Late Neoarchean crust-mantle geodynamics : evidence from Pingquan Complex of the Northern Hebei Province, North China Craton

This study is financially supported by the National Natural Science Foundation of China (Grant Nos. 41530207, 41502179, 41472165, 41602198) and Central University Basic Scientific Research Business Expenses (Grant No. 2652015038). PAC acknowledges support from Australian Research Council grant FL160100168.A late Neoarchean intra-oceanic arc along the northwestern margin of Eastern Block (EB), North China Craton, provides important insights into the nature of Archean mantle sources and crust-mantle geodynamics. The Pingquan Complex and the entire Northern Hebei Province (NHB) are located in the middle part of the arc, and overlap the northern extent of the Trans-North China Orogen. Zircon U-Pb isotopic age data reveal that the Pingquan Complex consists of ∼2537-2515 Ma dioritic gneisses, ∼2506-2503 Ma amphibolites, and ∼2491 Ma quartz monzodioritic to monzogranitic gneisses, and they show dominantly positive zircon εHf(t) (-0.6-+5.4) that are lower than coeval model depleted mantle values. Geochemical data for the Pingquan rocks and synchronous metabasalts and granitoid gneisses of Huai’an-Xuanhua and Dantazi complexes in the NHB are integrated. Except for the monzogranitic gneisses that were derived from partial melting of juvenile metagreywackes, the other rocks of the Pingquan Complex were derived from a metasomatized lithospheric mantle, and subjected to variable fractionation of clinopyroxene, hornblende and plagioclase, without significant crustal contamination. Moderately depleted zircon εHf(t), and high Sm/Hf and Nb/Ta (mostly of 1.34-3.96 and 15.50-32.58) suggest that the lithospheric mantle was enriched by subducted pelagic sediments metamorphosed to rutile-bearing eclogites before melting. Late Neoarchean crust-mantle geodynamic processes in the NHB are reconstructed. Intra-oceanic subduction initiated offshore of the northwestern margin of the EB at ∼2.55 Ga or earlier. Partial melting of slab basalts occurred at ∼2542-2499 Ma, with the melts contaminated by mantle wedge materials forming TTGs. Meanwhile, the sub-arc lithospheric mantle was enriched by fluids and melts released from slab basalts and pelagic sediments, and partial melting of this moderately depleted mantle generated ∼2537-2503 Ma diorites and basalts. Following final accretion of the arc onto the continental margin of the EB, the slab rollback/breakoff and asthenospheric mantle upwelling triggered partial melting of the metasomatized lithospheric mantle and crustal anatexis, generating ∼2491 Ma quartz monzodioritic and monzogranitic rocks. Accordingly, the NHB records Neoarchean crustal growth linked to oceanic subduction and arc-continent accretion, and highlights the importance of resolving the nature of mantle sources and crust-mantle interactions in understanding Archean crustal growth and evolution.PostprintPeer reviewe

Cyclic formation and stabilization of Archean lithosphere by accretionary orogenesis : constraints from TTG and potassic granitoids, North China Craton

This study is financially supported by the National Natural Science Foundation of China (Grant Nos. 41502179, 41530207, 41472165) and Central University Basic Scientific Research Business Expenses of China University of Geosciences (Beijing) (Grant No. 2652015038). PAC acknowledges support from Australian Research Council grant FL160100168.Accretionary orogens are major sites of modern continental growth, yet their role in the development of Archean continental crust remains enigmatic. Diverse granitoid suites from tonalite-trondhjemite-granodiorite (TTG) to potassic granitoids appeared during late Archean, representing a period of major continental formation and stabilization. In this study, whole-rock geochemical and zircon U-Pb and Lu-Hf isotopic data are reported for Neoarchean granitoid gneisses from the Northern Liaoning Terrane, northeastern North China Craton (NCC). Older granitoid gneisses (~2592-2537 Ma) define three magmatic zones migrating from southeast to northwest, each showing a common magmatic evolution from high-pressure TTGs to medium-/low-pressure TTGs and potassic granitoids. They have depleted zircon ƐHf(t) of +0.5 to +8.7. Younger ~2529-2503 Ma potassic granitoids and TTGs occur throughout the terrane, which are marked by variable zircon ƐHf(t) of -4.7 to +8.1, and are coeval with regional high grade metamorphism. Petrogenetic modeling and changing Sr/Y and (La/Yb)N of the granitoids suggest that the crust experienced episodic thickening and thinning, and became progressively evolved through development of potassic granitoids and sedimentary successions. The metavolcanic basement to the granitoids display tholeiitic to calc-alkaline affinities, together with the top-to-the-northwest thrusting and associated VMS-type Cu-Zn deposits, suggesting cyclic crustal formation of Northern Liaoning within an accretionary orogen with a SE-dipping subduction polarity. Cyclic crustal thickening and thinning is related to tectonic switching from advancing to retreating relations between the downgoing and overriding plate. After ~2530 Ma, this accretionary system accreted to the ancient continental nucleus of NCC (Anshan-Benxi Terrane), signifying final lithosphere stabilization.Publisher PDFPeer reviewe

Late Neoarchean subduction-related crustal growth in the Northern Liaoning region of the North China Craton : evidence from ∼2.55-2.50 Ga granitoid gneisses

This study is financially supported by the National Natural Science Foundation of China (Grant Nos. 41272209, 41472165, 41502179, 41530207) and the Central University Basic Scientific Research Business Expenses of China University of Geosciences (Beijing) (Grant No. 2652015038).The North China Craton (NCC), dominated by ∼2.6-2.5 Ga tectonothermal events, provides a natural laboratory to study Neoarchean crustal growth and geodynamic evolution. Late Neoarchean granitoid gneisses are well exposed in the Northern Liaoning Province, located north of the ancient Anshan-Benxi terrane along the northeastern margin of the Eastern Block (EB) of the NCC. LA-ICPMS zircon U-Pb isotopic dating reveal that granitoid gneisses in the Qingyuan area can be grouped into two major episodes, i.e., ∼2559-2534 Ma strongly gneissic quartz dioritic and tonalitic to trondhjemitic gneisses; and ∼2529-2495 Ma weakly gneissic to massive quartz monzodioritic and monzogranitic gneisses, with subordinate tonalitic to trondhjemitic gneisses. The late magmatic episode was accompanied by regionally high-grade metamorphism (∼2510-2495 Ma). Most granitoid gneisses display highly depleted zircon εHf(t2) values (+4.2-+8.1), whereas one monzogranitic gneiss shows negative values of -4.7 to -1.0, indicating late Neoarchean crustal growth with minor involvement of ancient continental materials probably sourced from the Anshan-Benxi terrane. Geochemical and petrogenetic studies reveal that the quartz dioritic magmas were derived from partial melting of plagioclase-poor garnet amphibolites or eclogites metamorphosed from oceanic slab materials, with slab melts contaminated by mantle wedge peridotites during ascent. The tonalitic to trondhjemitic magmas stemmed from partial melting of mainly juvenile metabasaltic rocks with minor metagreywackes of lower arc crust. In comparison, the quartz monzodioritic and monzogranitic magmas were derived respectively from partial melting of depleted mantle sources metasomatized by slab-derived fluids and metagreywackes with different crustal resident ages at middle to lower crustal levels. Combined with previous studies of metavolcanic rocks, the Northern Liaoning Province records late Neoarchean crustal growth, evolving from mid-ocean ridge, through initiation and maturation of an intra-oceanic arc, to arc-continent collision. Arc-continent accretion and possibly slab rollback processes may have triggered reworking of both juvenile arc crust and minor ancient continental margin materials, generating the magmatic precursors for the monzogranitic gneisses. Overall, the intense late Neoarchean crustal growth of the EB was controlled mainly by arc-continent accretion, possibly linked to global assembly of cratonic fragments.PostprintPeer reviewe

Deep learning with knowledge graphs using graph neural networks

Knowledge Graphs (KGs) are reshaping the paradigm of representing, organising, and utilising information about the world. They provide rich semantic information, and have emerged as a driving power of Artificial Intelligence (AI). Primarily, there are two types of important research directions for KGs: one focuses on constructing and improving the quality of KGs, and the other delves into the wide range of applications of KGs. Recent years have also witnessed the advancement of Graph Neural Networks (GNNs), which are a class of deep learning techniques applicable to the graph domain and have demonstrated promising performance in many tasks. While there have been research attempts of applying GNNs to the KG-related tasks, there still remain several open challenges with the models’ function design, scalability issues, transductive nature of being limited to predicting for entities observed during training, and the quality of the benchmarks. In this thesis, towards deep learning with KGs using GNNs, we consider the tasks of inductive KG completion and inductive knowledge-enhanced recommendation in the context of the two directions, and propose novel GNN-based approaches to address the challenges. Our extensive empirical evaluation shows that our approaches outperform the state-of-the-art approaches on a collection of baselines, and can achieve efficient training and testing in practice. We also take a further step into the KG completion problem by revisiting the benchmarks in the transductive settings. In particular, we propose a new approach to generate benchmarks that can help empirically assess models’ ability to capture inference patterns. Our findings highlight the gaps between theoretical and empirical results concerning such inference ability

A novel pyruvate kinase and its application in lactic acid production under oxygen deprivation in Corynebacterium glutamicum

BACKGROUND: Pyruvate kinase (Pyk) catalyzes the generation of pyruvate and ATP in glycolysis and functions as a key switch in the regulation of carbon flux distribution. Both the substrates and products of Pyk are involved in the tricarboxylic acid cycle, anaplerosis and energy anabolism, which places Pyk at a primary metabolic intersection. Pyks are highly conserved in most bacteria and lower eukaryotes. Corynebacterium glutamicum is an industrial workhorse for the production of various amino acids and organic acids. Although C. glutamicum was assumed to possess only one Pyk (pyk1, NCgl2008), NCgl2809 was annotated as a pyruvate kinase with an unknown role. RESULTS: Here, we identified that NCgl2809 was a novel pyruvate kinase (pyk2) in C. glutamicum. Complementation of the WTΔpyk1Δpyk2 strain with the pyk2 gene restored its growth on d-ribose, which demonstrated that Pyk2 could substitute for Pyk1 in vivo. Pyk2 was co-dependent on Mn(2+) and K(+) and had a higher affinity for ADP than phosphoenolpyruvate (PEP). The catalytic activity of Pyk2 was allosterically regulated by fructose 1,6-bisphosphate (FBP) activation and ATP inhibition. Furthermore, pyk2 and ldhA, which encodes l-lactate dehydrogenase, were co-transcribed as a bicistronic mRNA under aerobic conditions and pyk2 deficiency had a slight effect on the intracellular activity of Pyk. However, the mRNA level of pyk2 in the wild-type strain under oxygen deprivation was 14.24-fold higher than that under aerobic conditions. Under oxygen deprivation, pyk1 or pyk2 deficiency decreased the generation of lactic acid, and the overexpression of either pyk1 or pyk2 increased the production of lactic acid as the activity of Pyk increased. Fed-batch fermentation of the pyk2-overexpressing WTΔpyk1 strain produced 60.27 ± 1.40 g/L of lactic acid, which was a 47% increase compared to the parent strain under oxygen deprivation. CONCLUSIONS: Pyk2 functioned as a pyruvate kinase and contributed to the increased level of Pyk activity under oxygen deprivation. ELECTRONIC SUPPLEMENTARY MATERIAL: The online version of this article (doi:10.1186/s12896-016-0313-6) contains supplementary material, which is available to authorized users

Control Strategy and Simulation of the Regenerative Braking of an Electric Vehicle Based on an Electromechanical Brake

The electromechanical brake (EMB) has very broad prospects for application in the automotive industry, especially in small- and medium-sized vehicles. To extend the endurance range of pure electric vehicles, a regenerative braking control strategy combined with an electromechanical brake model is designed that divides the braking modes according to the braking intensity and controls the regenerative braking force based on fuzzy theory. Considering a front-wheel-drive pure electric vehicle equipped with a floating clamp disc electromechanical brake as the research object, a structural form of electromechanical brake is proposed and a mathematical model of the electromechanical brake is built. Combined with the relevant influencing factors, the regenerative braking force is limited to a certain extent, and the simulation models of the electromechanical brake and the regenerative braking force distribution control strategy are built in MATLAB/Simulink. Co-simulation in MATLAB and AVL CRUISE software is conducted. The simulation results demonstrate that the braking energy recovery rate of the whole vehicle with the fuzzy control strategy put forward in this paper is 28.9% under mild braking and 34.11% under moderate braking. The control method substantially increases the energy utilization rate

Consumption Risks in Option Returns

We offer evidence that exposures to consumption growth and consumption volatility are significantly priced in the cross-section of delta-hedged option returns. Consumption growth commands a positive risk premium, whereas consumption volatility commands a negative risk premium. Our results suggest that consumption risk exposures provide rational foundations for well-known relations between options moneyness or idiosyncratic underlying-stock volatility and the cross-section of delta-hedged option returns. Furthermore, those risk premiums can also price stocks. In a representative-agent economy with recursive preferences, our results suggest that investors prefer early resolution of uncertainty