Electrophoretic deposition of cobalt oxide anodes for alkaline membrane water electrolyzer

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From visual comparison to robust satellite techniques: 30 years of thermal infrared satellite data analyses for the study of earthquake preparation phases

This review paper reports the main contributions and results achieved after more than 30 years of studies on the possible relationships among space-time variation of Earth’s thermally emitted radiation, measured by satellite sensors operating in the Thermal InfraRed (TIR) spectral range (8-14 m), and earthquake occurrence. Focus will be given on the different existing methods/models to: 1) discriminate a possible pre-seismic TIR anomaly from all the other TIR signal fluctuations; 2) correlate such anomalies with space, time and magnitude of earthquakes; 3) physically justify such a correlation

RST Analysis of Anomalous TIR Sequences in Relation with Earthquakes Occurred in Turkey in the Period 2004–2015

first_pagesettings Open AccessArticle RST Analysis of Anomalous TIR Sequences in Relation with Earthquakes Occurred in Turkey in the Period 2004–2015 by Carolina Filizzola 1ORCID,Angelo Corrado 2,Nicola Genzano 2ORCID,Mariano Lisi 1ORCID,Nicola Pergola 1ORCID,Roberto Colonna 2 andValerio Tramutoli 2,*ORCID 1 Institute of Methodologies for Environmental Analysis, National Research Council, 85050 Potenza, Italy 2 School of Engineering, University of Basilicata, 85100 Potenza, Italy * Author to whom correspondence should be addressed. Academic Editor: Stephan Havemann Remote Sens. 2022, 14(2), 381; https://doi.org/10.3390/rs14020381 Received: 12 November 2021 / Revised: 8 January 2022 / Accepted: 11 January 2022 / Published: 14 January 2022 (This article belongs to the Special Issue Advances in Remote Sensing Systems for Disaster Management and Risk Mitigation) Download PDF Browse Figures Citation Export Abstract The paper provides, for the first time, a long-term (>10 years) analysis of anomalous transients in Earth’s emitted radiation over Turkey and neighbouring regions. The RST (Robust Satellite Techniques) approach is used to identify Significant Sequences of Thermal Anomalies (SSTAs) over about 12 years (May 2004 to October 2015) of night-time MSG-SEVIRI satellite images. The correlation analysis is performed with earthquakes with M ≥ 4, which occurred in the investigated period/region within a pre-defined space-time volume around SSTA occurrences. It confirms, also for Turkey, the possibility to qualify SSTAs among the candidate parameters of a multi-parametric system for time-Dependent Assessment of Seismic Hazard (t-DASH). After analysing about 4000 images (about 400 million of single satellite records), just 155 SSTAs (about 4 every 100 images) were isolated; 115 (74% out of the total) resulted in earthquake-related (false-positive rate 26%). Results of the error diagram confirms a non-casual correlation between RST-based SSTAs and earthquake occurrences, with probability gain values up to 2.2 in comparison with the random guess. The analysis, separately performed on Turkish areas characterized by different faults and earthquakes densities, demonstrates the SSTA correlation with a dynamic seismicity more than with static tectonic settings

Optimal Setting of Earthquake-Related Ionospheric TEC (Total Electron Content) Anomalies Detection Methods: Long-Term Validation over the Italian Region

Over the last decade, thanks to the availability of historical satellite observations that have begun to be significantly large and thanks to the exponential growth of artificial intelligence techniques, many advances have been made in the detection of geophysical parameters such as seismic-related anomalies. In this study, the variations of the ionospheric Total Electron Content (TEC), one of the main parameters historically proposed as a seismic-connected indicator, are analyzed. To make a statistically robust analysis of the complex phenomena involved, we propose a completely innovative machine-learning approach developed in the R programming language. Through this approach, an optimal setting of the multitude of methodological inputs currently proposed for the detection of ionospheric anomalies is performed. The setting is optimized by analyzing, for the first time, multi-year—mostly twenty-year—time series of TEC satellite data measured by global navigation satellite systems (GNSS) over the Italian region, matched with the corresponding multi-year time series of seismic events. Seismic events including all the countries of the Mediterranean area, up to Turkey, are involved in the analysis. Tens of thousands of possible combinations of input methodological parameters are simulated and classified according to pre-established criteria. Several inputs examined return clear results. These results combined with each other highlight the presence of anomalous seismic-related sequences that have an extremely low probability of having been detected randomly (up to 2 out of 1 million). The anomalies identified represent the most anomalous behaviors of the TEC recorded during the entire period under investigation (e.g., 20 years). Some of the main conclusions are that, at mid-latitudes, ① the detection of seismic-TEC anomalies can be more efficient looking for punctual rather than persistent phenomena; ② the optimal thresholds for the identification of co-seismic anomalies can assume different values depending on type of anomaly (positive or negative) and type of observation; ③ single GNSS receiver data can be useful for capturing local earthquake-ionospheric effects and Global Ionospheric Maps (GIM) data can be functional in detecting large-scale earthquake-ionospheric effects; ④ earthquakes deeper than 50 km are less likely to affect the ionosphere

Thermodynamics of Surfactants, Block Copolymers and Their Mixtures in Water: The Role of the Isothermal Calorimetry

The thermodynamics of conventional surfactants, block copolymers and their mixtures in water was described to the light of the enthalpy function. The two methodologies, i.e. the van’t Hoff approach and the isothermal calorimetry, used to determine the enthalpy of micellization of pure surfactants and block copolymers were described. The van’t Hoff method was critically discussed. The aqueous copolymer+surfactant mixtures were analyzed by means of the isothermal titration calorimetry and the enthalpy of transfer of the copolymer from the water to the aqueous surfactant solutions. Thermodynamic models were presented to show the procedure to extract straightforward molecular insights from the bulk properties

Adsorption of triblock copolymers and their homopolymers at laponite clay/solution interface. Role played by the copolymer nature

The adsorption thermodynamics of copolymers, based on ethylene oxide (EO) and propylene oxide ( PO) units, at the laponite (RD) clay/liquid interface was determined at 298 K. The copolymer nature was tuned at molecular level by changing the hydrophilicity, the architecture and the molecular weight (Mw) keeping constant the EO/PO ratio. Polyethylene (PEGs) and polypropylene (PPGs) glycols with varying Mw and their mixture were also investigated to discriminate the role of the EO and the PO segments in the adsorption process. Enthalpies of transfer of RD, at fixed concentration, from water to the aqueous macromolecule solutions as functions of the macromolecule molality were determined. They were treated quantitatively by means of a model based on two equilibria: ( 1) one-to-one binding between the macromolecule and the site on the solid and ( 2) two-to-one binding following which one macromolecule interacts with another one adsorbed onto the solid. The good agreement between the equilibrium constants obtained from calorimetry and those determined from kinetic experiments conformed the reliability of the experimental and theoretical approaches. Almost all of the systems investigated are highlighted by the one-to-one binding; the L35 and 10R5 systems present both equilibria. The insights provided by the thermodynamics of adsorption of their homopolymers onto RD were fruitful in obtaining detailed information on the nature of the forces involved between RD and the copolymers. The data obtained in the present work clearly evidenced that for comparable polymer Mw, PPG is more suitable in building up a steric barrier around the RD particles and, indeed, exhibits several advantages and no drawbacks. Moreover, the parent copolymers may properly functionalize the RD surface by exploiting both their high affinity to the solid surface and the ability to self-assemble onto it as L35 and 10R5 clearly showed

Single layer graphene film by ethanol chemical vapor deposition: Highly efficient growth and clean transfer method

The choice of ethanol (C2H5OH) as carbon source in the Chemical Vapor Deposition (CVD) of graphene on copper foils can be considered as an attractive alternative among the commonly used hydrocarbons, such as methane (CH4) [1]. Ethanol, a safe, low cost and easy handling liquid precursor, offers fast and efficient growth kinetics with the synthesis of fullyformed graphene films in just few seconds [2]. In previous studies of graphene growth from ethanol, various research groups explored temperature ranges lower than 1000 °C, usually reported for methane-assisted CVD. In particular, the 650–850 °C and 900 °C ranges were investigated, respectively for 5 and 30 min growth time [3, 4]. Recently, our group reported the growth of highly-crystalline, few-layer graphene by ethanol-CVD in hydrogen flow (1– 100 sccm) at high temperatures (1000–1070 °C) using growth times typical of CH4-assisted synthesis (10–30 min) [5]. Furthermore, a synthesis time between 20 and 60 s in the same conditions was explored too. In such fast growth we demonstrated that fully-formed graphene films can be grown by exposing copper foils to a low partial pressure of ethanol (up to 2 Pa) in just 20 s [6] and we proposed that the rapid growth is related to an increase of the Cu catalyst efficiency due weak oxidizing nature of ethanol. Thus, the employment of such liquid precursor, in small concentrations, together with a reduced time of growth and very low pressure leads to highly efficient graphene synthesis. By this way, the complete coverage of a copper catalyst surface with high spatial uniformity can be obtained in a considerably lower time than when using methane

RST analysis of MSG-SEVIRI TIR radiances at the time of the Abruzzo 6 April 2009 earthquake

Space-time fluctuations of Earth's emitted Thermal Infrared (TIR) radiation have been observed from satellite months to weeks before earthquakes occurrence. The general RST approach has been proposed in order to discriminate normal (i.e. related to the change of natural factor and/or observation conditions) TIR signal fluctuations from anomalous signal transient possibly associated to earthquake occurrence. In this work RST approach is applied to the Abruzzo 6 April 2009 event (M(L)=5.8) by using for the first time MSG-SEVIRI (Meteosat Second Generation -Spinning Enhanced Visible and Infrared Imager) thermal infrared observations. A validation/confutation analysis has been performed in order to verify the presence/absence of anomalous space-time TIR transients in the presence/absence of significant seismic activity. March-April 2009 has been analyzed for validation purposes. Relatively unperturbed periods (no earthquakes with M(L)>= 5) have been taken for confutation. A specific TIR anomalies space-time persistence analysis as well as a cloud coverage distribution test have been introduced in order to eliminate artifacts and outliers both in the validation and confutation phases. Preliminary results show clear differences in TIR anomalies occurrence during the periods used for validation and confutation purposes. Quite clear TIR anomalies appear also to mark main tectonic lines related to the preparatory phases of others, low magnitude (M(L)similar to 4) earthquakes, occurred in the area

Incarcerated Foreign Minors in Italy: How to Treat them?

Abstract: The aim of this study is to provide data regarding the treatment of foreign juveniles in the Italian justice system. The authors examined the records from juvenile detention centers and primary juvenile reception centers in Italy in order to gain a better understanding of how foreign minors are treated with respect to their Italian counterparts. Statistical analysis was then carried out and the results revealed many inequalities. The authors believe that it is important to create secondary and tertiary prevention services in order to decrease the likelihood of recidivism, and to promote the minor's integration into the social fabric of their adopted country. Foreign minors are more frequently placed in jail than their Italian counterparts. The authors conclude that only through the development of a united partnership can a welcoming network be created: one that is able to pick up on the first signs of trouble that often confront foreign minors

Using RST approach and EOS-MODIS radiances for monitoring seismically active regions: a study on the 6 April 2009 Abruzzo earthquake

In the last few years, Robust Satellite data analysis Techniques (RST) have been proposed and successfully applied for monitoring major natural and environmental risks. Among the various fields of application, RST analysis has been used as a suitable tool for satellite TIR surveys in seismically active regions, devoted to detect and monitor thermal anomalies possibly related to earthquake occurrence. In this work, RST has been applied, for the first time, to thermal infrared observations collected by MODIS (Moderate Resolution Imaging Spectroradiometer) - the sensor onboard EOS (Earth Observing System) satellites - in the case of Abruzzo (Italy) earthquake occurred on 6 April 2009 (M(L)similar to 5.8). First achievements, shown in this work, seem to confirm the sensitivity of the proposed approach in detecting perturbations of the Earths emission thermal field few days before the event. The reliability of such results, based on the analysis of 10 years of MODIS observations, seems to be supported by the results achieved analyzing the same area in similar observation conditions but in seismically unperturbed periods (no earthquakes with M(L)>= 5) that will be also presente