

Superconductivity in Boron under pressure - why are the measured Tc_c's so low?

Using the full potential linear muffin-tin orbitals (FP-LMTO) method we examine the pressure-dependence of superconductivity in the two metallic phases of Boron: bct and fcc. Linear response calculations are carried out to examine the phonon frequencies and electron-phonon coupling for various lattice parameters, and superconducting transition temperatures are obtained from the Eliashberg equation. In both bct and fcc phases the superconducting transition temperature T$_c$ is found to decrease with increasing pressure, due to stiffening of phonons with an accompanying decrease in electron-phonon coupling. This is in contrast to a recent report, where T$_c$ is found to increase with pressure. Even more drastic is the difference between the measured T$_c$, in the range 4-11 K, and the calculated values for both bct and fcc phases, in the range 60-100 K. The calculation reveals that the transition from the fcc to bct phase, as a result of increasing volume or decreasing pressure, is caused by the softening of the X-point transverse phonons. This phonon softening also causes large electron-phonon coupling for high volumes in the fcc phase, resulting in coupling constants in excess of 2.5 and T$_c$ nearing 100 K. We discuss possible causes as to why the experiment might have revealed T$_c$'s much lower than what is suggested by the present study. The main assertion of this paper is that the possibility of high T$_c$, in excess of 50 K, in high pressure pure metallic phases of boron cannot be ruled out, thus substantiating the need for further experimental investigations of the superconducting properties of high pressure pure phases of boron.Comment: 16 pages, 8 figures, 1 Tabl

Strongly coupled plasma with electric and magnetic charges

A number of theoretical and lattice results lead us to believe that Quark-Gluon Plasma not too far from $T_c$ contains not only electrically charged quasiparticles -- quarks and gluons -- but magnetically charged ones -- monopoles and dyons -- as well. Although binary systems like charge-monopole and charge-dyon were considered in details before in both classical and quantum settings, it is the first study of coexisting electric and magnetic particles in many-body context. We perform Molecular Dynamics study of strongly coupled plasmas with $\sim 1000$ particles and different fraction of magnetic charges. Correlation functions and Kubo formulae lead to such transport properties as diffusion constant, shear viscosity and electric conductivity: we compare the first two with empirical data from RHIC experiments as well as results from AdS/CFT correspondence. We also study a number of collective excitations in these systems.Comment: 2nd version, 22 pages, 32 figures: two important new figures have been included to compare our results with RHIC experiments and AdS/CFT results; a few new references and comments are added as wel