1,175 research outputs found
Does the Borexino experiment have enough resolution to detect the neutrino flavor day-night asymmetry?
The Earth's density distribution can be approximately considered piecewise
continuous at the scale of two-flavor oscillations of neutrinos with energies
about 1 MeV. This quite general assumption appears to be enough to analytically
calculate the day-night asymmetry factor. Using the explicit time averaging
procedure, we show that, within the leading-order approximation, this factor is
determined by the electron density immediately before the detector, i.e. in the
Earth's crust. Within the approximation chosen, the resulting asymmetry factor
does not depend either on the properties of the inner Earth's layers or on the
substance and the dimensions of the detector. For beryllium neutrinos, we
arrive at the asymmetry factor estimation of about , which
is at least one order of magnitude beyond the present experimental resolution,
including that of the Borexino experiment.Comment: 16 pages, 3 figures; Talk given at the 17th International Seminar on
High Energy Physics "QUARKS'2012" (Yaroslavl, Russia, June 4-10, 2012); to
appear in the Proceedings volum
Nucleation and Crystallization of Ferrous Phosphate Hydrate via an Amorphous Intermediate
The fundamental processes of nucleation and crystallization are widely observed in systems relevant to material synthesis and biomineralization; yet most often, their mechanism remains unclear. In this study, we unravel the discrete stages of nucleation and crystallization of Fe3(PO4)2·8H2O (vivianite). We experimentally monitored the formation and transformation from ions to solid products by employing correlated, time-resolved in situ and ex situ approaches. We show that vivianite crystallization occurs in distinct stages via a transient amorphous precursor phase. The metastable amorphous ferrous phosphate (AFEP) intermediate could be isolated and stabilized. We resolved the differences in bonding environments, structure, and symmetric changes of the Fe site during the transformation of AFEP to crystalline vivianite through synchrotron X-ray absorption spectroscopy at the Fe K-edge. This intermediate AFEP phase has a lower water content and less distorted local symmetry, compared to the crystalline end product vivianite. Our combined results indicate that a nonclassical, hydration-induced nucleation and transformation driven by the incorporation and rearrangement of water molecules and ions (Fe2+ and PO43–) within the AFEP is the dominating mechanism of vivianite formation at moderately high to low vivianite supersaturations (saturation index ≤ 10.19). We offer fundamental insights into the aqueous, amorphous-to-crystalline transformations in the Fe2+–PO4 system and highlight the different attributes of the AFEP, compared to its crystalline counterpart
Pressure, stress, and strain distribution in the double-stage diamond anvil cell
Double stage diamond anvil cells (DAC) of two designs have been assembled and
tested. We used a standard symmetric DAC as a primary stage and CVD microanvils
machined by a focused ion beam - as a second. We evaluated pressure, stress,
and strain distributions in Au and Fe-Au samples as well as in secondary anvils
using synchrotron x-ray diffraction with a micro-focused beam. A maximum
pressure of 240 GPa was reached independent of the first stage anvil culet
size. We found that the stress field generated by the second stage anvils is
typical of conventional DAC experiments. The maximum pressures reached are
limited by strains developing in the secondary anvil and by cupping of the
first stage diamond anvil in the presented experimental designs. Also, our
experiments show that pressures of several megabars may be reached without
sacrificing the first stage diamond anvils
Comparative high-pressure investigations of Ag2ZnSnS4 and Ag2CdSnS4 compounds
Quaternary kesterite-type (KS) compounds have attracted worldwide attention from the scientific community as promising materials for solar cells. On the route to optimizing their performance, the effect of stress and strain constitutes a critical factor when it comes to thin film applications. Following a recent theoretical study, we report here joint experimental and computational high-pressure investigations on the KS Ag2ZnSnS4 and wurtz–kesterite (WZ–KS)-type Ag2CdSnS4 compounds. Our results reveal that both materials undergo successive transformations, first into a GeSb-type and then toward a CrN-type modification at ambient temperature. Our theoretical calculations predict a metallic character for all Ag2ZnSnS4 and Ag2CdSnS4 high-pressure phases. In addition, structural disorder is observed in KS Ag2ZnSnS4 upon moderate compression, prior to its KS → GeSb-type transition. Decompression leads to the recovery of a disordered zinc blende-type structure in the latter, whereas Ag2CdSnS4 retains the disordered GeSb-type modification. The similarities and deviations from the archetypical KS Cu2ZnSnS4 are discussed
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