Simultaneous space charge and conduction current measurements in solid dielectrics under high dc electric field

The importance of space charge in solid dielectrics has been recognized for many years and various attempts have been made to map the distribution and assess its influence on the electrical performance of solid dielectrics. Significant development in non-destructive measurement techniques emerged two decades ago. Crosslinked polyethylene (XLPE) has been used for ac power cable insulation up to 500 kV for many years. There is a tendency to use XLPE for dc power cable. However, the easy formation of space charge under dc electric field within XLPE is a major concern for such an application. Space charge in insulation can distort electric field distribution, causing electric field increase in one region and reduction in another. The electric field enhancement could lead to degradation and result in premature failure. Electrical treeing in solid dielectrics is a typical example of local field enhancement due to space charge accumulation. In this report several popular non-destructive techniques are briefly reviewed. This is followed by detailed description of a modified pulsed electroacoustic (PEA) technique that allows simultaneous measurement of space charge and conduction current in a solid dielectric subjected to high dc electric fields. Finally, we report the relationship between space charge dynamics and electrical conduction current in XLPE using the modified PEA system. The effect of electrode material on both charge dynamics and current has been investigated using semiconducting material and aluminium. It has been found charge dynamics in the material depend on electrode configuration. More importantly, it has been noticed that the so called space charge limited transient current peaks are closely related to the meetings of negative and positive charge front in the bulk of the sample

Phase Diffusion in Single-Walled Carbon Nanotube Josephson Transistors

We investigate electronic transport in Josephson junctions formed by single-walled carbon nanotubes coupled to superconducting electrodes. We observe enhanced zero-bias conductance (up to 10e^2/h) and pronounced sub-harmonic gap structures in differential conductance, which arise from the multiple Andreev reflections at superconductor/nanotube interfaces. The voltage-current characteristics of these junctions display abrupt switching from the supercurrent branch to resistive branch, with a gate-tunable switching current ranging from 50 pA to 2.3 nA. The finite resistance observed on the supercurrent branch and the magnitude of the switching current are in good agreement with calculation based on the model of classical phase diffusion

Dielectric Breakdown Strength of Polyethylene Nanocomposites

The term “nanometric dielectrics” or simply “nanodielectrics” was introduced in 1994 when Lewis [1] anticipated the potential property changes that would benefit electrical insulation due to nano-sized inclusion. Such materials, containing homogenous dispersion of small amount (normally less than 10wt%) of nanoparticles (with at least one dimension in nanometre range) in host matrix, are of specific dielectric interest. Although much effort has been put forth to investigate the potential dielectric benefit of such newly emerging materials, many uncertainties remain unanswered, and much remains to be explored [2]. Current experimental work is to investigate the preparation of nanodielectrics via solution blending approach. Polyethylene blend composed of 20wt% of high density polyethylene (HDPE) in low density polyethylene (LDPE) is proposed as the base polymer, with varying content of nanosilica (between 0wt% and 10wt%) as the fillers. Although expensive, solution blending method, when compared with melt compounding method, is expected to provide better dispersion of nanoparticles in polymers, thus providing qualitative data in understanding the behaviour of nanodielectrics [3]. Upon successful preparation of polyethylene nanocomposites, breakdown strength based on ASTM Standard D149-87 is to be conducted to determine the feasibility of such dielectric materials in engineering point of view. Figure 1 illustrates the schematic diagram of the breakdown test configuration. The samples are placed between two 6.3mm diameter steel ball bearings immersed in silicone fluid. AC voltage at a preset ramp rate will be applied until the samples fail and the values of breakdown voltages will be recorded and analysed using two-parameter Weibull distribution. Based upon top-down research approach, the underlying physics and chemistry associated with dielectric property changes will then be explored

Water droplet excess free energy determined by cluster mitosis using guided molecular dynamics

Atmospheric aerosols play a vital role in affecting climate by influencing the properties and lifetimes of clouds and precipitation. Understanding the underlying microscopic mechanisms involved in the nucleation of aerosol droplets from the vapour phase is therefore of great interest. One key thermodynamic quantity in nucleation is the excess free energy of cluster formation relative to that of the saturated vapour. In our current study, the excess free energy is extracted for clusters of pure water modelled with the TIP4P/2005 intermolecular potential using a method based on nonequilibrium molecular dynamics and the Jarzynski relation. The change in free energy associated with the "mitosis" or division of a cluster of N water molecules into two N/2 sub-clusters is evaluated. This methodology is an extension of the disassembly procedure used recently to calculate the excess free energy of argon clusters [H. Y. Tang and I. J. Ford, Phys. Rev. E 91, 023308 (2015)]. Our findings are compared to the corresponding excess free energies obtained from classical nucleation theory (CNT) as well as internally consistent classical theory (ICCT). The values of the excess free energy that we obtain with the mitosis method are consistent with CNT for large cluster sizes but for the smallest clusters, the results tend towards ICCT; for intermediate sized clusters, we obtain values between the ICCT and CNT predictions. Furthermore, the curvature-dependent surface tension which can be obtained by regarding the clusters as spherical droplets of bulk density is found to be a monotonically increasing function of cluster size for the studied range. The data are compared to other values reported in the literature, agreeing qualitatively with some but disagreeing with the values determined by Joswiak et al. [J. Phys. Chem. Lett. 4, 4267 (2013)] using a biased mitosis approach; an assessment of the differences is the main motivation for our current study

Treatment of HBeAg-Positive Hepatitis B with Peginterferon and Lamivudine: Author's replies

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The Pacific Basin in World Trade: Part III, An Analysis of Changing Trade Patterns, 1955-1975

This is the third of a sequence of papers on international flows of trade among fifteen Pacific Basin (PB) countries and between them and eleven regions in the Rest of the World (ROW). In Part I of the sequence (Hickman, Kuroda and Lau, 1977a) we presented and documented annual data on bilateral flows of total exports valued f.o.b. in current dollars among the twenty-six countries and regions for the years 1948 through1975. The primary data source is the Direction of Trade computer tape of the International Monetary Fund, but these data were supplemented from other sources, especially as regards the international trade of the socialist countries. The second report (1977b) extended the data base to include unit value export price indexes and the corresponding constant dollar trade flow matrices for the period 1955-1975. In this third report we analyze the changing pattern of PB trade over the same period, using as tools export growth decomposition indexes, trend analysis, and regression analysis of the price elasticity of import market shares. The present paper is organized as follows. In Section 2 we describe the trends in the export performance of the PB countries and ROW regions, as measured by the cumulative percentage change in each country's share of world exports between 1955 and 1975 and for selected sub periods. In Section 3 and Appendices B and C these export share changes are decomposed into three sources: changes in the degree of penetration of the various import markets, changes in the size of the import markets themselves, and an interaction effect. The decomposition indexes are shown in Section 4 to be dominated by the market penetration or competitiveness effect, so that a country gains or loses in world trade according to whether or not it can increase its shares of the markets in which it sells rather than as a passive result of changes in the size of the markets themselves. This leads to a descriptive analysis in Section 5 of the secular growth rates of the market shares of each country or region in the import markets of the twenty-five remaining countries and regions. Finally, we conclude the paper in Section 6 with art exploratory regression analysis of the responsiveness of the market shares to changes in the relative prices of the various exporting countries competing in each import market, leading to the general conclusion that relative prices do matter and presenting estimates of share or substitution elasticities in the various import markets.

The Pacific Basin in World Trade: Part II, Constant-Price Trade Matrices, 1955-1975

This is the second of a sequence of papers on international flows of merchandise trade among fifteen Pacific Basin countries and between them and eleven regions in the Rest of the World. In the first paper in this sequence (Hickman, Kuroda and Lau (1977)) we presented annual data on bilateral flows of exports in current prices among the twenty-six countries and regions for the years 1948 through 1975. The basic purpose of this second report is to present and document data on annual export price indexes of the twenty-six countries and regions and annual bilateral flows of exports in constant U.S. dollar prices among the twenty-six countries and regions in matrix form from 1955 through 1975. A third report will analyze the changing pattern of Pacific Basin trade over the same period. The present report is organized as follows: In Section 2 we present the data sources for the export price indexes. Using these export price indexes, the current price trade matrices derived in the first report(Hickman, Kuroda and Lau (1977)) are deflated to obtain the constant price trade matrices. In Section 3 we examine whether the concept of a Pacific Basin regional economy may still be justified when viewed in a constant price context and describe the postwar trends in its share of world trade and in its internal trading relationships on a constant price basis. In Section 4 we present terms of trade indexes for each country and region from 1955 through 1975 and discuss some of their implications.