6 research outputs found

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    We investigated mesoporous Nd0.7Sr0.3CoO3–?? electrocatalytic properties for the ORR. Mesoporous Nd0.7Sr0.3CoO3−?? has been prepared with a polymethyl methacrylate (PMMA) hard-template for an energy storage system. The prepared 3-dimensionally ordered mesoporous Nd0.7Sr0.3CoO3-??. (3DOM-NSC) has a well-developed mesoporous structure and has high specific surface area (22.0 m2 g-1). The catalytic activity for the oxygen reduction reaction (ORR) has been studied by a rotating-ring-disk electrode (RRDE). In the ORR test, a limiting current density of 3DOM-NSC was 5.83 mA cm-2 at 0.7 V (V vs. Hg/HgO) with 1600 rpm and the value was good compared with that of Pt/C. Moreover, it shows the stable and excellent performance in a hybrid Li-air battery

    Advance in Cathodic Properties with Nano-structured Double Perovskite via Infiltration for Solid Oxide Fuel Cells

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    The cathode polarization resistance (Rp) has been regarded as one of challenges for intermediate temperature solid oxide fuel cells (IT-SOFCs). To reduce the cathode Rp, the active sites for oxygen reduction reaction (ORR) should be attained as many as possible. In this study, the layered perovskite GdBa0.5Sr0.5CoFeO5+?? (GBSCF) was chosen as a cathode material due to its excellent structural stability and electrochemical characteristics. The optimized microstructure of GBSCF cathode for enhanced ORR was fabricated into villus structure composed of nano particles with pertinent sintering temperature. The optimized GBSCF cathode shows outstanding results cathode area specific resistance (ASR) of 0.006 ?? cm2 and maximum power density of 0.593 W cm-2 at 700oC on the YSZ electrolyte supported cell with thickness of ~80 mm
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